Vacancy designed 2D materials for electrodes in energy storage devices.

Vacancies are ubiquitous in nature, usually playing an important role in determining how a material behaves, both physically and chemically. As a consequence, researchers have introduced oxygen, sulphur and other vacancies into bi-dimensional (2D) materials, with the aim of achieving high performance electrodes for electrochemical energy storage. In this article, we focused on the recent advances in vacancy engineering of 2D materials for energy storage applications (supercapacitors and secondary batteries). Vacancy defects can effectively modify the electronic characteristics of 2D materials, enhancing the charge-transfer processes/reactions. These atomic-scale defects can also serve as extra host sites for inserted protons or small cations, allowing easier ion diffusion during their operation as electrodes in supercapacitors and secondary batteries. From the viewpoint of materials science, this article summarises recent developments in the exploitation of vacancies (which are surface defects, for these materials), including various defect creation approaches and cutting-edge techniques for detection of vacancies. The crucial role of defects for improvement in the energy storage performance of 2D electrode materials in electrochemical devices has also been highlighted.

In situ growth of laser-induced graphene micro-patterns on arbitrary substrates.

In this article we report a new laser processing method, combining the in situ graphitization of polyimide with simultaneous transfer of the graphene patterns to arbitrary substrates. The synthesis conditions are similar to those normally used for the well-known laser-induced graphene method. The approach is based on the enclosure of polyimide sheets between microscope glass slides. Graphene patterns have been successfully generated on glass and on PDMS, as well as graphene decorated with metals and oxides. In order to illustrate the usefulness of the proposed approach, the method was applied to the fabrication of hybrid supercapacitors, which exhibited very good electrochemical performance.

Microwave as a Tool for Synthesis of Carbon-Based Electrodes for Energy Storage.

This Spotlight on Applications highlights the significant impact of microwave-assisted methods for synthesis and modification of carbon materials with enhanced properties for electrodes in energy storage applications (supercapacitors and batteries). For the past few years, microwave irradiation has been increasingly used for the synthesis of carbon materials with different morphologies using various precursors. Microwave processing exhibits numerous advantages, such as short processing times, high yield, expanded reaction conditions, high reproducibility, and high purity of products. On this frontier research area, we have discussed microwave-assisted synthesis, defect creation, simultaneous reduction and exfoliation, and heteroatom doping in carbon materials. By careful manipulation of microwave irradiation parameters, the method becomes a powerful and efficient tool to generate different morphologies in carbon-based materials. Other important outcomes are the flexible control over the degree of reduction and exfoliation of graphene derivatives, the generation of defects in graphene-based materials by metals, the intercalation of metal oxides into graphene derivatives, and heteroatom doping of graphene materials. The Spotlight on Applications aims to provide a condensed overview of the current progress in carbon-based electrodes synthesized by microwave, pointing out outstanding challenges and offering a few suggestions to trigger more research endeavors in this important field.

Direct laser writing of micro-supercapacitors on thick graphite oxide films and their electrochemical properties in different liquid inorganic electrolytes.

In this article we demonstrate a simple approach to fabricate interdigitated in-plane electrodes for flexible micro-supercapacitors (MSCs). A nanosecond ultraviolet laser treatment is used to reduce and pattern the electrodes on thick graphite oxide (GO) freestanding films. These laser-treated regions obtained by direct writing provide the conducting channels for electrons in the capacitors. The electrochemical performance of the MSCs was evaluated in the presence of two different electrolytes and they exhibit characteristics of nearly electrical double layer capacitors. The MSCs have areal capacitances as 2.40, 2.23 and 1.62µF/cm2 for NaOH, Na2SO4 and KCl electrolytes respectively, for measurements performed at the scan rate of 50mV/s. They retain ∼93.1% of their initial capacitances after 3500 cycles (scan rate=80mV/s) in NaOH electrolyte. The proposed laser treatment approach enables facile and fast fabrication of flexible MSCs without the need for tedious processing methods such as photolithographic micro-patterning and deposition of porous carbon or metallic current collectors.