Urea-rich sodium alginate-based hydrogel fertilizer as a water reservoir and slow-release N carrier for tomato cultivation under different water-deficit levels.

In this study, a new eco-friendly urea-rich sodium alginate-based hydrogel with a slow-release nitrogen property was prepared, and its effectiveness was evaluated in the cultivation of tomato plants under different water stress levels. The structure and performance of the hydrogel were investigated by FTIR, XRD, TGA, DTG, and SEM. The swelling and release experiments showed that prepared urea-rich hydrogel exhibited a high-water holding capacity (412 ± 4 g/g) and showed a sustained and slow nitrogen release property. A greenhouse pot experiment was conducted using two hydrogel levels (0.1 and 0.5 wt%) under two water deficit levels (30 and 70 % based on required water irrigation). Germination tests indicated that the developed hydrogel fertilizer has no phytotoxicity and has a positive impact on the germination rate even under water deficit conditions. The application of hydrogel fertilizer at 0.5 wt% significantly (p > 0.05) enhanced plant growth parameters such as leaf number, chlorophyll content, stem diameter, and plant length compared to the control treatment. The magnitude of the responses to the hydrogel fertilizer application depended on the concentration of applied hydrogel fertilizer and stress severity with the most positive effects on the growth and yield of tomato observed at a level of 0.5 %. Tomato yield was significantly enhanced by 19.58 %-12.81 %, 18.58 %-22.02 %, and 39.38 %-43.18 % for the plant amended with hydrogel at 0.1-0.5 wt% and grown under water deficit levels of 0, 30, and 70 %, respectively, compared to the control treatment.

Fixed-bed adsorption of Pb(ii) and Cu(ii) from multi-metal aqueous systems onto cellulose-g-hydroxyapatite granules: optimization using response surface methodology.

We prepared cellulose microfibrils-g-hydroxyapatite (CMFs-g-HAPN (8%)) in a granular form. We evaluated the ability of these granules to eliminate Pb(ii) and Cu(ii) ions from aqueous solution in dynamic mode using a fixed-bed adsorption column. Several operating parameters (inlet ion concentration, feed flow rate, bed height) were optimized using response surface methodology (RSM) based on a Doehlert design. Based on ANOVA and regression analyses, adsorption was found to follow the quadratic polynomial model with p < 0.005, R2 = 0.976, and R2 = 0.990, respectively, for Pb(ii) and Cu(ii) ions. Moreover, three kinetic models (Adams-Bohart, Thomas, Yoon-Nelson) were applied to fit our experimental data. The Thomas model and Yoon-Nelson model represented appropriately the whole breakthrough curves. The Adams-Bohart model was suitable only for fitting the initial part of the same curves. Our adsorbent exhibited high selectivity towards Pb(ii) over Cu(ii) ions in the binary metal system, with a maximum predicted adsorption capacity of 59.59 ± 3.37 and 35.66 ± 1.34 mg g-1, respectively. Under optimal conditions, multi-cycle sorption-desorption experiments indicated that the prepared adsorbent could be regenerated and reused up to four successive cycles. The prepared CMFs-g-HAPN was an efficient and effective reusable adsorbent for removal of heavy metals from aqueous systems, and could be a suitable candidate for wastewater treatment on a large scale.

Efficient removal of Cu2+ and methylene blue pollutants from an aqueous solution by applying a new hybrid adsorbent based on alginate-chitosan and HAP derived from Moroccan rock phosphate.

Alginate-chitosan/hydroxyapatite (Alg-Cs/HAP) beads were prepared as adsorbent to remove methylene blue (MB) and copper ions from an aqueous solution using a batch system. FTIR, TGA, point of zero charge (pHpzc), SEM, XRD, and BET analysis were used to characterize the elaborated material. The effect of several parameters such as initial pH value, adsorbent dose, temperature, contact time, and initial pollutant concentration were also investigated. The obtained results showed that Alg-Cs/HAP exhibit excellent adsorption properties for Cu (II) and MB removal, with high adsorption capacities of copper ions (208.34 mg/g) and methylene blue (454.54 mg/g). The kinetic of the adsorption process is correlated with the pseudo-first-order for methylene blue and the pseudo-second-order for copper ions. The equilibrium data for MB dye fitted the Freundlich isotherm model, thus implying that the adsorption process consists of multilayer adsorption as well as interactions between the adsorbate and the adsorbent. The equilibrium data for copper ions corresponds closely with the Langmuir model which suggests that the adsorbed molecules occur over a monolayer. Various thermodynamic parameters such as the standard Gibbs energy (ΔG°), standard enthalpy (ΔH°), and standard entropy (ΔS°) were calculated. All results indicated that Alg-Cs/HAP material has a good potential for the treatment of wastewater.

Ultrasound-assisted degradation of organophosphorus pesticide methidathion using CuFe2O4@SiO2-GOCOOH as a magnetic separable sonocatalyst.

Water contamination by pesticides is a critical environmental issue, necessitating the development of sustainable and efficient degradation methods. This study focuses on synthesizing and evaluating a novel heterogeneous sonocatalyst for degrading pesticide methidathion. The catalyst consists of graphene oxide (GO) decorated CuFe2O4@SiO2 nanocomposites. Comprehensive characterization using various techniques confirmed the superior sonocatalytic activity of the CuFe2O4@SiO2-GOCOOH nanocomposite compared to CuFe2O4@SiO2 alone. The enhanced performance is attributed to the combined effects of GO and CuFe2O4@SiO2, including increased surface area, enhanced adsorption capabilities, and efficient electron transfer pathways. Reaction parameters such as time, temperature, concentration, and pH significantly influenced the degradation efficiency of methidathion. Longer reaction times, higher temperatures, and lower initial pesticide concentrations favored faster degradation and higher efficiency. Optimal pH conditions were identified to ensure effective degradation. Remarkably, the catalyst demonstrated excellent recyclability, indicating its potential for practical implementation in pesticide-contaminated wastewater treatment. This research contributes to the development of sustainable methods for environmental remediation, highlighting the promising potential of the graphene oxide decorated CuFe2O4@SiO2 nanocomposite as an effective heterogeneous sonocatalyst for pesticide degradation.