Electrochemical sensors modified with iron oxide nanoparticles/nanocomposites for voltammetric detection of Pb (II) in water: A review.

Permissible limits of Pb2+ in drinking water are being reduced from 10 µgL-1 to 5 µgL-1, which calls for rapid, and highly reliable detection techniques. Electrochemical sensors have garnered attention in detection of heavy metal ions in environmental samples due to their ease of operation, low cost, and rapid detection responses. Selectivity, sensitivity and detection capabilities of these sensors, can be enhanced by modifying their working electrodes (WEs) with iron oxide nanoparticles (IONPs) and/or their composites. Therefore, this review is an in-depth analysis of the deployment of IONPs/nanocomposites in modification of electrochemical sensors for detection of Pb2+ in drinking water over the past decade. From the analyzed studies (n = 23), the optimal solution pH, deposition potential, and deposition time ranged between 3 and 5.6, -0.7 to -1.4 V vs Ag/AgCl, and 100-400 s, respectively. Majority of the studies employed square wave anodic stripping voltammetry (n = 16), in 0.1 M acetate buffer solution (n = 19) for detection of Pb2+. Limits of detection obtained (2.5 x 10-9 - 4.5 µg/L) were below the permissible levels which indicated good sensitivities of the modified electrodes. Despite the great performance of these modified electrodes, the primary source of IONPs has always been commercial iron-based salts in addition to the use of so many materials as modifying agents of these IONPs. This may limit reproducibility and sustainability of the WEs due to lengthy and costly preparation protocols. Steel and/or iron industrial wastes can be alternatively employed in generation of IONPs for modification of electrochemical sensors. Additionally, biomass-based activated carbons enriched with surface functional groups are also used in modification of bare IONPs, and subsequently bare electrodes. However, these two areas still need to be fully explored.

Synthesis, characterization and application of steel waste-based iron oxide nanoparticles for removal of heavy metals from industrial wastewaters.

Water treatment and reuse can avail more clean and safe water for human use. In this study, iron oxide waste powder generated from the steel pickling process was used to develop iron oxide nanoparticles (IONPs) using solution gelation synthesis process. The powder and developed IONPs were characterized by X-ray fluorescence and diffraction (XRF, XRD), scanning electron microscopy, Fourier-transform infrared spectroscopy, and Brunauer-Emmett-Teller (BET) analyses. Adsorption experiments were carried out on synthetic water with lead and chromium metal ions. The adsorption data were analysed with Langmuir and Freundlich models. Adsorption kinetics were also analysed with Pseudo-First-Order and Pseudo-Second-Order models using non-linear regression. The synthesized IONPs were porous with active surface functional groups of hydroxyl bonds, with BET specific surface area of 325.02 m2/g. XRD results confirmed the cubic spinel structure of IONPs with particle sizes of 20-30 nm. The nanoparticles at a dosage of 0.35 g in 10 mL for 50 min effectively removed Pb(II) and Cr(VI) metal ions up to 99.9% from both synthetic water and industrial wastewater. The adsorption capacity (qmax) of IONPs was found to be 417 and 326.80 for Pb(II) and Cr(VI) respectively. Freundlich isotherm model data fitted best for the removal of both metal ions. The regression values for kinetic models confirmed that pseudo-second-order best fit the adsorption of both Pb(II) and Cr(VI) confirming chemisorption processes. This study contributes to elucidating alternative application of pickling waste from the steel rolling mills for the benefit of heavy metal removal in industrial wastewater.

Iron oxide nanoparticles/nanocomposites derived from steel and iron wastes for water treatment: A review.

