Applicability of photovoltaic panel rainwater harvesting system in improving water-energy-food nexus performance in semi-arid areas.

Growing food demand challenges the expansion of agriculture, while water and energy shortages have seriously jeopardized agricultural sustainability. Therefore, the water-energy-food (WEF) nexus must be integrated into sustainable agriculture management. However, despite the increasing sophistication of models for WEF optimization, more studies have considered only how to reduce resource consumption and less on how to increase resource supply. This paper outlines an agricultural WEF optimization model based on photovoltaic panel rainwater harvesting (PVRH). The model innovatively incorporates the PVRH system into the agricultural WEF nexus, providing a decision-making framework that exploits and conserves resources in parallel, while contributing to economic benefits. The model was applied in a rural case study in a semi-arid region of China. The results highlight the significant potential of the PVRH system to exploit water and energy, and the increased resources are allocated to irrigated alfalfa and vegetables, which would significantly increase revenue. However, the model does not recommend large-scale vegetable cultivation, which would increase water and energy consumption and reduce the WEF indicator values indicating agricultural sustainability. The final scheme will build a 98.92MWp PV power station, develop 1.31 × 108 kW·h of electricity and 1.97 × 107 m3 of rainwater into agricultural production. And through cropping restructuring, it will increase 23.61 % of economic revenue and save 57.74 % of water and 3.24 % of energy. In general, the model framework is transferable and applicable to similar agricultural areas under semi-arid climatic conditions.

Revealing the Role of Donor/Acceptor Interfaces in Nonfullerene-Acceptor Based Organic Solar Cells: Charge Separation versus Recombination.

Organic solar cells (OSCs) based on nonfullerene-acceptors (NFAs) have achieved rapid development, while the role of donor/acceptor (D/A) interfaces in NFA based heterosystems has not been fully addressed. Here, we clarify that the photoinduced spontaneous charge separation efficiency in typical NFA heterosystems can reach up to 67%, and the charge separation efficiency contributed by the D/A interface is only 25%. The more important role of D/A interfaces is reducing the charge recombination rate, especially optimizing the competition between radiative and nonradiative charge recombination, thus reducing the nonradiative voltage loss. Systematical simulations demonstrate that there exists an optimal interfacial distance for a fixed energy offset, at which the D/A interface can reduce the nonradiative voltage loss by a maximum value of 0.12 V. Hence, we propose that optimizing the interfacial distance combined with the actual interfacial energy offset of a given heterosystem is important to develop its best photovoltaic performance.

An all-organic conditioning method to achieve deep dewatering of waste activated sludge and the underlying mechanism.

Among the common treatment/disposal routes of excessive activated sludge from municipal wastewater treatment plant, dewatering process functions as an essential pre-/post-treatment for volume minimization and transportation facilitation. Since inorganic coagulants have long been criticized for their high dosage and solid residue in sludge cake, there is an urgent need for investigations regarding the potential of applying organic chemicals as the conditioner. In this study, combined use of poly dimethyldiallylammonium chloride (PDMD) and tannic acid (TA) were investigated as an all-organic co-conditioning method for sewage sludge pre-treatment. Results showed that this all-organic conditioning strategy can effectively improve the dewaterability of sewage sludge. The capillary suction time reduced from 128.8 s to 23.1 s, and the filtration resistance reduced from 1.24 × 1012 cm/g to 7.38 × 1010 cm/g. The moisture content of dewatered sludge cake decreased to as low as 55.83%, showing the highest dewatering efficiency reported so far. In addition, the combination of PDMD and TA maximized the treating efficiency with very limited consumption of conditioners (added up to 4% of total solid). Based on the physic-chemical and rheological property investigation, it was proposed that the intermediate molecular weight polymer-based flocculation process and the TA agent-based protein precipitation process, could remarkably strengthen the compactness and structure robustness of sludge. In all, this PDMD-TA-based conditioning method suggested practical significance in consideration of its cost-effectiveness and disposal convenience of sludge cake.

Tryptophan carbon dots and their ability to cross the blood-brain barrier.

