Flower shaped Bi2O2.33/Bi2WO6 composite: An efficient photocatalyst for degradation of methylene blue from aqueous solution in direct solar light.

Herein, we synthesized a Bi2O2.33/Bi2WO6 heterostructure as a platform for the degradation of methylene blue (MB) dye in an aqueous phase. The heterostructure was synthesized by facile ultrasonicated assisted solvothermal method. Various structural, morphological and other techniques such as XRD, FTIR, PL, EIS, UV-DRS, FESEM, HRTEM, XPS, EPR, TGA, BET surface area were used to analyze the characteristics of as-synthesized Bi2O2.33/Bi2WO6. The morphological studies revealed the deposition of Bi2O2.33 flowers in high density on Bi2WO6. Under solar irradiation, 98.6% degradation of MB was achieved in 190 min at optimal conditions (pH = 5, catalyst dose = 0.35 gL-1 and MB concentration = 10 mgL-1). The improved photocatalytic ability of composite in contrast to Bi2O2.33 and Bi2WO6 could be usually ascribed to the interface created between them, assisting the charge transfer. Based on the findings of radical trapping experiments, the charge transfer process over the photocatalyst was completely studied. Additionally, the present heterostructure demonstrated good recyclability over five runs. In nutshell, this study provided a facile approach for synthesizing solar light driven photocatalyst for degradation of methylene blue in aqueous phase and can further explored to be utilized for varied environmental remediation.

Solar-light-driven photocatalytic degradation of pharmaceutical pollutants utilizing 2D g-C3N4/BiOCl composite.

Pharmaceuticals, which have been praised for protecting countless lives, have become a new category of environmental pollutants in recent decades as most of these pharmaceutical compounds are discovered in water bodies in concentrations ranging from ng/L to mg/L. Recently, metal-free g-C3N4 (GCN)-based composites have received considerable attention for the degradation of pharmaceutical compounds. In this study, GCN/BiOCl composite was prepared using a simple ultrasonication-assisted stirring method and characterized using various analytical and spectroscopic techniques including XRD, FTIR, PL, Elemental mapping, UV-DRS, FESEM, HRTEM, and TGA. The as-prepared composite was utilized to degrade levofloxacin (LVX) under solar light irradiation and showed excellent stability for the degradation of LVX. Furthermore, the universality of the GCN/BiOCl composite was investigated by degrading diverse pharmaceuticals such as ofloxacin (OFX), norfloxacin (NOX), ciprofloxacin (COX), and ketorolac tromethamine (KTC) in an aqueous phase. Therefore, this work provides an effective method to degrade pharmaceutical contaminants simultaneously in water using GCN/BiOCl composite.

Construction of multifunctional NH2-UiO-66 metal organic framework: sensing and photocatalytic degradation of ketorolac tromethamine and tetracycline in aqueous medium.

Existence of pharmaceutical residues in water has endangered environmental pollution worldwide, which makes it ineludible to develop prospective bifunctional materials which not only possess excellent fluorescence behaviour to monitor pharmaceuticals but also exhibit simultaneous photocatalytic removal efficiency. Strengthened by functionalized metal organic framework (MOF) materials, we present here an amine functionalized zirconium-based MOF NH2-UiO-66 which has been successfully synthesized using solvothermal approach. The as prepared MOF was subjected to numerous structural, morphological and compositional characterizations. Interestingly, featured by the excellent fluorescent intensity of MOF modulated by LMCT effect, NH2-UiO-66 was screened to detect pharmaceutical compounds with KTC and TC in aqueous solution. The prepared functionalized MOF showcased excellent sensing platform with magnificent response range (0‒3 µM), lower limit of detection (160 nM; KTC and 140 nM; TC), excellent selectivity and influential anti-interference capability. More importantly, the practical utility of the proposed sensor was further explored for the determination of pharmaceutical drugs in real water samples with suitable recoveries. Simultaneously, the synthesized MOF also exhibited high photocatalytic efficiency towards the removal of KTC and TC under solar light irradiation. The degradation efficiency for KTC and TC was found to be 68.3% and 71.8% within 60 and 280 min of solar light, respectively. Moreover, excellent recyclability was demonstrated by the current synthesized system over five cycles. Overall, this study presents a feasible route for the utilization of functionalized MOFs as potential dual functional materials towards the simultaneous detection and degradation of specific pharmaceuticals from aqueous medium.

