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Phys Rev E Stat Nonlin Soft Matter Phys ; 79(2 Pt 1): 021806, 2009 Feb.
Article in English | MEDLINE | ID: mdl-19391771

ABSTRACT

We have evaluated a universal ratio between diffusion constants of the ring polymer with a given knot K and a linear polymer with the same molecular weight in solution through the Brownian dynamics under hydrodynamic interaction. The ratio is found to be constant with respect to the number of monomers, N , and hence the estimate at some N should be valid practically over a wide range of N for various polymer models. Interestingly, the ratio is determined by the average crossing number (N{AC}) of an ideal conformation of knotted curve K , i.e., that of the ideal knot. The N{AC} of ideal knots should therefore be fundamental in the dynamics of knots.

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