Construction of arsenic selective chelating resin with iron precursor for removal of low-concentration arsenic: Breakthrough modeling and field deployment.

The presence of exorbitant arsenic contamination in the aquatic environment causes astronomically immense health quandaries affecting millions of people, which may lead to death in the case of prolonged indigestion of arsenic-containing drinking water. Herein, we are reporting porous chelating resin with an iron precursor for the removal of arsenic ions from water. Weak acid cation resin was functionalized under varying experimental conditions to get a suitable resin with high arsenic uptake. The theoretical results revealed that the maximum Langmuir adsorption capacities of 3.27 mg g-1 and 1.13 mg g-1 were achieved for As(V) and As(III), respectively. The kinetics of adsorption followed the pseudo-second-order (PSO) model with a high determination coefficient (R2) of 0.9963 and 0.9895 for As(V) and As(III), respectively. The Adams-Bohart, Thomas, Yoon-Nelson, and Pore diffusion models were used to identify the breakthrough curve in the fixed bed adsorption column. The column performance improved with a larger bed height (55 cm), low concentration of influent (0.25 mg L-1), and low flow rate of influent (80 mL min-1). Under this condition, the breakthrough time and exhaustion time were 314 min and 408 min for As(V) and 124 min and 185 min for As(III), respectively.

One-pot facile approach to design an efficient macro-porous polymeric matrix to remediate Hg(II)and Pb(II) from aqueous medium and its performance evaluation study by mathematical modelling.

In the present scenario discharge of heavy-metal ions into water bodies is a global threat that is causing serious health hazards even in low concentrations. Thus, in order to remediate the heavy-metal [Hg(II) and Pb(II)] toxicity, an organic-inorganic hybrid functional porous metallo-polymeric network i. e, poly(Zirconyl methacrylate-co-1-vinyl imidazole) (pZrVIm) was fabricated via one-pot facile synthesis approach. The pZrVIm architecture has shown high removal efficiency for Hg(II) and Pb(II) aqueous medium even in extremely low quantities. Advanced instrumental techniques were used to characterize the structural and morphological characteristics of pZrVIm. Different experimental variables i.e., reaction time, pH, initial feed concentration, co-ion effects etc. were explored to examine adsorption behaviour. The maximum adsorption capacities (qmax) of pZrVIm5 were calculated as 168.06 and 162.34 mg g-1 for Hg(II) and Pb(II) respectively by the Langmuir isotherm model. Data from isotherms showed that monolayer adsorption on a homogeneous surface is the rate-limiting stage and followed pseudo-second-order kinetic process. The Artificial Neural Network (ANN) modelling was used to validate kinetics and isotherm data which revealed high accuracy of the model with correlation coefficient values (R = 0.99). Various types of isotherm models such as Langmuir, Freundlich, Dubinin-Radushkevich, Temkin, Redlich-Peterson, Toth and Koble-Corigen have been studied to determine the adsorption phenomena. The pore diffusion model revealed breakthrough time of 91 h and 84 h, Hg(II) and Pb(II) with the feed concentration of 15 mg L-1 respectively. The study revealed that pZrVIm5 has great potential for heavy metal ions remediation for water treatment.

Synchronous Removal of Arsenic and Fluoride from Aqueous Solution: A Facile Approach to Fabricate Novel Functional Metallopolymer Microspheres.

Concurrence of arsenic (As) and fluoride (F-) ions in groundwater is a serious concern due to their fatal effects. Herein, an attempt was made to fabricate quaternized poly(zirconyl dimethacrylate-co-vinylbenzyl chloride)] (ZrVBZ), a metallopolymeric microsphere in three-dimensional shape with a porous texture. The synthesized ZrVBZ was utilized for the synchronal removal of As and F- from water. Techniques such as Fourier transform infrared spectroscopy, 13C-nuclear magnetic resonance, scanning electron microscopy, and Brunauer-Emmett-Teller surface area were used to characterize the ZrVBZ. The maximum adsorption capacity of ZrVBZ for both fluoride and arsenic (q max F-: 116.5 mg g-1, q max As(V): 7.0 mg g-1, and q max As(III): 6.5 mg g-1) at given experimental conditions (adsorbents' dose: 0.250 g L-1, feed of F-: 50 mg L-1, As(V)/As(III): 2000 µg L-1, and pH: 7.0 ± 0.2) was ascribed to the porous spherical architecture with dual functional sites to facilitate adsorption. The adsorption followed pseudo-second-order kinetics with a correlation coefficient of 0.996, 0.997, and 0.990 for F-, As(V), and As(III), respectively. The isotherm data fitted to the Langmuir isotherm model, and the maximum capacity was 121.5, 7.246, and 6.68 mg g-1 for F-, As(V), and As(III), respectively. The results of this study indicated that ZrVBZ could be used as an effective adsorbent for the simultaneous removal of F-, As(V), and As(III) from an aqueous medium.