Highly fluorescent nickel based metal organic framework for enhanced sensing of Fe3+ and Cr2O72- ions.

Heavy metal contamination has sparked widespread concern among the populace. The significant issues necessitate the creation of high-performance fluorescent pigments that can identify harmful elements in water. The present study deals with metal organic framework [MOF] based on nickel [Ni-BDC MOF]. The Ni-BDC MOF was prepared by facile solvothermal method using nickel nitrate hexahydrate and terephthalic acid ligand as precursors. The MOF was characterized by various techniques in order to examine the crystal, morphological, structural, composition, thermal and optical properties. The detailed characterizations revealed that the synthesized Ni-BDC MOF are well-crystalline with high purity and possessing 3D rhombohedral microcrystals with rough surface. The MOF demonstrate good luminescence performance and excellent water stability. According to the Stern Volmer plot, the tests set up under optimized conditions demonstrate a linear correlation between the fluorescence intensity and concentration of both ions, i.e. Fe3+, and Cr2O72- ions. The linear range and detection limit for Fe3+ and Cr2O72- were found to be 0-1.4 nM and 0.159 nM, and 0-1 nM and 0.120 nM, respectively. The mechanisms for the selective detection of cations and anions were also explored. The recyclability for the prepared MOF was checked up to five cycles which showed excellent stability with just a slight reduction in efficiency. The constructed sensor was also used to assess the presence of Fe3+ and Cr2O72- ions in actual water samples. The results of the different experiments revealed that the prepared MOF is a good material for detecting Fe3+ and Cr2O72- ions.

rGO-WO3 Heterostructure: Synthesis, Characterization and Utilization as an Efficient Adsorbent for the Removal of Fluoroquinolone Antibiotic Levofloxacin in an Aqueous Phase.

Herein, the heterostructure rGO-WO3 was hydrothermally synthesized and characterized by HRTEM (high-resolution transmission electron microscopy), FESEM (field emission scanning electron microscopy), XRD (X-ray diffraction), FT-IR (Fourier transform infrared spectroscopy), XPS (X-ray photoelectron microscopy), nitrogen physisorption isotherm, Raman, TGA (thermogravimetric analysis) and zeta potential techniques. The HRTEM and FESEM images of the synthesized nanostructure revealed the successful loading of WO3 nanorods on the surface of rGO nanosheets. The prepared heterostructure was utilized as an efficient adsorbent for the removal of a third-generation fluoroquinolone antibiotic, i.e., levofloxacin (LVX), from water. The adsorption equilibrium data were appropriately described by a Langmuir isotherm model. The prepared rGO-WO3 heterostructure exhibited a Langmuir adsorption capacity of 73.05 mg/g. The kinetics of LVX adsorption followed a pseudo-second-order kinetic model. The adsorption of LVX onto the rGO-WO3 heterostructure was spontaneous and exothermic in nature. Electrostatic interactions were found to have played a significant role in the adsorption of LVX onto the rGO-WO3 heterostructure. Thus, the prepared rGO-WO3 heterostructure is a highly promising material for the removal of emerging contaminants from aqueous solution.

Dual Fluorometric Detection of Fe3+ and Hg2+ Ions in an Aqueous Medium Using Carbon Quantum Dots as a "Turn-off" Fluorescence Sensor.