Drug traversal across the blood-brain barrier has come under increasing scrutiny recently, particularly concerning the treatment of sicknesses, such as brain cancer and Alzheimer's disease. Most therapies and medicines are limited due to their inability to cross this barrier, reducing treatment options for maladies affecting the brain. Carbon dots show promise as drug carriers, but they experience the same limitations regarding crossing the blood-brain barrier as many small molecules do. If carbon dots can be prepared from a precursor that can cross the blood-brain barrier, there is a chance that the remaining original precursor molecule can attach to the carbon dot surface and lead the system into the brain. Herein, tryptophan carbon dots were synthesized with the strategy of using tryptophan as an amino acid for crossing the blood-brain barrier via LAT1 transporter-mediated endocytosis. Two types of carbon dots were synthesized using tryptophan and two different nitrogen dopants: urea and 1,2-ethylenediamine. Carbon dots made using these precursors show excitation wavelength-dependent emission, low toxicity, and have been observed inside the central nervous system of zebrafish (Danio rerio). The proposed mechanism for these carbon dots abilities to cross the blood-brain barrier concerns residual tryptophan molecules which attach to the carbon dots surface, enabling them to be recognized by the LAT1 transporter. The role of carbon dots for transport open promising avenues for drug delivery and imaging in the brain.

Monitoring interfacial lectin binding with nanomolar sensitivity using a plasmon field effect transistor.

By immobilizing glycopolymers onto the surface of the recently developed plasmonic field effect transistor (FET), the recognition between lectins and surface-immobilized glycopolymers can be detected over a wide dynamic range (10-10 to 10-4 M) in an environment that resembles the glycocalyx. The binding to the sensor surface by various lectins was tested, and the selectivities and relative binding affinity trends observed in solution were maintained on the sensor surface, and the significantly higher avidities are attributed to cluster-glycoside effects that occur on the surface. The combination of polymer surface chemistry and optoelectronic output in this device architecture produces amongst the highest reported detection sensitivity for ConA. This work demonstrates the benefits that arise from combining emerging device architectures and soft-matter systems to create cutting edge nanotechnologies that lend themselves to fundamental biological studies and integration into point-of-use diagnostics and sensors.

Carbohydrate nanotechnology: hierarchical assembly using nature's other information carrying biopolymers.

Despite their central role in directing some of the most complex biological processes, carbohydrates--nature's other information carrying biopolymer--have been largely ignored as building blocks for synthetic hierarchical assemblies. The non-stoichiometric binding and astronomical diversity characteristic of carbohydrates could lead to tantalizingly complex assembly algorithms, but these attributes simultaneously increase the difficulty of preparing carbohydrate assemblies and anticipating their behavior. Convergences in biotechnology, nanotechnology, polymer chemistry, surface science, and supramolecular chemistry have led to many recent important breakthroughs in glycan microarrays and synthetic carbohydrate receptors, where the idiosyncrasies of carbohydrate structure and binding are increasingly considered. We hope to inspire more researchers to consider carbohydrate structure, diversity, and binding as attractive tools for constructing synthetic hierarchical assemblies.

Strong and selective adsorption of lysozyme on graphene oxide.

Biosensing methods and devices using graphene oxide (GO) have recently been explored for detection and quantification of specific biomolecules from body fluid samples, such as saliva, milk, urine, and serum. For a practical diagnostics application, any sensing system must show an absence of nonselective detection of abundant proteins in the fluid matrix. Because lysozyme is an abundant protein in these body fluids (e.g., around 21.4 and 7 µg/mL of lysozyme is found in human milk and saliva from healthy individuals, and more than 15 or even 100 µg/mL in patients suffering from leukemia, renal disease, and sarcoidosis), it may interfere with detections and quantification if it has strong interaction with GO. Therefore, one fundamental question that needs to be addressed before any development of GO based diagnostics method is how GO interacts with lysozyme. In this study, GO has demonstrated a strong interaction with lysozyme. This interaction is so strong that we are able to subsequently eliminate and separate lysozyme from aqueous solution onto the surface of GO. Furthermore, the strong electrostatic interaction also renders the selective adsorption of lysozyme on GO from a mixture of binary and ternary proteins. This selectivity is confirmed by sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE), fluorescence spectroscopy, and UV-vis absorption spectroscopy.