ABSTRACT
Phosphorus (P) is the key in maintaining food security and ecosystem functions. Population growth and economic development have increased the demand for phosphate rocks. China has gradually developed from zero phosphate mining to the world's leading P miner, fertilizer, and agricultural producer since 1949. China released policies, such as designating phosphate rock as a strategic resource, promoting eco-agricultural policies, and encouraging the use of solid wastes produced in mining and the phosphorus chemical industry as construction materials. However, methodological and data gaps remain in the mapping of the long-term effects of policies on P resource efficiency. Here, P resource efficiency can be represented by the potential of the P cycle to concentrate or dilute P as assessed by substance flow analysis (SFA) complemented by statistical entropy analysis (SEA). P-flow quantification over the past 70 years in China revealed that both resource utilization and waste generation peaked around 2015, with 20 and 11 Mt of mined and wasted P, respectively. Additionally, rapidly increasing aquaculture wastewater has exacerbated pollution. The resource efficiency of the Chinese P cycle showed a U-shaped change with an overall improvement of 22.7%, except for a temporary trough in 1975. The driving force behind the efficiency decline was the roaring phosphate fertilizer industry, as confirmed by the sharp increase in P flows for both resource utilization and waste generation from the mid-1960s to 1975. The positive driving forces behind the 30.7% efficiency increase from 1975 to 2018 were the implementation of the resource conservation policy, downstream pollution control, and, especially, the circular agro-food system strategy. However, not all current management practices improve the P resource efficiency. Mixing P industry waste with construction materials and the development of aquaculture to complement offshore fisheries erode P resource efficiency by 2.12% and 9.19%, respectively. With the promotion of a zero-waste society in China, effective P-cycle management is expected.
Subject(s)
Economic Development , Phosphorus , China , Fertilizers , AgricultureABSTRACT
This study investigated the trade-off between energy saving and N2O emission reduction of WWTP under the precise control of dissolved oxygen (DO) concentration through model simulation. A long-term dynamic model for full-scale WWTP GHG emissions was established and calibrated with monitored year-round hourly water quality data to quantify the annual GHG emissions from WWTP. Results showed that N2O dominated the direct emission, up to 76.1%, and the variability of N2O generation could better be revealed by dynamic simulation. Furthermore, GHG emissions of the WWTP were mainly contributed by electric energy, among which the blower consumes the most electricity. To reduce the electricity consumption of blowers, improve mechanical efficiency and reduce DO concentration should be considered. DO setting played a significant role in the N2O and CH4 emission, electricity consumption and effluent quality, which was challenging to balance. The ultralow-oxygen (0-1/0.2-1 mg/L) and low oxygen (1-2 mg/L) control strategies were proposed, and their effects on total GHG emissions and effluent water quality were discussed. If the anaerobic environment (DO<0.2 mg/L)could be avoided, the control frequency (high and low) of the DO set-point did not have a significant effect on the emissions of N2O and CH4 and the effluent quality. The ultralow-oxygen strategy (0.2-1 mg/L) with a high-frequency control strategy achieved the lowest GHG emissions under the current energy mix. However, by 2050, as the energy supply gets cleaner, the total GHG emissions of WWTPs with ultralow-oxygen aeration (0.2-1 mg/L) will exceed low-oxygen aeration by 3.6%-4.2%, as N2O dominates 61.6%. Therefore, considering the trade-off between N2O emission and energy saving in WWTP, ultralow-oxygen aeration is a transition scheme to cleaner energy.