The present study aimed to develop a carbon dots-based fluorescence (FL) sensor that can detect more than one pollutant simultaneously in the same aqueous solution. The carbon dots-based FL sensor has been prepared by employing a facile hydrothermal method using citric acid and ethylenediamine as precursors. The as-synthesized CDs displayed excellent hydrophilicity, good photostability and blue fluorescence under UV light. They have been used as an efficient "turn-off" FL sensor for dual sensing of Fe3+ and Hg2+ ions in an aqueous medium with high sensitivity and selectivity through a static quenching mechanism. The lowest limit of detection (LOD) for Fe3+ and Hg2+ ions was found to be 0.406 µM and 0.934 µM, respectively over the concentration range of 0-50 µM. Therefore, the present work provides an effective strategy to monitor the concentration of Fe3+ and Hg2+ ions simultaneously in an aqueous medium using environment-friendly CDs.

Adsorptive removal of antibiotic ofloxacin in aqueous phase using rGO-MoS2 heterostructure.

This paper reports the synthesis, characterization and detailed adsorption studies of rGO-MoS2 heterostructure. The heterostructure was explored for the adsorption of ofloxacin from the aqueous phase. Detailed studies were conducted to study the effect of crucial parameters such as pH of drug solution, adsorbent dose, temperature and initial drug concentration on the adsorption capacity. Even with a low surface area of 17.17 m2/g, the adsorbent exhibited maximum removal efficiency of 95% at a dose of 0.35 g/L and an initial drug concentration of 10 mg/L in 240 min. Thermodynamic study revealed the values for ∆H0 and ∆G0 to be - 101.15 and - 7.47 kJ/mol respectively, indicating that the process is spontaneous and exothermic in nature. The heterostructure adsorbent exhibited remarkable reusability and stability up to five cycles. The heterostructure combines excellent adsorption capabilities arising from the two-dimensional structures of rGO and MoS2 with the stronger and more specific interaction with the drug molecules which results in better performance towards the removal of the drug. The excellent performance of the heterostructure indicates that combining 2D materials can be a good strategy for producing highly efficient materials towards the adsorptive removal of pollutants.

Bi2WO6/C-Dots/TiO2: A Novel Z-Scheme Photocatalyst for the Degradation of Fluoroquinolone Levofloxacin from Aqueous Medium.

Photocatalytic materials and semiconductors of appropriate structural and morphological architectures as well as energy band gaps are materials needed for mitigating current environmental problems, as these materials have the ability to exploit the full spectrum of solar light in several applications. Thus, constructing a Z-scheme heterojunction is an ideal approach to overcoming the limitations of a single component or traditional heterogeneous catalysts for the competent removal of organic chemicals present in wastewater, to mention just one of the areas of application. A Z-scheme catalyst possesses many attributes, including enhanced light-harvesting capacity, strong redox ability and different oxidation and reduction positions. In the present work, a novel ternary Z-scheme photocatalyst, i.e., Bi2WO6/C-dots/TiO2, has been prepared by a facile chemical wet technique. The prepared solar light-driven Z-scheme composite was characterized by many analytical and spectroscopic practices, including powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), N2 adsorption-desorption isotherm, Fourier-transform infrared spectroscopy (FT-IR), photoluminescence (PL) and UV-vis diffuse reflectance spectroscopy (DRS). The photocatalytic activity of the Bi2WO6/C-dots/TiO2 composite was evaluated by studying the degradation of fluoroquinolone drug, levofloxacin under solar light irradiation. Almost complete (99%) decomposition of the levofloxacin drug was observed in 90 min of sunlight irradiation. The effect of catalyst loading, initial substrate concentration and pH of the reaction was also optimized. The photocatalytic activity of the prepared catalyst was also compared with that of bare Bi2WO6, TiO2 and TiO2/C-dots under optimized conditions. Scavenger radical trap studies and terephthalic acid (TPA) fluorescence technique were done to understand the role of the photo-induced active radical ions that witnessed the decomposition of levofloxacin. Based on these studies, the plausible degradation trail of levofloxacin was proposed and was further supported by LC-MS analysis.

Efficient Conversion of Glucose into Fructose via Extraction-Assisted Isomerization Catalyzed by Endogenous Polyamine Spermine in the Aqueous Phase.

