Graphene-Based Temperature Sensors-Comparison of the Temperature and Humidity Dependences.

Four different graphene-based temperature sensors were prepared, and their temperature and humidity dependences were tested. Sensor active layers prepared from reduced graphene oxide (rGO) and graphene nanoplatelets (Gnp) were deposited on the substrate from a dispersion by air brush spray coating. Another sensor layer was made by graphene growth from a plasma discharge (Gpl). The last graphene layer was prepared by chemical vapor deposition (Gcvd) and then transferred onto the substrate. The structures of rGO, Gnp, and Gpl were studied by scanning electron microscopy. The obtained results confirmed the different structures of these materials. Energy-dispersive X-ray diffraction was used to determine the elemental composition of the materials. Gcvd was characterized by X-ray photoelectron spectroscopy. Elemental analysis showed different oxygen contents in the structures of the materials. Sensors with a small flake structure, i.e., rGO and Gnp, showed the highest change in resistance as a function of temperature. The temperature coefficient of resistance was 5.16-3·K-1 for Gnp and 4.86-3·K-1 for rGO. These values exceed that for a standard platinum thermistor. The Gpl and Gcvd sensors showed the least dependence on relative humidity, which is attributable to the number of oxygen groups in their structures.

FFF 3D Printing in Electronic Applications: Dielectric and Thermal Properties of Selected Polymers.

The present study is a focused and comprehensive analysis of the dielectric and thermal properties of twenty-four 3D printed polymers suitable for fused filament fabrication (FFF) in electronic applications. The selected polymers include various thermoplastic elastomers, such as thermoplastics based on polycarbonate (PC), polyethylene terephthalate glycol (PETG), and acrylonitrile butadiene styrene (ABS-T). Their overall thermal behavior, including oxidation stability, glass transition, and melting temperature, was explored using simultaneous thermal analysis (STA) and differential scanning calorimetry (DSC). Considering their intended usage in electronic applications, the dielectric strength (Ep) and surface/volume resistivity (ρs/ρv) were comprehensively tested according to IEC 60243-1 and IEC 62631-3, respectively. The values of the dielectric constant (ε') and loss factor (ε") were also determined by broadband dielectric spectroscopy (BDS). While, on the one hand, exceptional dielectric properties were observed for some thermoplastic elastomers, the materials based on PCs, on the other hand, stood out from the others due to their high oxidation stability and above average dielectric properties. The low-cost materials based on PETG or ABS-T did not achieve thermal properties similar to those of the other tested polymers; nevertheless, considering the very reasonable price of these polymers, the obtained dielectric properties are promising for undemanding electronic applications.

Halloysite Nanotubes as an Additive to Ensure Enhanced Characteristics of Cold-Curing Epoxy Resins under Fire Conditions.

At present, the most commonly used electrical insulating materials, including cold-curing epoxy resins, are well designed for normal operating conditions. However, new generations of materials should also be capable of withstanding extreme emergency conditions, e.g., in case of fire. For this reason, this study presents the possibilities of an improved cold-curing epoxy resin using halloysite nanotubes (HNTs) to increase its operational safety. The positive effect of HNT addition is indicated mainly in terms of the suppression of thermo-oxidation processes, which has been demonstrated by the decreases in the maximum heat flow peaks as well as the specific enthalpy values during the thermal decomposition of the epoxy resin. The observed dielectric parameters of the HNT-added materials differ only slightly from those without a filler, whereas their mechanical properties strongly depend on the amount of dispersed HNTs.

Magnesium Oxide Nanoparticles: Dielectric Properties, Surface Functionalization and Improvement of Epoxy-Based Composites Insulating Properties.

