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1.
ChemSusChem ; 16(6): e202201924, 2023 Mar 22.
Article in English | MEDLINE | ID: mdl-36513946

ABSTRACT

Herein, surface-functionalized carbon nanotubes (CNTs) were successfully synthesized by dry ball milling that facilitates industrial application. The optimal conditions were determined by analyzing the physicochemical characteristics of CNTs, including the content of the carboxyl group (-COOH) induced on the surface of CNTs by co-existing dry ice based on the ball milling time. Among them, 30 s ball milling (CNTs-30s) showed a high dispersibility in N-methyl-2-pyrrolidone (NMP) while retaining most carboxyl groups and maintaining the intrinsic high conductivity. In the evaluation of rate capability and 5 C/5 C cyclability applied to the Li1+x (Ni1-y-z Coy Mnz )1-x O2 with 60 % Ni (NCM622) cathode, CNTs-30s showed excellent performance based on a well-formed conductive network. Regarding improved dispersion properties and electrochemical performance, the optimal surface functionalization conditions, dispersibility, and electrode properties according to the processing time were analyzed; based on these, the correlation with electrochemical performance was confirmed.

2.
Cancer Res Treat ; 55(2): 513-522, 2023 Apr.
Article in English | MEDLINE | ID: mdl-36097806

ABSTRACT

PURPOSE: Assessing the metastasis status of the sentinel lymph nodes (SLNs) for hematoxylin and eosin-stained frozen tissue sections by pathologists is an essential but tedious and time-consuming task that contributes to accurate breast cancer staging. This study aimed to review a challenge competition (HeLP 2019) for the development of automated solutions for classifying the metastasis status of breast cancer patients. Materials and Methods: A total of 524 digital slides were obtained from frozen SLN sections: 297 (56.7%) from Asan Medical Center (AMC) and 227 (43.4%) from Seoul National University Bundang Hospital (SNUBH), South Korea. The slides were divided into training, development, and validation sets, where the development set comprised slides from both institutions and training and validation set included slides from only AMC and SNUBH, respectively. The algorithms were assessed for area under the receiver operating characteristic curve (AUC) and measurement of the longest metastatic tumor diameter. The final total scores were calculated as the mean of the two metrics, and the three teams with AUC values greater than 0.500 were selected for review and analysis in this study. RESULTS: The top three teams showed AUC values of 0.891, 0.809, and 0.736 and major axis prediction scores of 0.525, 0.459, and 0.387 for the validation set. The major factor that lowered the diagnostic accuracy was micro-metastasis. CONCLUSION: In this challenge competition, accurate deep learning algorithms were developed that can be helpful for making a diagnosis on intraoperative SLN biopsy. The clinical utility of this approach was evaluated by including an external validation set from SNUBH.


Subject(s)
Breast Neoplasms , Deep Learning , Humans , Female , Breast Neoplasms/pathology , Sentinel Lymph Node Biopsy , Lymph Nodes/pathology , Lymphatic Metastasis/pathology , Algorithms
3.
Nanomaterials (Basel) ; 12(23)2022 Dec 01.
Article in English | MEDLINE | ID: mdl-36500894

ABSTRACT

Lithium-ion batteries (LIBs) continue to dominate the battery market with their efficient energy storage abilities and their ongoing development. However, at high charge/discharge C-rates their electrochemical performance decreases significantly. To improve the power density properties of LIBs, it is important to form a uniform electron transfer network in the cathode electrode via the addition of conductive additives. Carbon nanotubes (CNTs) with high crystallinity, high electrical conductivity, and high aspect ratio properties have gathered significant interest as cathode electrode conductive additives. However, due to the high aggregational properties of CNTs, it is difficult to form a uniform network for electron transfer within the electrode. In this study, to help fabricate electrodes with well-dispersed CNTs, various electrodes were prepared by controlling (i) the mixing order of the conductive material, binder, and active material, and (ii) the sonication process of the CNTs/NMP solution before the electrode slurry preparation. When the binder was mixed with a well sonicated CNTs/NMP solution, the CNTs uniformly adsorbed to the then added cathode material of LiNi0.6Co0.2Mn0.2O2 and were well-dispersed to form a flowing uniform network. This electrode fabrication process achieved > 98.74% capacity retention after 50 cycles at 5C via suppressed polarization at high current densities and a more reversible H1-M phase transition of the active material. Our study presents a novel design benchmark for the fabricating of electrodes applying well-dispersed CNTs, which can facilitate the application of LIBs in high current density applications.

