1.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 2): m274, 2008 Jan 04.
Article
in English
| MEDLINE
| ID: mdl-21201257
ABSTRACT
In the title compound, [Co(C(14)H(8)N(2)O(6))(H(2)O)(4)](n), each 5,5'-diazenediylbis(2-hydroxy-benzoato) ligand acts as a dicarboxyl-ate bridge, leading to the formation of polymeric chains running in the [10] direction. The Co atom is hexa-coordinated in a distorted octa-hedral geometry by six O atoms [Co-O = 2.039â (4)-2.115â (4)â Å] from two ligands and four water mol-ecules. Inter-molecular O-Hâ¯O and O-Hâ¯N hydrogen bonds build up a three-dimensional supra-molecular structure.