Multifunctional Interlayer Engineering for Silkworm Excrement-Derived Porous Carbon Enabling High-Energy Lithium Sulfur Batteries.

Lithium-sulfur (Li-S) batteries show advantage of high theoretical capacity. However, the shuttle effect of polysulfides and sluggish sulfur redox kinetics seriously reduce their service life. Inspired by the porous structural features of biomass materials, herein, a functional interlayer is fabricated by silkworm excrement-derived three-dimensional porous carbon accommodating nano sized CoS2 particles (SC@CoS2 ). The porous carbon delivers a high specific surface area, which provides adequate adsorption sites, being responsible for suppressing the shuttle effect of polysulfides. Meanwhile, the porous carbon is favorable for hindering the aggregation of CoS2 and maintaining its high activity during extended cycles, which effectively accelerates the polysulfides conversion kinetics. Moreover, the SC@CoS2 functional interlayer effectively limits the formation of Li dendrites and promotes the uniform deposition of Li on the Li electrode surface. As a result, the CMK-3/S cathode achieves a high initial capacity of 1599.1 mAh g-1 at 0.2 C rate assisted by the polypropylene separator coated with the functional interlayer and 1208.3 mAh g-1 is maintained after the long cycling test. This work provides an insight into the designing of long-lasting catalysts for stable functional interlayer, which encourages the application of biomass-derived porous carbon in high-energy Li-S batteries.

Emerging disposal technologies of harmful phytoextraction biomass (HPB) containing heavy metals: A review.

Phytoextraction is an effective approach for remediation of heavy metal (HM) contaminated soil. After the enhancement of phytoextraction efficiency has been systematically investigated and illustrated, the harmless disposal and value-added use of harmful phytoextraction biomass (HPB) become the major issue to be addressed. Therefore, in recent years, a large number of studies have focused on the disposal technologies for HPB, such as composting, enzyme hydrolysis, hydrothermal conversion, phyto-mining, and pyrolysis. The present review introduces their operation process, reaction parameters, economic/ecological advantages, and especially the migration and transformation behavior of HMs/biomass. Since plenty of plants possess comparable extraction abilities for HMs but with discrepancy constitution of biomass, the phytoextraction process should be combined with the disposal of HPB after harvested in the future, and thus a grading handling strategy for HPB is also presented. Hence, this review is significative for disposing of HPB and popularizing phytoextraction technologies.