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1.
The First Biscarbene Complex of a Group 4 Metal: [Zr{C(Me(2)P=NSiMe(3))(2)}(2)] We thank the Natural Sciences and Engineering Research Council of Canada, NOVA Chemicals Corp., and the University of Alberta for financial support.
Aparna, Kasani; Kamalesh Babu, Ruppa P.; McDonald, Robert; Cavell, Ronald G..
Angew Chem Int Ed Engl ; 40(23): 4400-4402, 2001 Dec 03.
Article in English | MEDLINE | ID: mdl-12404428
2.
[Ph2 P(NSiMe3 )]2 CLi2 : A Dilithium Dianionic Methanide Salt with an Unusual Li4 C2 Cluster Structure.
Kasani, Aparna; Kamalesh Babu, Ruppa P; McDonald, Robert; Cavell, Ronald G.
Angew Chem Int Ed Engl ; 38(10): 1483-1484, 1999 May 17.
Article in English | MEDLINE | ID: mdl-29711582

ABSTRACT

Four lithium atoms in a square-planar arrangement are capped by two carbon atoms and encapsulated by NSiMe3 chelation in the dilithium methanide salt 1. This air- and moisture-sensitive complex is formed by the reaction of CH2 (Ph2 P=NSiMe3 )2 with alkyl- or aryllithium reagents.

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