In the present study, natural polyamine spermine is demonstrated as a potential basic catalyst for glucose-to-fructose isomerization. For instance, spermine achieves a decent fructose yield (30% wt) and selectivity (74%) during the single-step aqueous phase isomerization under the modest operating conditions (100 °C for 15 min). In addition to the expected reaction byproduct monosugar mannose, spermine also assists in the synthesis of rare and important monosugar, that is, psicose up to 4% wt. Psicose is a zero calorie rare sugar, exhibits a low caloric value, and possesses anti-adipogenic property. A comparative study involving other polyamines concluded that the presence of 20 amines tends to exhibit the most significant impact in improving the target product yield by releasing a higher number of OH- ions, which are responsible for isomerization through the formation of an enediol anion. An attempt was made to further improve the fructose yield through the addition of neutral salts, but it promoted a meager achievement. In an alternate study, a selective extraction strategy was followed for the isolation of fructose from the reaction mixture. The employed aryl monoboronic acid remarkably improved the net fructose concentration, that is, fructose productivity up to 75% wt (cumulative) and 70% selectivity within three consecutive extractions and isomerization cycles, which is comparatively three times shorter than that reported in the literature. Notably, spermine itself provided the essential and necessary basic environment for selective fructose extraction and glucose isomerization, ruling out the use of any external reagents and thus establishing itself as a versatile material suitable for a typical isomerization reaction in an upscaled reactor.

Highly photoluminescent and pH sensitive nitrogen doped carbon dots (NCDs) as a fluorescent sensor for the efficient detection of Cr (VI) ions in aqueous media.

Fluorescent carbon dots (CDs) are contemporary class of fluorescent materials that has emerged recently and have gathered increasing attention due to its excellent properties as compared to traditional semiconductor quantum dots. CDs have lucrative benefits of less toxicity, biocompatibility, eco friendliness, tunable fluorescence, high chemical and photostability, effortless synthesis routes and uncomplicated surface modifications and functionalization. In the present work, nitrogen-doped carbon dots (NCDs) were prepared by a facile hydrothermal process using l-ascorbic acid and ethylene diamine as precursors. The as-prepared NCDs were hydrophilic in nature and could remain stable for several weeks. NCDs displayed bright blue fluorescence under UV light irradiation and also exhibited an extensive range of emission spectra in the visible region to infra-red region based upon the excitation wavelength. NCDs possessed quasi-spherical morphology and high density growth. NCDs were further utilized as nanoprobes for the pH sensing and proficient sensitive and selective detection of chromium (VI) ions present in aqueous phase. Under augmented modifications and conditions, the photoluminescence intensity of NCDs against various micromolar concentration of chromium (VI) ions presented a linear relationship, as per Stern-Volmer equation. The calibration curve was found to be linear in the range of 0-4 µM and from the slope of the linear curve, the limit of detection (LOD) was calculated to be 2.598 nM. The Stern-Volmer calibration curve was also plotted against different temperatures, verifying static quenching mechanism. Therefore, the as synthesized NCDs can be successfully demonstrated for the efficient pH sensing and the detection of Cr (VI) ions.

Solar light active silver/iron oxide/zinc oxide heterostructure for photodegradation of ciprofloxacin, transformation products and antibacterial activity.

