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1.
Mar Pollut Bull ; 61(1-3): 37-51, 2010.
Article in English | MEDLINE | ID: mdl-20153485

ABSTRACT

This paper provides a review and critique of the distributions and characteristics of non-cohesive and cohesive sediments within the Severn Estuary, with particular reference to floc properties. The estuary is hyper-tidal and, consequently, highly turbid along most of its length and it generally has two turbidity maxima. In the upper reaches of the estuary, suspended particulate matter (SPM) concentrations can be in excess of 10 g l(-1) for river flows up to 50 m(3)s(-1), rising to over 50 g l(-1) during periods of lower river flow. The lower estuary turbidity maximum originates in the vicinity of Bridgwater Bay where SPM concentrations may vary between 0.1-200 g l(-1). The formation of fluid mud is coupled to the spring-neap cycle and strong vertical gradients in SPM concentrations produce turbulence damping and drag reduction effects, and hence impair the ability of the flow to transport sediments. Flocculation is an important mechanism for controlling the behaviour of fine sediments and mean settling velocities of flocs vary between 0.8-6 mm s(-1). A secondary consequence of flocculation is the formation of mud:sand mixtures in turbid suspensions. Improved understanding of the significance of flocculation processes is crucial as they may exert an influence on the mechanism by which adsorbed contaminants are transported in the system.


Subject(s)
Geologic Sediments/analysis , Geologic Sediments/chemistry , Rivers , Seawater/chemistry , Water Movements , Flocculation , United Kingdom
2.
Mar Pollut Bull ; 61(1-3): 52-67, 2010.
Article in English | MEDLINE | ID: mdl-20152994

ABSTRACT

The contemporary inputs of total metals to the Severn Estuary and the inner Bristol Channel from land-based sources have declined over the past 25 years, with the possible exception of chromium. Coherent measurements of dissolved and suspended particulate and sedimentary metals, dissolved nutrients and master variables, including salinity, suspended particulate matter (SPM) concentration, dissolved oxygen saturation and chlorophyll concentration, were made in the Severn Estuary and inner Bristol Channel during 2004 and 2005. Concentrations of total inorganic nitrogen (TIN) were comparable with values reported 20 years ago but were dominated by nitrate, possibly from diffuse sources. Sediments had total metal concentrations similar to the World averages for riverine particulate material, except for Cu which had elevated values in 2004. Concentrations of suspended particulate As, Cr and Zn showed little spatial variability. Dissolved concentrations of most metals were generally below their respective environmental quality standards, although high concentrations of dissolved Cu, and possibly As, appeared to be emanting from a sedimentary source. The K(D)s for As, Cr, Cu and Zn displayed an inverse relationship with SPM concentration, whereas the K(D)s for Hg increased with SPM. The results show that there is a need for a sediment inventory of metals to account for metal release during sediment resuspension events.


Subject(s)
Geologic Sediments/analysis , Geologic Sediments/chemistry , Metals/analysis , Rivers/chemistry , Seawater/chemistry , Ammonia/analysis , Chlorophyll/analysis , Metals/chemistry , Nitrates/analysis , Nitrites/analysis , Nitrogen/analysis , Oxygen/chemistry , Oxygen/metabolism , Particulate Matter/analysis , Particulate Matter/chemistry , Phosphorus/analysis , Salinity , Silicates/analysis , Time Factors , United Kingdom , Water Movements
3.
Mar Pollut Bull ; 61(1-3): 68-82, 2010.
Article in English | MEDLINE | ID: mdl-20106492

ABSTRACT

When the first MPB special issue was published 25 years ago it was suggested that high body burdens of metals and selected organic pollutants in the Severn Estuary were the result of anthropogenic loadings from a variety of sources. The objective of this synopsis is to illustrate recent trends for contaminants (metals, PAHs, PCBs) in sediments and benthic biota and to consider the evidence for improved environmental quality over the last quarter of a century. Contaminants in sediments and sediment-dwelling fauna such as Hediste(=Nereis)diversicolor are, generally, evenly distributed over the estuary - which is the consequence of extensive re-suspension and redistribution of fine sediment by strong tidal currents. Such dispersal tends to mask the influences of individual discharges and physical characteristics are considered to be the major drivers affecting biodiversity in the Severn Estuary, often overshadowing contaminant concerns. Following the closure of major industries and the introduction of stricter pollution control, many inputs have ceased or been reduced and there are indications that environmental concentrations are now lower. Bioaccumulation of most contaminants has declined accordingly (with the possible exception of Cr). Intuitively, better environmental quality should be linked to ecological improvements. However, due to the dynamic nature of the system (and a lack of biological-effects data) it is difficult to establish direct relationships between inputs, body burdens and biological/ecological consequence. Uniquely, the long-term integrated monitoring program of AstraZeneca (Avonmouth) indicates that recovery of faunal diversity and abundance has occurred in mid-sections of the estuary in recent years implying that contaminants have indeed been a forcing feature for Severn biota. In this context, we highlight contaminant issues and biogeochemical changes which may need to be addressed in connection with the development of proposals for tidal energy schemes.


Subject(s)
Ecosystem , Environmental Monitoring , Geologic Sediments/chemistry , Rivers , Seawater , Water Pollutants, Chemical/analysis , Water Pollutants, Chemical/toxicity , Ammonia/analysis , Biodiversity , Metals/analysis , Metals/toxicity , Plant Development , Plants/drug effects , Plants/metabolism , Polychlorinated Biphenyls/analysis , Polychlorinated Biphenyls/toxicity , Polycyclic Aromatic Hydrocarbons/analysis , Polycyclic Aromatic Hydrocarbons/toxicity , Radioisotopes/analysis , Radioisotopes/toxicity , Time Factors , United Kingdom , Water Movements
5.
Mar Pollut Bull ; 61(1-3): 124-31, 2010.
Article in English | MEDLINE | ID: mdl-20079502

ABSTRACT

The regulatory requirements imposed by the Habitats Directive (EU 93/43/EEC) require the Environment Agency for England and Wales (EA) to review consented discharges and determine whether they are compliant with Environmental Quality Standards (EQS). Since the EQS are annual averages, model predictions, and sample comparisons, should be made on an annual average basis. Advection and dispersion of metal contaminants in the Severn Estuary were computed using a coupled 1-D and 2-D hydrodynamic-water quality model. The external inputs of dissolved copper, arsenic, mercury and chromium to the model were from 66 industrial discharges and sewage treatment works and 30 rivers. The annual average predicted concentrations were compared with the annual average dissolved metal concentrations from the 2004 and 2005 monitoring programme, and any discrepancy used to identify the role of additional processes, mainly involving the sediments. This ability to separate anthropogenic inputs from internal estuarine processes contributes to a better understanding of the functioning of the estuary and hence an improved management capability. The paper discusses the approach in designing scenarios and characterising uncertainty, when decision-making in the regulatory context.


Subject(s)
Environmental Monitoring , Models, Theoretical , Rivers/chemistry , Seawater/chemistry , Water Pollutants, Chemical/analysis , Geography , Metals/analysis , Risk Assessment , Sewage/analysis , Sewage/chemistry , Time Factors , United Kingdom , Water Movements , Water Supply/analysis , Water Supply/standards
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