ABSTRACT
ABSTRACT: This study investigated the concentration of the pesticide residues found in Fragaria and Myrica rubra sold in the city of Hangzhou, People's Republic of China. From an analysis of 151 (77 Fragaria and 74 M. rubra) samples using gas chromatography-tandem mass spectrometry (GC-MS/MS) and liquid chromatography-tandem mass spectrometry (LC-MS/MS), 41 pesticide residues were found to be present. Of the 41 residues, 14 were found using GC-MS/MS and 27 were found using LC-MS/MS. Of the 151 samples, 10 (13.0%) of the 77 Fragaria samples and 5 (6.8%) of the 74 M. rubra samples were found to contain a specific pesticide residue, and only 4 Fragaria samples and 2 M. rubra samples were found to be without pesticide residue. In addition, 18 of the 41 pesticides were not detected in either Fragaria or M. rubra samples. Of the 41 residues, 10 were detected in Fragaria samples and 20 were detected in M. rubra samples. In Fragaria, procymidone was the most commonly detected residue, with a detection rate of 88.3%, followed by prochloraz, with a detection rate of 53.2%. In M. rubra, prochloraz was the most commonly detected residue, with a detection rate of 71.6%, followed by carbendazim, with a detection rate of 68.9%. The pesticide residues in some samples exceeded the maximum residue limit set in China. The limit of dimethomorph was exceeded in three of the Fragaria samples, and that of dichlorvos was exceeded in two of the M. rubra samples.
Subject(s)
Fragaria , Myrica , Pesticide Residues , Chromatography, Liquid/methods , Food Contamination/analysis , Humans , Pesticide Residues/analysis , Tandem Mass Spectrometry/methodsABSTRACT
The effect of L-proline as a promoter on the condensation reaction of salicylaldehyde or its derivatives with ethyl acetoacetate in neutral ionic liquid [emim]BF4 was studied. All reactions were carried out under mild reaction conditions and achieved high yields. Moreover, the ionic liquid containing L-proline could be recycled and reused for several times without noticeably decreasing in productivity. The results show that the L-proline-[emim]BF4 system has a potential in contribution to the development of environmentally friendly and inexpensive processes in organic syntheses.
Subject(s)
Coumarins , Ionic Liquids , Chemistry , Proline , ChemistryABSTRACT
The binding of pefloxacin mesylate (PFLX) to bovine lactoferrin (BLf) and human serum albumin (HSA) in dilute aqueous solution was studied using fluorescence spectra and absorbance spectra. The binding constant K and the binding sites n were obtained by fluorescence quenching method. The binding distance r and energy-transfer efficiency E between pefloxacin mesylate and bovine lactoferrin as well as human serum albumin were also obtained according to the mechanism of Förster-type dipole-dipole nonradiative energy-transfer. The effects of pefloxacin mesylate on the conformations of bovine lactoferrin and human serum albumin were also analyzed using synchronous fluorescence spectroscopy.
