A Layer-by-Layer Self-Assembled Bio-Macromolecule Film for Stable Zinc Anode.

Side reactions on zinc metal (Zn) anodes are formidable issues that cause limited battery life of aqueous zinc-ion batteries (AZIBs). Here, a facile and controllable layer-by-layer (LbL) self-assembly technique is deployed to construct an ion-conductive and mechanically robust electrolyte/anode interface for stabilizing the Zn anode. The LbL film consists of two natural and biodegradable bio-macromolecules, chitosan (CS) and sodium alginate (SA). It is shown that such an LbL film tailors the solvation sheath of Zn ions and facilitates the oriented deposition of Zn. Symmetric cells with the four double layers of CS/SA ((CS/SA)4 -Zn) exhibit stable cycles for over 6500 h. The (CS/SA)4 -Zn||H2 V3 O8 coin cell maintains a specific capacity of 125.5 mAh g-1 after 14 000 cycles. The pouch cell with an electrode area of 5 × 7 cm2 also presents a capacity retention of 83% for over 500 cycles at 0.1 A g-1 . No obvious dendrites are observed after long cycles in both symmetric and full cells. Given the cost-effective material and fabrication, and environmental friendliness of the LbL films, this Zn protection strategy may boost the industrial application of AZIBs.

A Molecular-Sieve Electrolyte Membrane enables Separator-Free Zinc Batteries with Ultralong Cycle Life.

The poor stability of the zinc-metal anode is a main bottleneck for practical application of aqueous zinc-ion batteries. Herein, a series of molecular sieves with various channel sizes are investigated as an electrolyte host to regulate the ionic environment of Zn2+ on the surface of the zinc anode and to realize separator-free batteries. Based on the ZSM-5 molecular sieve, a solid-liquid mixed electrolyte membrane is constructed to uniformize the transport of zinc ions and foster dendrite-free Zn deposition. Side reactions can also be suppressed through tailoring the solvation sheath and restraining the activity of water molecules in electrolyte. A V2 O5 ||ZSM-5||Zn full cell shows significantly enhanced performance compared to cells using glass fiber separator. Specifically, it exhibits a high specific capacity of 300 mAh g-1 , and a capacity retention of 98.67% after 1000 cycles and 82.67% after 3000 cycles at 1 A g-1 . It is attested that zeolites (ZSM-5, H-ß, and Bate) with channel sizes of 5-7 Å result in best cycle stability. Given the low cost and recyclability of the ZSM and its potent function, this work may further lower the cost and boost the industrial application of AZIBs.

Modulation of laser damage by temporal shaping of double picosecond pulses.

We propose a temporally shaped double-picosecond-pulse train at a sub-nanosecond scale to control the damage dynamics of optical glass. Both damage threshold and morphology are significantly modulated by pulse-train shaping. The ramp-up-shaped train effectively increases its damage threshold and decreases the damage density and size, which clearly shows that a pump pulse with optimized fluence has a strong positive modification of damage precursors. Furthermore, the temporal evolution of damage modulation is experimentally revealed by varying the interval of pump-probe pulses, and after pump exposure with optimized fluence, enhancement of the probe threshold reaches the maximum at a delay of about 260 ps.

Defect edge steepness dependence of multiple nonlinear hot-image formation from a single phase defect.

Nonlinear hot image is one of the key elements that limit the output performance of high-power laser systems. In most hot-image researches, only one hot image peak is observed in the conjugate position for a single defect. Generally, multiple hot image peaks occur for multiple defects or cascaded nonlinear media. However, a new phenomenon is found by numerical simulation in our work: one defect can also afford two hot-image peaks near the conjugate position when considering the defect edge steepness. The super-Gaussian defect model is employed to mimic the defect edge steepness. When the super-Gaussian order is higher than one, there could be two hot image peaks under certain conditions. The formation of the double hot image peaks is primarily due to the co-effect of the hard-edge diffraction and the self-focusing effect. The influence of different factors, including the super-Gaussian order, defect size, modulation depth, and Kerr medium thickness, on the double hot image peaks intensity and location is systematically investigated. The results show that with the increase in the super-Gaussian order, the intensity of the double hot image peaks increases gradually. The defect size has a great influence on the position of the two hot image peaks. The modulation depth and thickness of the Kerr medium influence the intensity of the two hot image peaks; however, they have less impact on the peak location. Importantly, the defect edge steepness and size dependences of multiple nonlinear hot-image formation from a single-phase defect are further discussed in this paper. The two hot image peaks are fatal to optical components in high-power laser systems; in particular, the hot image peak behind the conjugate position is totally unexpected for a single defect. This research provides insights into basic physical images and hot-image formation laws. It also provides important guidance for optical defect specification evaluation and optical component layout design, as well as for beam quality control, in high-power laser systems.

Phase defect detection of large-aperture optics with static multiplanar coherent diffraction imaging.

Phase defect detection with micrometer scale on large aperture optical elements is one of the challenges in precision optical systems. An efficient scheme is proposed to detect phase defects. First, the defects are positioned in a large aperture by dark-field imaging based on large aperture photon sieves to improve the detection efficiency with a relatively low cost. Second, static multiplanar coherent diffraction imaging is used to retrieve the phase of the positioned defects in a small field of view. Here, a spatial light modulator is used as a multifocal negative lens to eliminate the mechanical errors in multiplanar imaging. The use of a negative lens instead of a positive lens has the advantage of a larger imaging space for the system configuration. Compared to the traditional interferometry system, this diffraction detection system has a simpler optical path and doesn't require sparse distribution of the defects. Experiment results demonstrate the success of the proposed scheme with a detection resolution better than 50 µm. We believe this work provides an effective method to rapidly detect phase defects on large aperture optics with high accuracy and high resolution.

Determination of the damage growth threshold of multilayer dielectric gratings by picosecond laser pulses based on saturation damage size analysis.

We propose two efficient methods of determining damage growth threshold (DGT) based on the saturation damage size analysis (SDSA) for multilayer dielectric gratings by picosecond pulsed lasers. The damage size at laser fluences above DGT increases with the shot number and finally saturates due to the Gaussian focal spot. The DGT is extracted by mapping the boundary of a saturation damage site obtained at single fluence to the beam profile, which is called the monofluence SDSA method. Meanwhile, the saturation damage size decreases when reducing laser fluence. The fitting and extrapolation of the saturation damage sizes at different fluences are also useful to accurately determine the DGT, which is called the multifluence SDSA method. Although the saturation damage site is asymmetric, the DGTs measured with two SDSA methods are almost identical for the same axis, and both are in very good agreement with those obtained with the growth probability method. The underlying mechanisms and advantages of two SDSA methods are extensively discussed. The consistence of two SDSA methods in determining DGT is attributed to the same morphology of the initial damage and the saturation damage boundary, as well as the local damage dynamics. The relation of the lifetime damage threshold and DGT obtained with the SDSA method is also revealed.