Sanitary landfill leachate treatment by aerated electrochemical Fenton process.

The aerated electrochemical Fenton procedure was investigated as a viable treatment approach for electrolytic degradation and decolourization of sanitary landfill leachate. The optimization effects of initial pH, applied voltage, H2O2 concentration and combination of iron electrodes on detoxification were demonstrated by COD and colour removal from stabilized leachate, respectively. The study illustrates that, under the optimum experimental parameters voltage of 4.5 V, electrolysis time of 90 min, H2O2 dosage of 5 g/L, pH 3, 99% of chemical oxygen demand (COD) and 100% colour are removed from stabilized leachate, and the biodegradability ratio of the five-day biochemical oxygen demand (BOD5) to COD increases from 0.1 to 0.72. In addition, the pure catalytic metallic iron anode and cathode electrode used in the electrochemical Fenton process was first electro-oxidized to Fe2+ for use during the Fenton reaction, then with Fe3+ that was reverted back to Fe2+ under the applied electrochemical-magnetic field, resulting in the iron dissolution and regeneration circuit (Fe2+/Fe3+/Fe2+). Additionally, Fe2+/Fe3+ served as bridges for agglomerates to coalesce into big, closely packed particles for better filterability and sedimentation action. As a preparatory step for the biochemical treatment, this technology has been effectively used to treat stabilized landfill leachate containing toxic refractory recalcitrant organics on a large scale. Additionally, by estimating the scientific experiment with a regression model approach for the outcomes, RSM software was employed in order to standardize the ECF treatment process, significantly reducing the number of test cases and trials.

Combination of electrocoagulation with solar photo Fenton process for treatment of landfill leachate.

The aim of the present work was to provide a viable and active way to remove COD and colour from landfill leachate treated by adopting combined process of electrocoagulation and solar photo Fenton process. Coagulating agents such as metal hydroxides are created by the electrolysis process through self-sacrificial electrodes. Aluminium and iron dissolves at the anode and hydrogen gas are generated at the cathode when aluminium and iron electrodes are utilised. The contaminants interact with the coagulating agent to generate enormous organic flocs. The leachate was obtained from a landfill in Madurai and then it was characterised in terms of its major predominant pollutants. In this study, the electrocoagulation process was used in conjunction with the solar photo Fenton process to treat the leachate under ideal conditions of pH = 7, NaCl = 2 g/L, voltage = 4 V, Al & Fe electrodes and inter electrode distance = 3 cm with a COD and colour removal effectiveness of 75% and 76%, respectively. Furthermore, the effluent from the electrocoagulation process was treated using a solar photo Fenton process at pH = 3, H2O2 = 10 g/L and Fe2+ = 1 g/L with COD and colour reduction effectiveness of 90% and 91%, respectively. In this combination of treatment systems, leachate biodegradability increased from 0.35 to 0.73, favouring the biological oxidation process in conventional treatment plants. This research demonstrates that employing this paired electrocoagulation-solar photo Fenton to treat landfill leachate can achieve consistent treatment effects with high removal efficiencies, and that it is an acceptable treatment technique for landfill leachate.