ABSTRACT
Most liquid lithium-ion-battery electrolytes incorporate cosolvent blends, but the dominant electrochemical transport models adopt a single-solvent approximation, which assumes in part that nonuniform cosolvent ratios do not affect cell voltage. For the popular electrolyte formulation based on ethyl-methyl carbonate (EMC), ethylene carbonate (EC), and LiPF6, we perform measurements with fixed-reference concentration cells, finding appreciable liquid-junction potentials when only the cosolvent ratio is polarized. A previously reported junction-potential correlation for EMC:LiPF6 is extended to cover much of the ternary composition space. We propose a transport model for EMC:EC:LiPF6 solutions grounded in irreversible thermodynamics. Thermodynamic factors and transference numbers are entwined in liquid-junction potentials, but concentration-cell measurements determine observable material properties we call junction coefficients, which appear in the extended form of Ohm's law that accounts for how composition changes induce voltage drops. Junction coefficients of EC and LiPF6 are reported and illustrate the extent to which ionic current induces solvent migration.
ABSTRACT
OBJECTIVE: To compare the effect of foot orthotics and rehabilitation exercises by assessing balancing ability and joint proprioception in athletes who have chronic ankle instability. METHODS: Forty-one athletes who visited hospitals due to chronic ankle instability were randomly assigned to two groups. One group had ankle rehabilitation exercises while the other group had the same rehabilitation exercises as well as foot orthotics. Joint position sense of the ankle joint was examined by using an isokinetic exercise machine. Balancing abilities categorized into static, dynamic and functional balance abilities were evaluated by using computerized posturography. We tested the subjects before and after the four-week rehabilitation program. RESULTS: After the four-week treatment, for joint reposition sense evaluation, external 75% angle evaluation was done, revealing that the group with the application of foot orthotics improved by -1.07±1.64 on average, showing no significant difference between the two groups (p>0.05). Static, dynamic and functional balancing abilities using balance masters were evaluated, revealing that the two groups improved in some items, but showing no significant difference between them (p>0.05). CONCLUSION: This study found that athletes with chronic ankle instability who had foot orthotics applied for four weeks improved their proprioceptive and balancing abilities, but did not show additional treatment effects compared with rehabilitation exercise treatment.
