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1.
Environ Res ; 255: 119110, 2024 Aug 15.
Article in English | MEDLINE | ID: mdl-38723992

ABSTRACT

Landfills require effective containment systems to prevent the leakage of leachate into the underground environment. Cutoff walls are commonly employed for this purpose, with options including rigid and flexible designs. In areas where structural strength is not a primary concern, flexible cutoff walls offer lower permeability and environmental benefits due to their lack of cement content, thereby reducing CO2 emissions. This study investigates the use of dredged sediment and attapulgite as materials for flexible cutoff walls. Through analyses of bound water content, free water content, hydraulic conductivity, and scanning electron microscopy, we explore the impact of confining pressures on cutoff wall permeability. Our findings reveal that the consolidation induced by confining pressure does not significantly alter the bound water content within the cutoff wall. Instead, changes in water content are predominantly attributed to variations in free water content. Under identical confining pressures, we observe a positive correlation between permeability and hydraulic gradient, with permeability increasing as the hydraulic gradient rises, and anti-permeability decreasing accordingly. Additionally, when holding the hydraulic gradient constant, increasing confining pressure leads to a continuous decrease in permeability. Microscopic analyses highlight that high confining pressure not only compresses pore diameter but also alters pore morphology, thereby influencing permeability. This study contributes to the understanding of cutoff wall behavior under different conditions. Our results demonstrate that increasing confining pressure during soil consolidation effectively reduces cutoff wall permeability to meet design standards. However, the influence of high leachate head on permeability should also be considered. These findings provide a more environmentally friendly and lower permeability option for landfill sites, which is significant for the design and enhancement of containment systems in landfill sites.


Subject(s)
Geologic Sediments , Pressure , Waste Disposal Facilities , Geologic Sediments/chemistry , Geologic Sediments/analysis , Permeability , Magnesium/analysis , Magnesium/chemistry , Microscopy, Electron, Scanning , Magnesium Compounds , Silicon Compounds
2.
Environ Res ; 252(Pt 2): 118895, 2024 Jul 01.
Article in English | MEDLINE | ID: mdl-38604483

ABSTRACT

Landfill gases can have numerous detrimental effects on the global climate and urban ecological environment. The protective efficacy of the final cover layer against landfill gases, following exposure to periodic natural meteorological changes during long-term service, remains unclear. This study conducted centrifuge tests and gas permeability tests on compacted loess. The experiments examined the impact and relationship of wetting-drying cycles and dry density on the soil water characteristic curve (SWCC) and gas permeability of compacted loess. Research findings reveal that during the dehumidification process of compacted loess, the gas permeability increases non-linearly, varying the gas permeability of soil with different densities to different extents under wetting-drying cycles. Two models were introduced to describe the impact of wetting-drying cycles on gas permeability of loess with various dry densities, where fitting parameters increased with the number of wetting-drying cycles. Sensitivity analysis of the parameters in the Parker-Van Genuchten-Mualem (P-VG-M) model suggests that parameter γ's accuracy should be ensured in practical applications. Finally, from a microstructural perspective, wetting-drying cycles cause dispersed clay and other binding materials coalesce to fill minuscule pores, leading to an increase in the effective pores responsible for the gas permeability of the soil. These research results offer valuable guidance for designing water retention and gas permeability in compacted loess cover layers under wetting-drying cycles.


Subject(s)
Permeability , Soil , Soil/chemistry , Water/chemistry , Wettability , Refuse Disposal/methods , Gases , Desiccation/methods , Air Pollutants/analysis
3.
J Environ Manage ; 348: 119405, 2023 Dec 15.
Article in English | MEDLINE | ID: mdl-37924693