Iron oxide nanoparticles (IONPs) are characterized by superior magnetic properties, high surface area to volume ratio, and active surface functional groups. These properties aid in removal of pollutants from water, through adsorption and/or photocatalysis, justifying the choice of IONPs in water treatment systems. IONPs are usually developed from commercial chemicals of ferric and ferrous salts alongside other reagents, a procedure that is costly, environmentally unfriendly and limits their mass production. On the other hand, steel and iron industries produce both solid and liquid wastes which in most cases are piled, discharged into water streams or landfilled as strategies to dispose them off. Such practices are detrimental to environmental ecosystems. Given the high content of iron present in these wastes, they can be used to generate IONPs. This work reviewed published literature through selected key words on the deployment of steel and/or iron-based wastes as IONPs precursors for water treatment. The findings reveal that steel waste-derived IONPs have properties such as specific surface area, particle sizes, saturation magnetization, and surface functional groups that are comparable or sometimes better than those synthesized from commercial salts. Furthermore, the steel waste-derived IONPs have high removal efficacy for heavy metals and dyes from water with possibilities of being regenerated. The performance of steel waste-derived IONPs can be enhanced by functionalization with different reagents such as chitosan, graphene, and biomass based activated carbons. Nonetheless, there is need to explore the potential of steel waste-based IONPs in removing contaminants of emerging concern, modifying pollutant detection sensors, their techno-economic feasibility in large treatment plants, toxicity of these nanoparticles when ingested into the human body, among other areas.

Optimization of roughing filtration unit for a handwashing wastewater recirculation point-of-use system.

A downward roughing filter unit consisting of silica sand as the filter medium was optimized for performance towards removal of turbidity and suspended solids from handwashing wastewater. Design-Expert software was employed to optimize media particle size, filter depth, and flowrate. Linear and quadratic models were found to best fit the responses of turbidity and suspended solids removal, respectively. Particle size and flow rate were the only parameters with significant effects on removal of turbidity and suspended solids. Optimal conditions were found to be media particle size 0.6 mm, filter depth 12 cm, and flow rate 0.3 Lmin-1, corresponding to removal efficiencies of 62 and 67% for turbidity and total suspended solids (TSS), respectively, as predicted by the model. Validation of model at optimal conditions resulted in turbidity and TSS removal of 55 and 53%, respectively. Additionally, removal efficiencies of the roughing filter towards apparent colour, true colour, biochemical oxygen demand (BOD5), and chemical oxygen demand (COD) from handwashing wastewater were 56, 20, 32, and 5%, respectively. Overall, although turbidity of filtered water was >50 NTU, the reduction achieved by roughing filtration is a significant step in enhancing the performance of water treatment processes downstream, including filtration and adsorption by slow sand filters and activated carbon, respectively.

Synergetic effects of biochar addition on mesophilic and high total solids anaerobic digestion of chicken manure.

High solids anaerobic digestion (AD) of chicken manure (CM) is often challenging due to ammonia-N inhibition and accumulation of volatile fatty acids (VFAs). This study evaluated the effect of adding biochars from different feedstock to ameliorate semi-dry AD of fresh CM during batch fermentation. Experiments were performed in 300 mL at two total solid (TS) levels (12% and 15%) under mesophilic (36 ±1ᵒC) conditions for 55 d, using activated sludge as inoculum. Treatments included: fresh CM (at 12% or 15% TS) mixed separately with rice husks char (RB), wood char (WB) and bamboo char (BB) at biochar dosages of 2.5%, 5% and 10% of TS in the CM, inoculum only and inoculum plus CM without addition of char as the control. Results indicated that addition of biochar reduced the lag phases to 4-5.4 d and AD performances were significantly improved with total volatile solids removal of 53-67% and 62-71%, and cumulative methane of 277-380 mL/gVS (CH4 content ≈ 51-63%) and 297-438 mL/gVS (CH4 content ≈ 49-67%) at 12% and 15% TS, respectively. Biochar buffered over acidification and stabilized pH in the range of 6.5-7.8 but mild ammonia inhibition still occurred in all biochar treatments due to the high residual total ammonia-N (4.3 g-5.6 g/L). For all the investigated parameters, WB amended digesters exhibited the best results owing to its high specific surface area, porosity, cationic exchange capacity, and elemental composition which were superior to those of RB and BB. At 10% dosage of all tested biochars, the AD process was more stable and methane content neared optimal of >65% CH4. Therefore, addition of biochar from lignocellulosic materials at a given threshold dosage could promote semi-dry and dry biogas production from chicken manure and thus add value to this waste which in most cases is improperly managed.

Biofuel characteristics of non-charred briquettes from dried fecal sludge blended with food market waste: Suggesting a waste-to-biofuel enterprise as a win-win strategy to solve energy and sanitation problems in slums settlements.

