3D camera based on laser light absorption by atmospheric oxygen at 761†nm.

A 3D camera based on laser light absorption of atmospheric oxygen at 761 nm is presented. The camera uses a current-tunable single frequency distributed feedback laser for active illumination and a silicon-based image sensor as a receiver. This simple combination enables capturing 3D images with a compact and mass producible set-up. The 3D camera is validated in indoor environments. Distance accuracy of better than 4 cm is demonstrated between 4 m and 10 m distances. Future potential and improvements are discussed.

Mid-infrared hyperspectral sensor based on MEMS Fabry-Pérot interferometer for stand-off sensing applications.

We report a novel hyperspectral sensor employing a Fabry-Pérot interferometer based on micro-electro-mechnical system and a custom mid-infrared supercontinuum laser. The Fabry-Pérot interferometer allows on-axis filtering, of spectral components of supercontinuum light backscattered from a target, with a spectral resolution of about 25 nm. We demonstrated hyperspectral identification of black polypropylene (PP) and polyethylene (PE500) using the 3-3.5 [Formula: see text]m region of the supercontinuum spectrum and a corresponding measurement rate of 62.5 spectra / s. The resulted spectra show excellent agreement with the reference based on an FTIR spectrometer. Furthermore, we showed that the coloring of the plastics has no effect on their identification at this wavelength range.

Active hyperspectral imager using a tunable supercontinuum light source based on a MEMS Fabry-Perot interferometer.

We have developed an active hyperspectral imager based on a tunable near-infrared supercontinuum light source. Non-dispersive wavelength selection of the supercontinuum laser source is achieved with a microelectromechanical Fabry-Perot interferometer. The tunable light source enables the use of any monochromatic imaging sensor with a suitable spectral sensitivity for hyperspectral imaging. The imager is characterized and demonstrated in the laboratory for remote detection of ice.

Oxygen-18 and carbon-13 isotopes in eCO2and erythrocytes carbonic anhydrase activity of Finnish prediabetic population.

Complex human physiological processes create the stable isotopic composition of exhaled carbon dioxide (eCO2), measurable with noninvasive breath tests. Recently, isotope-selective breath tests utilizing natural fluctuation in18O/16O isotope ratio in eCO2have been proposed for screening prediabetic (PD) individuals. It has been suggested that18O/16O fractionation patterns reflect shifts in the activity of carbonic anhydrase (CA), an enzyme involved in the metabolic changes in the PD state. To evaluate the applicability of the breath sampling method in Finnish PD individuals, breath delta values (BDVs, ‰) of18O/16O (δ18O) were monitored for 120 min in real-time with a high-precision optical isotope ratio spectrometer, both in the fasting state and during a 2 h oral glucose tolerance test (2 h OGTT) with non-labeled glucose. In addition, the BDV of13C/12C (δ13C) was measured, and total erythrocyte CA activity was determined.δ18O and CA did not demonstrate any statistically significant differences between PD and non-diabetic control (NDC) participants. Instead,δ13C was significantly lower in PD patients in comparison to NDCs in the fasting state and at time points 90 and 120 min of the 2 h OGTT, thus indicating slightly better potential in identifying Finnish PD individuals. However, overlapping values were measured in PD participants and NDCs, and therefore,δ13C cannot be applied as a sole measure in screening prediabetes at an individual level. Thus, because the combination of environmental and lifestyle factors and anthropometric parameters has a greater effect on glucose metabolism and CA activity in comparison to the PD state,18O/16O and13C/12C fractionations or CA activity did not prove to be reliable biomarkers for impaired glucose tolerance in Finnish subjects.This study was conducted under the clinicaltrials.gov ID NCT03156478.

Optical interruption of a quantum cascade laser for cavity ring-down spectroscopy.

We demonstrate optical unlocking of a cavity resonance in a mid-infrared (MIR) quantum cascade laser (QCL) cavity ring-down spectrometer using a low-power multimode near-infrared (NIR) laser diode. A NIR laser with a center wavelength of 1310 nm is injected into a QCL whose amplitude and frequency are modulated as a result. The shift in frequency leads to a rapid interruption of the cavity resonance. The optical method is compared to cavity interruption with a current step by measuring ring-down times in a high-finesse optical cavity, coupled with a QCL with a center wavelength of 4.5 µm. The results indicate the comparable performance of the all-optical method with the more conventional current modulation, but with significantly reduced bandwidth requirements for the QCL driver, opening the way to other potential applications in MIR laser spectroscopy.

Active Hyperspectral Sensor Based on MEMS Fabry-Pérot Interferometer.

An active hyperspectral sensor (AHS) was developed for target detection and classification applications. AHS measures light scattered from a target, illuminated by a broadband near-infrared supercontinuum (SC) light source. Spectral discrimination is based on a voltage-tunable MEMS Fabry-Pérot Interferometer (FPI). The broadband light is filtered by the FPI prior to transmitting, allowing for a high spectral-power density within the eye-safety limits. The approach also allows for a cost-efficient correction of the SC instability, employing a non-dispersive reference detector. A precision of 0.1% and long-term stability better than 0.5% were demonstrated in laboratory tests. The prototype was mounted on a car for field measurements. Several road types and objects were distinguished based on the spectral response of the sensor targeted in front of the car.

Determining Biogenic Content of Biogas by Measuring Stable Isotopologues 12CH4, 13CH4, and CH3D with a Mid-Infrared Direct Absorption Laser Spectrometer.

A tunable laser absorption spectrometer (TLAS) was developed for the simultaneous measurement of δ13C and δD values of methane (CH4). A mid-infrared interband cascade laser (ICL) emitting around 3.27 µm was used to measure the absorption of the three most abundant isotopologues in CH4 with a single, mode-hop free current sweep. The instrument was validated against methane samples of fossil and biogenic origin with known isotopic composition. Three blended mixtures with varied biogenic content were prepared volumetrically, and their δ13C and δD values were determined. Analysis demonstrated that, provided the isotopic composition of the source materials was known, the δ13C and δD values alone were sufficient to determine the biogenic content of the blended samples to within 1.5%.

Long distance active hyperspectral sensing using high-power near-infrared supercontinuum light source.

A hyperspectral remote sensing instrument employing a novel near-infrared supercontinuum light source has been developed for active illumination and identification of targets. The supercontinuum is generated in a standard normal dispersion multi-mode fiber and has 16 W total optical output power covering 1000 nm to 2300 nm spectral range. A commercial 256-channel infrared spectrometer was used for broadband infrared detection. The feasibility of the presented hyperspectral measurement approach was investigated both indoors and in the field. Reflection spectra from several diffusive targets were successfully measured and a measurement range of 1.5 km was demonstrated.