ABSTRACT
<p><b>OBJECTIVE</b>To investigate the chemical constituents from the leaves of Vaccinium bracteatum.</p><p><b>METHOD</b>Many column chromatographic techniques were used for the isolation and separation of chemical constituents. Their structures were elucidated on the basis of spectral analysis and chemical evidences.</p><p><b>RESULT</b>Twelve compounds were isolated from the plant, and they were identified as chrysoeriol (1), scopoletin (2), trans-p-hydroxycinnamic acid (3), trans-p-hydroxycinnamic acid ethyl ester (4), cafeic acid ethyl ester (5), beta-sitosterol (6), iuteolin (7), quercetin (8), esculetin (9), cafeic acid (10), isolariciresinol-9-O-beta-D-xyloside (11), 10-O-trans-p-coumaroylsandoside (12).</p><p><b>CONCLUSION</b>Compounds 4, 5, 11, 12 were isolated from the genus Vaccinium for the first time, and compounds 1, 2, 9, 10 were isolated from this plant for the first time.</p>
Subject(s)
Coumaric Acids , Chemistry , Flavones , Flavonoids , Chemistry , Furans , Chemistry , Glycosides , Chemistry , Lignin , Chemistry , Molecular Structure , Plant Leaves , Chemistry , Scopoletin , Chemistry , Sitosterols , Chemistry , Umbelliferones , Chemistry , Vaccinium , ChemistryABSTRACT
<p><b>OBJECTIVE</b>To study the chemical constituents from roots of Platycodon grandiflorum.</p><p><b>METHOD</b>Column chromatography (silica gel, macroporous resin, sephadex LH - 20 and the preparative RP - HPLC were used to isolate the constituents. Their structures were elucidated by physical and spectral data.</p><p><b>RESULT</b>Eight compounds were isolated and identified as tangeritin (1), 3-O-beta-D-glucopyranosylplatycodigenin methyl ester (2), 3-O-beta-D-glucopyranosylplaticogenic acid A lactone (3), 3-O-beta-D-glucopyranosylplatycodigenin (4), deapio-platyconic acid A lactone (5), deapio-platycodin-D (6), platycoside-G1 (7) and platycoside-E (8).</p><p><b>CONCLUSION</b>Compounds 1,3 and 5 were isolated from this plant for the first time.</p>
Subject(s)
Flavones , Chemistry , Lactones , Chemistry , Oleanolic Acid , Chemistry , Plant Extracts , Chemistry , Plant Roots , Chemistry , Plants, Medicinal , Chemistry , Platycodon , Chemistry , Saponins , ChemistryABSTRACT
<p><b>AIM</b>To study the triterpenoid saponins in the whole plant of Lysimachia davurica Ledeb.</p><p><b>METHODS</b>Column chromatography (including AB-8 macroporous resin, silica gel and ODS) was used to separate triterpenoid saponins whose structures were elucidated by ESI-MS, NMR (1D and 2D) and hydrolysis methods.</p><p><b>RESULTS</b>Two new triterpenoid saponins were isolated and established as 3beta, 16alpha, 28-trihydroxy-olean-12-en-3-0-(beta-D-glucopyranosyl-(1 --> 2)-beta-D-glucuronopyranosyl)-28-0-beta-D-glucopyranoside) (I), 3beta, 16alpha, 28-trihydroxy-olean-12-en-3-O-(beta-D-glucopyranosyl-(1 --> 2)-beta-D-glucuronopyranosyl)-28-0-beta-D-glucopyranoside) (II).</p><p><b>CONCLUSION</b>Compounds I and II are new compounds and named as davuricosides D and J.</p>
Subject(s)
Molecular Conformation , Molecular Structure , Plants, Medicinal , Chemistry , Primulaceae , Chemistry , Saponins , Chemistry , Triterpenes , ChemistryABSTRACT
<p><b>AIM</b>To study the triterpenoid saponins in the whole plants of Lysimachia capillipes Hemsl..</p><p><b>METHODS</b>Column chromatography (including AB-8 macroporous resin, silica gel and ODS) was used to separate triterpenoid saponins whose structures were elucidated by ESI-MS, NMR (1D and 2D) and hydrolysis methods.</p><p><b>RESULTS</b>Two new triterpenoid saponins were isolated and established as 3beta, 22alpha-dihydroxy-16alpha-angeloyloxy-28-->13-lactone-oleanane-3-O-[beta-D-glucopyranosyl-(1-->2)-alpha-L-arabinpyranosyl]-22-O-(6-acetyl)-beta-D-glucopyranoside (I), 3beta, 13beta, 22alpha-trihydroxy-16alpha-acetyloxyoleanane-28-oic acid Na-3-O-[beta-D-glucopyranosyl-(1-->2)-alpha-L-arabinpyranosyl]-22-O-beta-D-glucopyranoside (II).</p><p><b>CONCLUSION</b>Compounds I and II are new compounds and named as capilliposide I and capilliposide J.</p>
Subject(s)
Flavonoids , Chemistry , Molecular Conformation , Molecular Structure , Plants, Medicinal , Chemistry , Primulaceae , Chemistry , Triterpenes , ChemistryABSTRACT
<p><b>OBJECTIVE</b>To study the chemical constituents from the whole plant of Lysimachia davurica.</p><p><b>METHOD</b>The constituents were separated and purified by column chromatograph, and identified by spectral analysis and physical data.</p><p><b>RESULT</b>Six compounds were isolated and identified as triacontanoic acid(I), palmitic acid(II), beta-amyrin(III), stigmasterol(IV), oleanolic acid(V), soya-cerebroside I (VI).</p><p><b>CONCLUSION</b>I, III, VI were isolated from this gene for the first time.</p>