ABSTRACT

municipal solid waste incineration (MSWI) fly ash partially replaces cement to solidify sediment, and then can be used as intermediate cover materials in landfill as one of the resources utilization ways of MSWI fly ash and sediment. The strength and the semi-dynamic leaching characteristics of MSWI fly ash solidified sediment under hydrochloric acid attack at different pH were studied by means of unconfined compressive strength (UCS), semi-dynamic leaching, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and Thermogravimetric analysis (TGA). Results revealed that the UCS strength increased as the curing age and cement content increased. When the curing content is 50% and the replacement ratio of MSWI fly ash is 75% and 80%, the UCS of 7 d can be greater than 50 kPa. The primary contribution to the strength development was from silicic acid gels such as calcium silicate hydrate (C-S-H) and carbonates. Notably, the leaching behavior of Zn and Cu within the solidified sediment underwent substantial alterations. The leaching amount of heavy metals in a strong acidic environment (pH = 2) is significantly greater than that in a weak acidic (pH = 4) and neutral (pH = 7) environment. Conversely, minimal disparities were observed in the leaching characteristics of Zn and Cu between the weakly acidic and neutral environments. Ca(OH)2, C-S-H and carbonate exhibits a remarkable acid-resistant buffering capacity in the solidified sediment. The obvious diffusion coefficient (Dobs) was less than 10-9 m2/s in semi-dynamic leaching tests. Moreover, the mobility of Zn and Cu surpassing 12.5, coupled with a leaching index exceeding 8, further attests to the favorable S/S outcome achieved. Based on these findings, the solidified material is confidently recommended to be used as suitable landfill middle soil cover material.


Subject(s)
Metals, Heavy , Refuse Disposal , Coal Ash/chemistry , Incineration , Solid Waste/analysis , Particulate Matter , Carbon/chemistry , Metals, Heavy/analysis
4.
Environ Sci Pollut Res Int ; 28(30): 40053-40059, 2021 Aug.
Article in English | MEDLINE | ID: mdl-32198684

ABSTRACT

Extensive attention has been paid to the treatment and disposal of dredged material, and there is a need to clarify the feasibility of recycling dredged material by using it as backfill in soil-bentonite vertical cutoff walls. By setting the dredged material in the Baimao storage yard of Meiliang Bay in Taihu Lake and bentonite as the research objects, this paper studied the influences of bentonite content, confining pressure and pore size distribution on the permeability of dredged material-bentonite backfills. According to the test results, from the perspective of medium-term and short-term permeability, it is feasible to recycle dredged material by using it as backfill in a vertical cutoff wall. The permeability of the dredged material-bentonite soil mixture decreases with increasing bentonite content, but the degree of decrease is not significant. At the same time, the higher the confining pressure is, the smaller the variation in hydraulic conductivity with bentonite content. The permeability of the soil mixture decreases with increasing confining pressure, and the range of reduction is within a certain order of magnitude. Moreover, the confining pressure has a similar impact on the decrease in the permeability of the soil mixtures with different bentonite contents. The hydraulic conductivity of the dredged material-bentonite mixture decreases because the addition of bentonite changes the pore size distribution and reduces the porosity and characteristic pore size D50 of the soil mixture.


Subject(s)
Bentonite , Soil , Lakes , Permeability , Porosity
5.
J Environ Manage ; 237: 155-162, 2019 May 01.
Article in English | MEDLINE | ID: mdl-30784863

ABSTRACT

Leachate contains composite contaminants, and the chemical compatibility of soil-bentonite cut-off walls is unclear. To better understand the issue, Fujian standard sand is used to represent a sandy soil stratum. Two clays were used as additive to examine the chemical compatibility of the soil-bentonite model backfills under the condition of composite contaminants. The results indicate that there is a representative cation when the backfills are permeated with NaCl, CaCl2, and ZnCl2 solutions and an NaCl-CaCl2-ZnCl2 mixed solution of the same ionic strength. Ca2+ has the highest maximum ionic strength among all cations from leachates. Moreover, the change in hydraulic conductivity, bound water content and effective porosity of sand-bentonite with the Ca2+ concentration or chemical oxygen demand (COD) exhibit a concentration threshold; i.e., when the concentration is smaller than the threshold, the hydraulic conductivity and effective porosity significantly increase, whereas the bound water content rapidly decreases; when the concentration is higher than the threshold, the hydraulic conductivity, bound water content and effective porosity tend to stabilize. In addition, under the condition of composite contaminants, the threshold is observed, while the hydraulic conductivity, bound water content and effective porosity vary with the COD. Thus, both the type and concentration of chemicals can change the effective porosity and affect hydraulic conductivity. Furthermore, there is a power function relationship between permeability and the effective pore.


Subject(s)
Bentonite , Soil , Porosity , Waste Disposal Facilities , Water
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