ABSTRACT
The preparation and characterization of certified reference materials (CRMs) for radionuclide content in sediments collected offshore of Bikini Atoll (IAEA-410) and in the open northwest Pacific Ocean (IAEA-412) are described and the results of the certification process are presented. The certified radionuclides include: (40)K, (210)Pb ((210)Po), (226)Ra, (228)Ra, (228)Th, (232)Th, (234)U, (238)U, (239)Pu, (239+240)Pu and (241)Am for IAEA-410 and (40)K, (137)Cs, (210)Pb ((210)Po), (226)Ra, (228)Ra, (228)Th, (232)Th, (235)U, (238)U, (239)Pu, (240)Pu and (239+240)Pu for IAEA-412. The CRMs can be used for quality assurance and quality control purposes in the analysis of radionuclides in sediments, for development and validation of analytical methods and for staff training.
Subject(s)
Geologic Sediments/analysis , Radioisotopes/analysis , Radioisotopes/standards , Radiometry/standards , Soil Pollutants, Radioactive/analysis , Soil Pollutants, Radioactive/standards , Certification/standards , Geologic Sediments/chemistry , Micronesia , Pacific Ocean , Radioisotopes/chemistry , Reference Values , Soil Pollutants, Radioactive/chemistryABSTRACT
A Certified Reference Material (CRM) for radionuclides in seaweed (Fucus vesiculosus) from the Baltic Sea (IAEA-446) is described and the results of the certification process are presented. The (40)K, (137)Cs, (234)U and (239+240)Pu radionuclides were certified for this material, and information values for 12 other radionuclides ((90)Sr, (99)Tc, (210)Pb ((210)Po), (226)Ra, (228)Ra, (228)Th, (230)Th, (232)Th, (235)U, (238)U, (239)Pu and (240)Pu) are presented. The CRM can be used for Quality Assurance/Quality Control of analysis of radionuclides in seaweed and other biota samples, as well as for development and validation of analytical methods, and for training purposes.
Subject(s)
Seaweed/chemistry , Water Pollutants, Radioactive/analysis , Baltic States , Reference Standards , Water Pollutants, Radioactive/standardsABSTRACT
The second part of an intercomparison of the coincidence summing correction methods is presented. This exercise concerned three volume sources, filled with liquid radioactive solution. The same experimental spectra, decay scheme and photon emission intensities were used by all the participants. The results were expressed as coincidence summing corrective factors for several energies of (152)Eu and (134)Cs, and different source-to-detector distances. They are presented and discussed.
Subject(s)
Algorithms , Artifacts , Radioisotopes/analysis , Radioisotopes/standards , Radiometry/methods , Radiometry/standards , Spectrometry, Gamma/methods , Half-Life , Internationality , Radiation Dosage , Radioisotopes/chemistry , Reference Standards , Reference ValuesABSTRACT
Five different numerical algorithms used for calculating coincidence summing corrections (CSCs) in HPGe gamma-spectrometry in case of complex radionuclide decay schemes were tested for their equivalence. Simulated point-source detection geometries and efficiency curves have been used to calculate and compare counting rates as well as CSCs of (133)Ba, (134)Cs and (152)Eu of 1MBq sources. Contributions of one X-ray per radionuclide were included. The algorithms were found to give identical results within their respective presuppositions.
ABSTRACT
It is shown how the decision threshold, the detection limit and the limits of a coverage interval - summarily called the characteristic limits - and, in addition, the best estimate and the associated standard uncertainty of a non-negative radiation measurand are to be calculated by using the Monte Carlo (MC) method in ionising-radiation measurements. The limits are mathematically defined by means of quantiles of the Bayesian distributions of the possible measurand values. The MC-induced uncertainties of the limits and typical problems connected with MC application are also treated. The paper can serve as a bridge between the ISO Guide to the Expression of Uncertainty in Measurement (GUM), Supplement 1 applying the MC method and ISO/FDIS 11929 (at present in preparation) dealing with the characteristic limits. As an illustration, a net count rate measurand, being the difference of a gross and a background count rate, is treated theoretically and numerically. More complex examples deal with the wipe test for surface contamination and with a linear multi-channel spectrum unfolding.
