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1.
J Am Soc Mass Spectrom ; 7(1): 118-22, 1996 Jan.
Article in English | MEDLINE | ID: mdl-24202803

ABSTRACT

A pulsed-leak valve that allows the introduction of a prolonged, flat, and controllable pulse of gas is described. Test results from the valve that utilized a Fourier transform ion cyclotron resonance mass spectrometer with Ar and C2H6 as the sample gases indicate that the valve functions as expected and yields basically rectangular pressure profiles in the cell region. The rise and fall times are similar to those of just the stand-alone pulsed valve and are believed to be determined mainly by the design of the vacuum system, rather than the design of the pulsed-leak valve. Kinetic data for the reaction of Nb(+) with C2H6, acquired with the use of the pulsed-leak valve to introduce the C2H6 gas, demonstrates the practical application of this valve for kinetic and other analogous studies. Use of the pulsed-leak valve greatly reduces the loss of the reactant ion signal during the cooling period.

2.
J Am Soc Mass Spectrom ; 6(6): 521-4, 1995 Jun.
Article in English | MEDLINE | ID: mdl-24214306

ABSTRACT

A study of the addition of Cu(II) to a ubiquitin electrospray solution shows that the copper ion in the ubiquitin remains doubly charged and displaces two protons on the protonated protein molecule. This observation indicates a chelating bond between the protein and the Cu(II) species. The addition of Cu(I) also was studied and significant intensity was observed for adducts with up to four Cu(I) species attached, with each Cu(I) bonded to one basic site on the protein.

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