Your browser doesn't support javascript.
loading
Show: 20 | 50 | 100
Results 1 - 2 de 2
Filter
Add more filters










Database
Language
Publication year range
1.
Bioresour Technol ; 242: 272-282, 2017 Oct.
Article in English | MEDLINE | ID: mdl-28341378

ABSTRACT

Chemical interesterification of rubber seed oil has been investigated for four different designed orifice devices in a pilot scale hydrodynamic cavitation (HC) system. Upstream pressure within 1-3.5bar induced cavities to intensify the process. An optimal orifice plate geometry was considered as plate with 1mm dia hole having 21 holes at 3bar inlet pressure. The optimisation results of interesterification were revealed by response surface methodology; methyl acetate to oil molar ratio of 14:1, catalyst amount of 0.75wt.% and reaction time of 20min at 50°C. HC is compared to mechanical stirring (MS) at optimised values. The reaction rate constant and the frequency factor of HC were 3.4-fold shorter and 3.2-fold higher than MS. The interesterified product was characterised by following EN 14214 and ASTM D 6751 international standards.


Subject(s)
Hevea , Plant Oils , Catalysis , Hydrodynamics , Rubber , Seeds
2.
Bioresour Technol ; 199: 414-422, 2016 Jan.
Article in English | MEDLINE | ID: mdl-26298387

ABSTRACT

Pretreatment of the high free fatty acid rubber seed oil (RSO) via esterification reaction has been investigated by using a pilot scale hydrodynamic cavitation (HC) reactor. Four newly designed orifice plate geometries are studied. Cavities are induced by assisted double diaphragm pump in the range of 1-3.5 bar inlet pressure. An optimised plate with 21 holes of 1mm diameter and inlet pressure of 3 bar resulted in RSO acid value reduction from 72.36 to 2.64 mg KOH/g within 30 min of reaction time. Reaction parameters have been optimised by using response surface methodology and found as methanol to oil ratio of 6:1, catalyst concentration of 8 wt%, reaction time of 30 min and reaction temperature of 55°C. The reaction time and esterified efficiency of HC was three fold shorter and four fold higher than mechanical stirring. This makes the HC process more environmental friendly.


Subject(s)
Biofuels , Biotechnology/methods , Hevea/chemistry , Plant Oils/chemistry , Biotechnology/instrumentation , Catalysis , Equipment Design , Esterification , Fatty Acids, Nonesterified/chemistry , Hydrodynamics , Methanol/chemistry , Pressure , Seeds/chemistry , Temperature
SELECTION OF CITATIONS
SEARCH DETAIL
...