This paper reports on the multitasking potential of a silver/iron oxide/zinc oxide (Ag/Fe2O3/ZnO) heterostructure, which was used for the photocatalytic decomposition of ciprofloxacin (CPX) and bacterial disinfection. The Ag/Fe2O3/ZnO heterostructure was successfully prepared using a facile precipitation method, and characterization results showed interesting structural, morphological, compositional and luminescent properties. The morphological results of the prepared heterostructure confirmed the deposition of Ag nanoparticles onto the surface of ZnO nanoplates and Fe2O3 nanorods. Treatment studies showed that the Ag/Fe2O3/ZnO heterostructure had superior solar light driven photocatalytic activity towards CPX degradation (76.4%) compared to bare Fe2O3 nanorods (43.2%) and ZnO nanoplates (63.1%), Ag/Fe2O3 (28.2%) and Ag/ZnO (64.5%) under optimized conditions (initial CPX concentration: 10 mg/L; pH 4; catalyst loading: 0.3 g/L). Reactive species study confirmed the roles of e-, h+, OH and O2- in the photocatalytic degradation process. This photocatalytic behaviour of the Ag/Fe2O3/ZnO heterostructure could be attributed to the improved full solar spectrum harvesting capacity, separation of charge carriers and migration of e-/h+ across the heterostructure interface. In addition, the Ag/Fe2O3/ZnO heterostructure also showed good antibacterial activity against Escherichia coli (E. coli) under both dark and visible light conditions. This might be due to generation of reactive oxygen species during the reaction. To the best of our knowledge, this is the first study till date on the utilization of Ag/Fe2O3/ZnO heterostructure for the photocatalytic degradation of CPX and E. coli bacteria disinfection. Therefore, this work offers an attractive path to design ZnO-based ternary heterostructures for solar-driven applications in wastewater remediation.

Rapid Solar-Light Driven Superior Photocatalytic Degradation of Methylene Blue Using MoS2-ZnO Heterostructure Nanorods Photocatalyst.

Herein, MoS2-ZnO heterostructure nanorods were hydrothermally synthesized and characterized in detail using several compositional, optical, and morphological techniques. The comprehensive characterizations show that the synthesized MoS2/ZnO heterostructure nanorods were composed of wurtzite hexagonal phase of ZnO and rhombohedral phase of MoS2. The synthesized MoS2/ZnO heterostructure nanorods were used as a potent photocatalyst for the decomposition of methylene blue (MB) dye under natural sunlight. The prepared MoS2/ZnO heterostructure nanorods exhibited ~97% removal of MB in the reaction time of 20 min with the catalyst amount of 0.15 g/L. The kinetic study revealed that the photocatalytic removal of MB was found to be in accordance with pseudo first-order reaction kinetics with an obtained rate constant of 0.16262 min-1. The tremendous photocatalytic performance of MoS2-ZnO heterostructure nanorods could be accredited to an effective charge transportation and inhibition in the recombination of photo-excited charge carriers at an interfacial heterojunction. The contribution of active species towards the decomposition of MB using MoS2-ZnO heterostructure nanorods was confirmed from scavenger study and terephthalic acid fluorescence technique.

Recycling of Waste Poly(ethylene terephthalate) Bottles by Alkaline Hydrolysis and Recovery of Pure Nanospindle-Shaped Terephthalic Acid.

Poly(ethylene terephthalate) (PET) is a versatile engineering plastic which exhibits exceptional mechanical and thermal properties. Huge amounts of PET are consumed in various industries such as food packaging industry, textile industry, in the manufacturing of audio, video tapes and X-ray films and so on. But due to its substantial fraction by volume in water bodies and its high persistence to the atmospheric and biological agents, it could be considered as a hazard substance. Thereby chemical recycling of PET serves as a solution to solid waste problem as it transforms PET into its monomers via hydrolysis. Chemical recycling of post consumed waste PET bottles via alkaline hydrolysis is the main aim of this paper. Operating parameters such as reaction time and temperature were optimized for the conversion of PET into nanospindle-shaped terephthalic acid (TPA). Depolymerization of PET was carried out via alkaline hydrolysis by varying reaction time and temperature and maximum yield of 92% was obtained at 200 °C with reaction time of 25 minutes. The formed TPA nanospindles were further characterized in detail which exhibited high crystallinity, purity and fascinating thermal and surface properties.

Expeditious isomerization of glucose to fructose in aqueous media over sodium titanate nanotubes.