Subject(s)
Models, Statistical , Radiometry/methods , Computer Simulation , Monte Carlo Method , Radiation Dosage , Scattering, RadiationABSTRACT
A new Certified Reference Material (CRM) for radionuclides in sediment (IAEA-385) is described and the results of the certification process are presented. Eleven radionuclides ((40)K, (137)Cs, (226)Ra, (228)Ra, (230)Th, (232)Th, (234)U, (238)U, (238)Pu, (239+240)Pu and (241)Am) have been certified and information mass activities with 95% confidence intervals are given for seven other radionuclides ((90)Sr, (210)Pb((210)Po), (235)U, (239)Pu, (240)Pu and (241)Pu). Results for less frequently reported radionuclides ((60)Co, (99)Tc, (134)Cs, (155)Eu, (224)Ra and (239)Np) and information on some activity and mass ratios are also reported. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in sediment samples, for the development and validation of analytical methods and for training purposes.
Subject(s)
Geologic Sediments/analysis , Practice Guidelines as Topic , Radiation Monitoring/standards , Radioisotopes/analysis , Radioisotopes/standards , Ireland , Oceans and Seas , Radiation Dosage , Reference ValuesABSTRACT
After the nuclear reactor accident of Chernobyl, the "Integrated Measurement and Information System (IMIS) for Monitoring the Environmental Radioactivity and Detecting Emissions from Nuclear Plants was implemented in Germany. IMIS is a nationwide comprehensive measuring system which permanently monitors the radioactivity in all important environment media in the whole federal territory. At approximately 40 sites, the activity concentration of radioactive substances is measured in air and precipitations. At least 14 of them are responsible for trace monitoring of radionuclides in the air. The legal bases of IMIS prescribe regular inter-laboratory comparison analyses in cooperation with the Physikalisch-Technische Bundesanstalt (PTB), with the use of reference materials prepared by the Federal Coordinating Laboratories. In order to fulfil this requirement in the field of trace survey measurements in ground-level air, the Federal Office for Radiation Protection ("Bundesamt für Strahlenschutz", BfS) and the PTB have conducted a comparison with real, dust-loaded reference filters in 2005. The comparison was organized within the framework of a cooperation of trace survey stations from Austria, Germany and Switzerland. The paper describes the preparation of the real, dust-loaded reference filters, the procedure for spiking the filters with the activity standard solution containing (22)Na, (88)Y, (89)Sr, (90)Sr, (125)Sb, (133)Ba, (134)Cs, and (241)Am. Some results are discussed and conclusions are given.
Subject(s)
Aerosols , Air Pollutants, Radioactive/analysis , Environmental Monitoring/methods , LaboratoriesABSTRACT
A certified reference material (CRM) for radionuclides in fish sample IAEA-414 (mixed fish from the Irish Sea and North Seas) is described and the results of the certification process are presented. Nine radionuclides (40K, 137Cs, 232Th, 234U, 235U, 238U, 238Pu, 239+240Pu and 241Am) were certified for this material. Information on massic activities with 95% confidence intervals is given for six other radionuclides (90Sr, 210Pb(210Po), 226Ra, 239Pu, 240Pu 241Pu). Less frequently reported radionuclides (99Tc, 129I, 228Th, 230Th and 237Np) and information on some activity and mass ratios are also included. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in fish sample, for the development and validation of analytical methods and for training purposes. The material is available from IAEA, Vienna, in 100 g units.
Subject(s)
Fishes/metabolism , Guidelines as Topic , Radiation Monitoring/methods , Radiation Monitoring/standards , Radioisotopes/analysis , Radioisotopes/standards , Reference Standards , Animals , International Cooperation , Ireland , Oceans and Seas , Radiation Dosage , Reference Values , Reproducibility of Results , Sensitivity and SpecificityABSTRACT
The International Atomic Energy Agency (IAEA) carried out an international project. 'The Study of the Radiological Situation at the Atolls of Mururoa and Fangataufa' with the aim of assessing the present and future radiological situation at the atolls and making recommendations for either monitoring or remedial actions if they are deemed necessary. The paper concentrates on marine radioactivity aspects and gives an estimation of present radionuclide concentrations in water, sediment and biota of the Mururoa and Fangataufa lagoons and the surrounding ocean. The dominant radionuclide in both lagoons is Pu in sediments (the total inventory is approximately 30 TBq). A decline in radionuclide concentrations has been observed in recent years in lagoon water, with the exception of 3H and 90Sr, for which a contribution from underground sources is to be expected. Radionuclide concentrations in biota from the lagoons and the surrounding ocean are low and consistent with previous measurements. The observed radionuclide concentrations in both lagoons imply that no radiological risk exists for hypothetical inhabitants of Mururoa and Fangataufa Atolls.
