ABSTRACT
The ambient concentration of ozone is high in Qingdao, and ozone pollution episodes occur frequently in summer. The refined source apportionment of ambient volatile organic compounds (VOCs) and their ozone formation potential (OFP) during ozone pollution episodes and non-ozone pollution periods can play an important role in effectively reducing air ozone pollution in coastal cities and continuously improving ambient air quality. Therefore, this study applied the online VOCs monitoring data with hourly resolution in summer (from June to August) in 2020 in Qingdao to analyze the chemical characteristics of ambient VOCs during the ozone pollution episodes and non-ozone pollution periods and conducted the refined source apportionment of ambient VOCs and their OFP using a positive matrix factorization (PMF) model. The results showed that the average mass concentration of ambient VOCs in Qingdao in summer was 93.8 µg·m-3, and compared with that during the non-ozone pollution period, the mass concentration of ambient VOCs during the ozone pollution episodes increased by 49.3%, and the mass concentration of aromatic hydrocarbons increased by 59.7%. The total OFP of ambient VOCs in summer was 246.3 µg·m-3. Compared with that in the non-ozone pollution period, the total OFP of ambient VOCs in the ozone pollution episodes increased by 43.1%; that of alkanes increased the most, reaching 58.8%. M-ethyltoluene and 2,3-dimethylpentane were the species with the largest increase in OFP and its proportion during the ozone pollution episodes. The main contributors of ambient VOCs in Qingdao in summer were diesel vehicles (11.2%), solvent use (4.7%), liquefied petroleum gas and natural gas (LPG/NG) (27.5%), gasoline vehicles (8.9%), gasoline volatilization (26.6%), emissions of combustion- and petrochemical-related enterprises (16.4%), and plant emissions (4.8%). Compared with that in the non-ozone pollution period, the contribution concentration of LPG/NG in the ozone pollution episodes increased by 16.4 µg·m-3, which was the source category with the largest increase. The contribution concentration of plant emissions increased by 88.6% in the ozone pollution episodes, which was the source category with the highest increase rate. In addition, emissions from combustion- and petrochemical-related enterprises were the largest contributor to the OFP of ambient VOCs in summer in Qingdao, with its OFP and contribution proportion being 38.0 µg·m-3and 24.5%, respectively, followed by that of LPG/NG and gasoline volatilization. Compared with the non-ozone pollution period, the total contributions of LPG/NG, gasoline volatilization, and solvent use to the increase in OFP for ambient VOCs in the ozone pollution episodes were 74.1%, which were the main contribution source categories.
ABSTRACT
Manipulation of underwater bubbles is of great importance in both scientific research and industrial applications. In this work, the motion of underwater bubbles on a microholed polydimethylsiloxane (PDMS) surface with gradient wettability is studied using a high-speed camera. It was found that underwater bubbles self-transported directionally from the smaller area fraction (SAF) to the larger area fraction (LAF) of the surface. Besides, the bubble motion was triggered by an effective depth range from hcr,min to hcr,max. Only the depth of the bubble was within the range when the self-transport motion occurred. Otherwise the bubble would adhere onto the surface eventually. The main cause for the motion is the trapped air inside the microholes, which generates the torque Tb and the retention force Fr driving the bubble directionally. The mathematical model is established to reveal the motion mechanism, which is verified by the experimental results. The outcomes of our work shed new light on the target transportation fields such as drug delivery and submarine gas collection.
ABSTRACT
Two pairs primers were designed base on the known sequence for amplification of FGF5 gene in the Inner Mongolian cashmere goats herd. It was found that a restrict fragment length polymorphism within the exon 1 of FGF5 gene from the second pair of primers using PCR-SSCP and PCR-RFLP. PCR products after recovered and purified, were sequenced that randomly selected from different genotypes. It was revealed a synonymous single base mutation (C-->T) for the AB genotype. The allele A was found to be predominant in Inner Mongolian cashmere goats and the allele and genotype frequencies in our sample coincident with the Hardy-Weinberg equilibrium. When analyzed for the association with fibre traits, this FGF5 SNP was found to have significant effect on cashmere fibre stretched length (P<0.01) and cashmere rate(P<0.05), but have slightly effect on others fibre traits (P>0.05). Cashmere fibre stretched length (P<0.01) and cashmere rate (P<0.05) in individuals of genotype AB was significantly higher than that in individuals of genotype AA.