This study explored the production and evaluation of briquettes made from dried fecal sludge mixed with fresh food waste as a dual strategy to solve energy poverty and poor sanitation problems in Ugandan slums. Cylindrical briquettes measuring 82 mm height by 76 mm diameter were produced from dried fecal sludge (FS) alone, and FS mixed separately with pineapple peels (FS + PP), charcoal fines (FS + CD), and bean husks (FS + BH) in a mix ratio of 50% FS: 50% biomass (wt/wt basis) using red soil as the binder. Physiochemical characteristics and fuel thermal efficiency of the briquettes were tested following ASTM standards and were compared to wood-derived charcoal and commonly traded briquettes on market in Uganda. The average moisture content was 5.1%. Bulk density was highest in FS briquettes (1.12 g/cm3) and lowest in FS + BH (0.847 g/cm3). Volatile matter (VM) was highest in FS + PP (39%) and lowest in FS alone (25.7%). The average ash content was 30.4%. FS + PP had the highest calorific value (17.92 MJ/kg) while FS alone had the lowest (6.19 MJ/kg). The highest burning rate was recorded in FS + CD briquettes (8 g/min) and was lowest in FS + PP (4 g/min). Based on the calculated burning rates and calorific values, the economic advantage calculations implied that blending one ton of dry FS with one ton of dry pineapple peels for fuel briquettes, and their use as a substitute could save consumers about USD 620 per ton of wood charcoal foregone.

Development and appraisal of handwash-wastewater treatment system for water recycling as a resilient response to COVID-19.

In this work, results from characterization of handwashing wastewater from selected stations in Kampala City, Uganda, revealed that handwashing wastewater did not meet permissible international standards for wastewater discharge to the environment. The ratio of BOD5 to COD of ˂ 0.5 implied that handwashing wastewater was not amenable to biological treatment processes. Turbidity of ˃ 50 NTU pointed to the need for a roughing filter prior to slow sand filtration. Subsequently, a handwashing wastewater treatment system consisting of selected particle sizes of silica sand, zeolite, and granular activated carbon as filtration and/or adsorption media was developed and assessed for performance towards amelioration of the physicochemical and biological parameters of the handwashing wastewater. Treated water from the developed wastewater treatment system exhibited a turbidity of 5 NTU, true color of 10 Pt-Co, apparent color of 6 Pt-Co, and TSS of 9 mgL-1, translating to removal efficiencies of up to 98.5%, 98.1%, 99.7%, and 96.9%, respectively. The residual total coliforms and E. coli of 1395 and 1180 CFU(100 mL)-1 respectively, were totally eliminated upon disinfection with 0.5 mL NaOCl (3.5% wt/vol) per liter of treated wastewater. The treated water was thus suitable for recycling for handwashing purpose as opposed to letting handwashing wastewater merely go down the drain. This approach provides a resilient response to COVID-19, where communities faced with water scarcity can treat and recycle handwashing wastewater at the point of washing. It thus enables more people to have the opportunity to practice handwashing, abating the high risks of infection, which could otherwise arise.

Nutrient recovery from pineapple waste through controlled batch and continuous vermicomposting systems.

The largest portion of pineapple peels and pulp generated from production points is disposed of haphazardly contributing to a number of environmental and health challenges. However, these wastes contain valuable plant nutrients that could be recovered to boost soil fertility, and increase agricultural production. This study evaluated the variation in physico-chemical parameters in batch and continuous vermicomposting systems as potential pathways for nutrient recovery from pineapple waste. The study compared the efficiency of waste reduction and nutrient recovery for batch (B), and continuous (C) vermicomposting systems during a 60-day period. The substrates were pineapple peels (PW), and cattle manure (CM) fed in a ratio of 4:1 (w/w). Control reactors were fed with 100% CM in both the feeding modes. Results indicated that waste degradation was 60%, and 54% while earthworm biomass increased by 57% and 129% for BPW, and CPW, respectively. pH significantly decreased with time in both systems. Total phosphorous increased with vermicomposting time with that of B being significantly higher than C systems. Nitrogen, potassium, and sodium significantly increased in the control experiments while the three elements significantly reduced for BPW, and CPW owing to high leachate production in the latter. The N, P, K, and C retention in vermicompost was 24.2%, 90.4%, 67.5%, 41.1%, and 32.6%, 91.2%, 79.3%, 46.1%, for BPW and CPW, respectively. Continuous systems produced higher earthworm biomass and retained more nutrients in vermicompost than batch systems, and can therefore, be recommended as better systems for pineapple waste vermicomposting.