Fluctuation-dissipation relations for thermodynamic distillation processes.

The fluctuation-dissipation theorem is a fundamental result in statistical physics that establishes a connection between the response of a system subject to a perturbation and the fluctuations associated with observables in equilibrium. Here we derive its version within a resource-theoretic framework, where one investigates optimal quantum state transitions under thermodynamic constraints. More precisely, we first characterize optimal thermodynamic distillation processes, and then we prove a relation between the amount of free energy dissipated in such processes and the free-energy fluctuations of the initial state of the system. Our results apply to initial states given by either asymptotically many identical pure systems or an arbitrary number of independent energy-incoherent systems, and they allow not only for a state transformation but also for the change of Hamiltonian. The fluctuation-dissipation relations we derive enable us to find the optimal performance of thermodynamic protocols such as work extraction, information erasure, and thermodynamically free communication, up to second-order asymptotics in the number N of processed systems. We thus provide a first rigorous analysis of these thermodynamic protocols for quantum states with coherence between different energy eigenstates in the intermediate regime of large but finite N.

Geometric structure of thermal cones.

The second law of thermodynamics imposes a fundamental asymmetry in the flow of events. The so-called thermodynamic arrow of time introduces an ordering that divides the system's state space into past, future, and incomparable regions. In this work, we analyze the structure of the resulting thermal cones, i.e., sets of states that a given state can thermodynamically evolve to (the future thermal cone) or evolve from (the past thermal cone). Specifically, for a d-dimensional classical state of a system interacting with a heat bath, we find explicit construction of the past thermal cone and the incomparable region. Moreover, we provide a detailed analysis of their behavior based on thermodynamic monotones given by the volumes of thermal cones. Results obtained apply also to other majorization-based resource theories (such as that of entanglement and coherence), since the partial ordering describing allowed state transformations is then the opposite of the thermodynamic order in the infinite temperature limit. Finally, we also generalize the construction of thermal cones to account for probabilistic transformations.