Isomerization reaction of glucose to fructose over sodium titanate nanotubes (Na-TNTs) as a Lewis base catalyst was studied. Analytical instruments recorded the specific structural, textural and basic properties of the as-synthesized Na-TNTs. Furthermore, studying the catalytic isomerization performance of the Na-TNTs confirmed their high catalytic efficiency and suitability in aqueous media. The catalyst prompted rapid glucose isomerization within 2 min by achieving nearly half of the maximum yield, whereas with a prolonged reaction up to 15 min the maximum glucose conversion could be reached with 31.26% fructose yield and 65.26% selectivity under relatively lower operating conditions (100 °C and 10% wt catalyst dose). However, the recyclability performance of the catalyst was not impressive due to the accelerated leaching of cations and surface retention of carbonaceous content, resulting in ∼16% reduced yield after 4 runs. A simple regeneration technique using NaOH led to the initial catalytic activity being totally regained. Overall, a titania-based catalyst (preferably nanotube structured sodium titanate) was shown as a potential catalyst for large-scale demonstration of glucose isomerization to achieve high fructose productivity.

A fluorescent probe based on nitrogen doped graphene quantum dots for turn off sensing of explosive and detrimental water pollutant, TNP in aqueous medium.

This paper reports the carbonization assisted green approach for the fabrication of nitrogen doped graphene quantum dots (N-GQDs). The obtained N-GQDs displayed good water dispersibility and stability in the wide pH range. The as synthesized N-GQDs were used as a fluorescent probe for the sensing of explosive 2,4,6-trinitrophenol (TNP) in aqueous medium based on fluorescence resonance energy transfer (FRET), molecular interactions and charge transfer mechanism. The quenching efficiency was found to be linear in proportion to the TNP concentration within the range of 0-16µM with detection limit (LOD) of 0.92µM. The presented method was successfully applied to the sensing of TNP in tap and lake water samples with satisfactory results. Thus, N-GQDs were used as a selective, sensitive and turn off fluorescent sensor for the detection of perilous water contaminant i.e. TNP.

Sunlight-driven photocatalytic degradation of non-steroidal anti-inflammatory drug based on TiO2 quantum dots.

This paper reports the facile synthesis, characterization and solar-light driven photocatalytic degradation of TiO2 quantum dots (QDs). The TiO2 QDs were synthesized by a facile ultrasonic-assisted hydrothermal process and characterized in terms of their structural, morphological, optical and photocatalytic properties. The detailed studies confirmed that the prepared QDs are well-crystalline, grown in high density and exhibiting good optical properties. Further, the prepared QDs were efficiently used as effective photocatalyst for the sun-light driven photocatalytic degradation of ketorolac tromethamine, a well-known non-steroidal anti-inflammatory drug (NSAID). To optimize the photocatalytic degradation conditions, various dose-dependent, pH-dependent, and initial drug-concentration dependent experiments were performed. The detailed solar-light driven photocatalytic experiments revealed that ∼99% photodegradation of ketorolac tromethamine drug solution (10 mg L(-1)) was observed with optimized amount of TiO2 QDs and pH (0.5 g L(-1) and 4.4, respectively) under solar-light irradiations. The observed results demonstrate that simply synthesized TiO2 QDs can efficiently be used for the solar-light driven photocatalytic degradation of harmful drugs and chemicals.

Highly effective Fe-doped TiO2 nanoparticles photocatalysts for visible-light driven photocatalytic degradation of toxic organic compounds.

This paper reports the synthesis of various molar concentrations of iron (Fe)-doped TiO2 nanoparticles and their efficient use as potential photocatalysts for photocatalytic degradation of toxic and harmful chemical, paranitrophenol. The nanoparticles were synthesized by a novel and facile ultrasonic assisted hydrothermal method and characterized in detail by various analytical techniques in terms of their morphological, structural, compositional, thermal, optical, pore size distribution, etc properties. The photocatalytic activities of the as-prepared Fe-doped TiO2 nanoparticles were examined under visible light illumination using para-nitrophenol as target pollutant. By detailed experimental findings revealed that the Fe dopant content crucially determines the catalytic activity of TiO2 nanoparticles. The maximum degradation rate of para-nitrophenol observed was 92% in 5 h when the Fe(3+) molar concentration was 0.05 mol%, without addition of any oxidizing reagents. The prepared nanoparticles demonstrated excellent photocatalytic response because of their small size, excellent crystalline structure, increase in threshold wavelength response and maximum separation of photogenerated charge carriers. Further, the determination of reaction intermediates has also been carried out and plausible mechanism of photocatalytic degradation of para-nitrophenol has been proposed.

