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1.
Sci Data ; 10(1): 612, 2023 09 11.
Article in English | MEDLINE | ID: mdl-37696807

ABSTRACT

EuroCrops contains geo-referenced polygons of agricultural croplands from 16 countries of the European Union (EU) as well as information on the respective crop species grown there. These semantic annotations are derived from self-declarations by farmers receiving subsidies under the common agricultural policy (CAP) of the European Commission (EC). Over the last 1.5 years, the individual national crop datasets have been manually collected, the crop classes have been translated into the English language and transferred into the newly developed hierarchical crop and agriculture taxonomy (HCAT). EuroCrops is publicly available under continuous improvement through an active user community.

2.
Front Big Data ; 2: 31, 2019.
Article in English | MEDLINE | ID: mdl-33693354

ABSTRACT

Vegetation state is largely driven by climate and the complexity of involved processes leads to non-linear interactions over multiple time-scales. Recently, the role of temporally lagged dependencies, so-called memory effects, has been emphasized and studied using data-driven methods, relying on a vast amount of Earth observation and climate data. However, the employed models are often not able to represent the highly non-linear processes and do not represent time explicitly. Thus, data-driven study of vegetation dynamics demands new approaches that are able to model complex sequences. The success of Recurrent Neural Networks (RNNs) in other disciplines dealing with sequential data, such as Natural Language Processing, suggests adoption of this method for Earth system sciences. Here, we used a Long Short-Term Memory (LSTM) architecture to fit a global model for Normalized Difference Vegetation Index (NDVI), a proxy for vegetation state, by using climate time-series and static variables representing soil properties and land cover as predictor variables. Furthermore, a set of permutation experiments was performed with the objective to identify memory effects and to better understand the scales on which they act under different environmental conditions. This was done by comparing models that have limited access to temporal context, which was achieved through sequence permutation during model training. We performed a cross-validation with spatio-temporal blocking to deal with the auto-correlation present in the data and to increase the generalizability of the findings. With a full temporal model, global NDVI was predicted with R 2 of 0.943 and RMSE of 0.056. The temporal model explained 14% more variance than the non-memory model on global level. The strongest differences were found in arid and semiarid regions, where the improvement was up to 25%. Our results show that memory effects matter on global scale, with the strongest effects occurring in sub-tropical and transitional water-driven biomes.

3.
Chem Commun (Camb) ; 49(71): 7839-41, 2013 Sep 14.
Article in English | MEDLINE | ID: mdl-23887355

ABSTRACT

The unsaturated side chain of l-propargylglycine (Pra) was used to study parahydrogen-induced polarization (PHIP) in synthetic oligopeptides. For the first time PHIP-induced NMR signal enhancement was demonstrated using model peptides bearing various functional side chains.


Subject(s)
Alkynes/chemistry , Glycine/analogs & derivatives , Oligopeptides/chemical synthesis , Amino Acid Sequence , Catalysis , Glycine/chemistry , Hydrogen/chemistry , Hydrogenation , Magnetic Resonance Spectroscopy , Oligopeptides/chemistry , Sulfhydryl Compounds/chemistry
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