Composite insulation materials are an inseparable part of numerous electrical devices because of synergy effect between their individual parts. One of the main aims of the presented study is an introduction of the dielectric properties of nanoscale magnesium oxide powder via Broadband Dielectric Spectroscopy (BDS). These unique results present the behavior of relative permittivity and loss factor in frequency and temperature range. Following the current trends in the application of inorganic nanofillers, this article is complemented by the study of dielectric properties (dielectric strength, volume resistivity, dissipation factor and relative permittivity) of epoxy-based composites depending on the filler amount (0, 0.5, 0.75, 1 and 1.25 weight percent). These parameters are the most important for the design and development of the insulation systems. The X-ray diffraction patterns are presented for pure resin and resin with optimal filler amount (1 wt %), which was estimated according to measurement results. Magnesium oxide nanoparticles were also treated by addition of silane coupling agent ( γ -Glycidoxypropyltrimethoxysilane), in the case of optimal filler loading (1 wt %) as well. Besides previously mentioned parameters, the effects of surface functionalization have been observed by two unique measurement and evaluation techniques which have never been used for this evaluation, i.e., reduced resorption curves (RRCs) and voltage response method (VR). These methods (developed in our departments), extend the possibilities of measurement of composite dielectric responses related to DC voltage application, allow the facile comparability of different materials and could be used for dispersion level evaluation. This fact has been confirmed by X-ray diffraction analyses.

Structure of self-organized diblock copolymer solutions in partially miscible solvents.

A diblock copolymer dissolved in a mixture of partially miscible solvents creates a self-organized microemulsion with a morphology that depends on the numerous parameters of the system. We discuss one particular case of spherical particles (containing the minority solvent) forming a hard gel with cubic structure and demonstrate using high-resolution synchrotron scattering experiments that the self-organized solution has a BCC structure. After fitting one- and two-dimensional form factors we extract from the data the one- and two-dimensional structure factors, S(q) and S(q,phi). The experimental S(q) corresponds almost quantitatively, up to the 9th order Bragg peak, to that calculated numerically for a randomly-oriented, finite-size BCC crystal. S(q,phi) contains a large number of reflections that allow the structure to be identified more exactly as a twin BCC morphology with some imperfections. Examination of the dependence of the structural parameters on polymer concentration reveals that the dilution law predicted theoretically for the center-to-center distance of the spheres is confirmed experimentally while the size of the spherical objects does not follow theoretical predictions due to chain extension with increasing concentration.

Hydration modes of an amphiphilic molecule: NMR, FTIR, and theoretical study of the interactions in the water-lutidine system.

Using (1)H and (13)C NMR spectra and relaxations, PFG NMR diffusion measurements, FTIR spectra, and quantum-chemical structure predictions and optimizations on the MP2/6-31G(d) level, we have studied interactions between water (W) and lutidine (2,6-dimethylpyridine, L) in a wide range of ratios. At low W content up to 35%, W was found to bind to L by an O-H***N hydrogen bond and form transient L-W aggregates containing two to four L molecules in cooperation with two to three other W molecules. At higher W content, these aggregates are gradually cleaved to single L molecules enwrapped by a hydration shell anchored in an O-H***N hydrogen bond. At all compositions of the mixture, the various hydrate forms are in fast mutual exchange with a correlation time on the order of 1 x 10(-5) s.

(1)H NMR and small-angle neutron scattering investigation of the structure and solubilization behavior of three-layer nanoparticles.

Three-layer nanoparticles were prepared by radiation-induced polymerization of 1-10 g/L of methyl methacrylate dissolved in a 0.1 wt % D(2)O solution of polystyrene-poly(methacrylic acid) (PS-PMA) micelles. According to NMR and small-angle neutron scattering (SANS), most of the poly(methyl methacrylate) (PMMA) is adsorbed at the core-shell interface of the particles. A small fraction of shorter PMMA probably sticks to outer parts of the PMA chains. The absorption kinetics and equilibria of benzene and chloroform were studied by NMR and SANS time-resolved experiments. The diffusion front in the PS core is very narrow but quite broad in the PMMA sheet suggesting, thus, a less compact state of PMMA. According to SANS, the diffusion kinetics is almost independent of the PMMA sheet thickness. In contrast to it, the absorption capacity, reflected by both SANS and NMR, increases markedly with the PMMA content in the particle. The maximum amount of solubilized compound depends on its positive interaction with PMMA (expressed by the chi parameter) but is restricted by the growing interface tension between swollen PMMA and D(2)O. In accordance with this conclusion, a particle saturated with benzene can absorb chloroform only at the expense of a part of benzene expelled into the surrounding medium and vice versa. Starting with 10 g PMMA/L (10 times the weight of the original micelles), the particles become unstable when being swollen with a good solvent.