Well-crystalline porous ZnO-SnO2 nanosheets: an effective visible-light driven photocatalyst and highly sensitive smart sensor material.

This work demonstrates the synthesis and characterization of porous ZnO-SnO2 nanosheets prepared by the simple and facile hydrothermal method at low-temperature. The prepared nanosheets were characterized by several techniques which revealed the well-crystallinity, porous and well-defined nanosheet morphology for the prepared material. The synthesized porous ZnO-SnO2 nanosheets were used as an efficient photocatalyst for the photocatalytic degradation of highly hazardous dye, i.e., direct blue 15 (DB 15), under visible-light irradiation. The excellent photocatalytic degradation of prepared material towards DB 15 dye could be ascribed to the formation of ZnO-SnO2 heterojunction which effectively separates the photogenerated electron-hole pairs and possess high surface area. Further, the prepared porous ZnO-SnO2 nanosheets were utilized to fabricate a robust chemical sensor to detect 4-nitrophenol in aqueous medium. The fabricated sensor exhibited extremely high sensitivity of ~ 1285.76 µA/mmol L(-1)cm(-2) and an experimental detection limit of 0.078 mmol L(-1) with a linear dynamic range of 0.078-1.25 mmol L(-1). The obtained results confirmed that the prepared porous ZnO-SnO2 nanosheets are potential material for the removal of organic pollutants under visible light irradiation and efficient chemical sensing applications.

Development of molecularly imprinted microspheres for the fast uptake of 4-cumylphenol from water and soil samples.

Molecularly imprinted microspheres containing binding sites for the extraction of 4-cumylphenol have been prepared for the first time. The imprinted microspheres were synthesized by a precipitation method using 4-cumylphenol as a template molecule, methacrylic acid as a functional monomer and divinylbenzene-80 as a cross-linker for polymer network formation. The formation and the morphology of molecularly imprinted microspheres were well characterized using infrared spectroscopy, thermogravimetric studies, and scanning electron microscopy. The Brunauer-Emmett-Teller analysis revealed the high surface area of the sorbent indicating formation of molecularly imprinted microspheres. The developed microspheres were employed as a sorbent for the solid-phase extraction of 4-cumylphenol and showed fast uptake kinetics. The sorption parameters were optimized to achieve efficient sorption of the template molecule, like pH, quantity of molecularly imprinted microspheres, time required for equilibrium set-up, sorption kinetics, and adsorption isotherm. A standard method was developed to analyze the sorbed sample quantitatively at 279 nm using high-performance liquid chromatography with diode array detection. It was validated by determining target analyte from synthetic samples, bottled water, spiked tap water, and soil samples. The prepared material is a selective and robust sorbent with good reusability.

Metal assisted approach to develop molecularly imprinted mesoporous material exhibiting pockets for the fast uptake of diethyl phthalate as copper complex.

A new molecularly imprinted mesoporous material (MIM) containing specific pockets for the extraction of diethyl phthalate (DEP) as copper complex has been prepared for the first time. The mesoporous material was developed by utilizing copper-phthalate complex (Cu-DEP) as the template molecule, 3-aminopropyltriethoxysilane (APS) as a functional monomer and tetraethoxyorthosilicate (TEOS) as the silica source for polymer network formation. The mesoporous material showed fast uptake kinetics, and equilibrium was obtained within 30 min due to the introduction of copper, which provides an additional site for interaction with the functional monomer. Synthesized polymer was well characterized using UV-Vis spectrophotometry, IR spectroscopy, TGA studies, and TEM. To achieve efficient extraction of the template molecule, various factors including sorption kinetics, quantity of MIM, time required for equilibrium set-up, sorption isotherm and reuse of MIM were optimized. The extracted DEP samples were analyzed quantitatively at 310 nm using an HPLC-DA system. The prepared material is robust and can be reused. In addition, it was found to be selective for DEP as compared to other phthalates.