4.
Nanomaterials (Basel) ; 12(12)2022 Jun 07.
Article in English | MEDLINE | ID: mdl-35745295

ABSTRACT

The electrode concept of graphite and silicon blending has recently been utilized as the anode in the current lithium-ion batteries (LIBs) industry, accompanying trials of improvement of cycling life in the commercial levels of electrode conditions, such as the areal capacity of approximately 3.3 mAh/cm2 and volumetric capacity of approximately 570 mAh/cm3. However, the blending concept has not been widely explored in the academic reports, which focused mainly on how much volume expansion of electrodes could be mitigated. Moreover, the limitations of the blending electrodes have not been studied in detail. Therefore, herein we investigate the graphite blending electrode with micron-sized SiOx anode material which is one of the most broadly used Si anode materials in the industry, to approach the commercial and practical view. Compared to the silicon micron particle blending electrode, the SiOx blending electrode showed superior cycling performance in the full cell test. To elucidate the cause of the relatively less degradation of the SiOx blending electrode as the cycling progressed in full-cell, the electrode level expansion and the solid electrolyte interphase (SEI) thickening were analyzed with various techniques, such as SEM, TEM, XPS, and STEM-EDS. We believe that this work will reveal the electrochemical insight of practical SiOx-graphite electrodes and offer the key factors to reducing the gap between industry and academic demands for the next anode materials.

5.
Polymers (Basel) ; 14(9)2022 Apr 23.
Article in English | MEDLINE | ID: mdl-35566895

ABSTRACT

Crystalline and noncrystalline poly(3-hyroxybutylate-co-4-hyroxybutylate) (P(3HB-co-4HB)) were melt blended to obtain mixtures of P(3HB-co-4HB) copolymers. The mixtures and P(3HB-co-4HB) copolymers of different 4HB contents were compared to study the effect of 4HB content on the properties of the copolymers and mixtures. P(3HB-co-4HB) copolymer mixtures, having various 4HB content, have been successfully made by melt blending instead of bacterial biosynthesis. In the case of copolymers, they were noncrystalline when the 4HB content was over 16%, while the P(3HB-co-4HB) mixtures at the same 4HB content were crystalline. The mixtures had a higher glass transition temperature, suggesting that their chain mobility is relatively low compared with the copolymer having the same 4HB content. Due to this effect, the mixture is expected to have a higher melt viscosity and a lower loss tangent to exhibit better melt processing properties. The mechanical properties of the mixtures show a similar behavior to the copolymers in that the tensile strength and the modulus decreases and elongation at the break increases with an increase in the 4HB content.

6.
Adv Mater ; 29(48)2017 Dec.
Article in English | MEDLINE | ID: mdl-28251710

ABSTRACT

Cathode material degradation during cycling is one of the key obstacles to upgrading lithium-ion and beyond-lithium-ion batteries for high-energy and varied-temperature applications. Herein, we highlight recent progress in material surface-coating as the foremost solution to resist the surface phase-transitions and cracking in cathode particles in mono-valent (Li, Na, K) and multi-valent (Mg, Ca, Al) ion batteries under high-voltage and varied-temperature conditions. Importantly, we shed light on the future of materials surface-coating technology with possible research directions. In this regard, we provide our viewpoint on a novel hybrid surface-coating strategy, which has been successfully evaluated in LiCoO2 -based-Li-ion cells under adverse conditions with industrial specifications for customer-demanding applications. The proposed coating strategy includes a first surface-coating of the as-prepared cathode powders (by sol-gel) and then an ultra-thin ceramic-oxide coating on their electrodes (by atomic-layer deposition). What makes it appealing for industry applications is that such a coating strategy can effectively maintain the integrity of materials under electro-mechanical stress, at the cathode particle and electrode- levels. Furthermore, it leads to improved energy-density and voltage retention at 4.55 V and 45 °C with highly loaded electrodes (≈24 mg.cm-2 ). Finally, the development of this coating technology for beyond-lithium-ion batteries could be a major research challenge, but one that is viable.

7.
Chem Commun (Camb) ; (2): 218-20, 2009 Jan 08.
Article in English | MEDLINE | ID: mdl-19099074

ABSTRACT

Li[Ni0.25Li0.15Mn0.6]O2 nanowires having an aspect ratio of several hundreds and with a diameter of about 30 nm were synthesized at a pH of 2 during a hydrothermal process at 200 degrees C for 5 h without using a template. The nanowires exhibited a first discharge capacity of 311 mA h g(-1) and a rate capability of 95% at 4C (=1200 mA g(-1)).

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