ABSTRACT
In the title mol-ecule, [Bi(C6H5)3(C4H5O2)2], the Bi(V) atom is in a distorted trigonal-bipyramidal environment with carboxyl-ate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi-O bond lengths are 2.283â (3) and 2.309â (2)â Å, but as a result of additional long Biâ¯O inter-actions [2.787â (3) and 2.734â (3)â Å], one of the C-Bi-C angles is 148.62â (13)°. In the crystal, weak C-Hâ¯O hydrogen bonds connect pairs of mol-ecules into inversion dimers. These dimers are further connected by weak C-Hâ¯π inter-actions into chains along [100] .
ABSTRACT
The asymmetric unit of the title compound, [Sb(C6H5)3(C10H9O3)2]·C6H6, contains one organometallic mol-ecule and one benzene mol-ecule that is disordered over two sets of sites with an occupancy ratio of 0.556â (15):0.444â (15). The Sb(V) atom is in a distorted trigonal-bipyramidal environment with the carboxyl-ate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional Sbâ¯O inter-actions, one of the C-Sb-C angles is widened to 140.19â (6)°.