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A highly selective 2''-O-glycosyltransferase from Ziziphus jujuba and De novo biosynthesis of isovitexin 2''-O-glucoside.
Zhang, Ya-Qun; Wang, Zi-Long; Chen, Zhuo; Jin, Zheng-Tong; Hasan, Aobulikasimu; Wang, Hai-Dong; Sun, Yu-Wei; Qiao, Xue; Wang, Yong; Ye, Min.
Chem Commun (Camb) ; 58(15): 2472-2475, 2022 Feb 17.
Article in English | MEDLINE | ID: mdl-35084410

ABSTRACT

A novel and efficient 2''-O-glycosyltransferase ZjOGT38 was identified from Ziziphus jujuba. It could regio-selectively glycosylate 2-hydroxyflavanone C-glycosides. ZjOGT38 allowed de novo biosynthesis of isovitexin 2''-O-glucoside in E. coli.


Subject(s)
Glucosides/biosynthesis , Glycosyltransferases/metabolism , Isoflavones/biosynthesis , Ziziphus/enzymology , Glucosides/chemistry , Isoflavones/chemistry , Molecular Structure
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