ABSTRACT
A comparison between the temperatures within imploding acoustic cavitation bubbles and the extent of sonoluminescence (SL) quenching by C(1)-C(5) aliphatic alcohols in 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM][EtSO(4)], a well known imidazolium based room temperature ionic liquid (RTIL)), has been made at an ultrasound frequency of 213 kHz. The temperatures obtained ranged from 3500 ± 200K, in neat [EMIM][EtSO(4)], to about 3200 ± 200K in RTIL-alcohol containing solutions. It was also found that the SL intensity decreased with increasing concentration (up to 1M) of the alcohols to a greater extent compared with the relative changes to the bubble temperatures. Both the extent of the reduction in the bubble temperatures and the SL quenching were much smaller than those obtained in comparable aqueous solutions containing aliphatic alcohols. Possible reasons for the differences in the observed trends between water/alcohol and [EMIM][EtSO(4)]/alcohol systems under sonication at 213 kHz are discussed.
ABSTRACT
The multibubble sonoluminescence (MBSL) intensities from water exposed to the simultaneous ultrasonic irradiation from 20 kHz (fixed at 6.3 W) and 355 kHz (variable power) ultrasound sources have been compared to the MBSL from the individual ultrasound sources under the same power conditions. A synergistic enhancement of the sonoluminescence (SL) signal, >30-fold, at low powers (4.6 W) of the higher frequency was observed. At a higher acoustic power level (15.8 W) the dual frequency operation produced a decrease in the SL signal. These results are in agreement with previously reported data [P. Ciuti, N.V. Dezhkunov, A. Francescutto, F. Calligaris, F. Sturman, Ultrasonics Sonochem. 10 (2003) 337; N.V. Dezhkunov, J. Eng. Phys. Therm. 76 (2003) 142] under similar experimental conditions. Numerical single bubble (SB) dynamics calculations have been used to help interpret the experimental results. It is suggested that the observed effects are caused by a combination of changes to the peak collapse temperature of individual bubbles as well as to changes in the active bubble population.
Subject(s)
Luminescence , Ultrasonics , Algorithms , Models, Statistical , Pressure , Temperature , Water/chemistryABSTRACT
In the present work, a cavity cluster of predetermined size has been considered to study the bubble dynamics in the hydrodynamic cavitation reactor. The effect of different operating and system parameters on the cavitational intensity has been numerically investigated. The yield of any cavitationally induced physical/chemical transformations depends not only on the collapse pressure of the cavities but also on the active volume of cavitation within the reactor. Empirical correlations have been developed to predict the collapse pressure and the active volume of cavitation as a function of different operating parameters based on the bubble dynamics studies. Recommendations are made for designing a cavitational reactor on the basis of the proposed empirical correlations. This work is a first step towards the designing and optimization of hydrodynamic cavitational reactor with cluster approach.
ABSTRACT
The erratic behaviour of cavitational activity exhibited in a sonochemical reactor pose a serious problem in the efficient design and scale-up; thus it becomes important to identify the active and passive zones existing in the reactor so as to enable proper placement of the reaction mixtures for achieving maximum benefits. In the present work mapping of ultrasonic horn has been carried with the help of local pressure measurement using a hydrophone and estimation of amount of liberated iodine using the Weissler reaction and a quantitative relationship has been established. The measured local pressure pulses have been used in the theoretical simulations of the bubble dynamics equations to check the type of cavitation taking place locally and also estimate the possible collapse pressure pulse in terms of maximum bubble size reached during the cavitation phenomena. Relationship has been also established between the observed iodine liberation rates and the maximum bubble size reached. The engineers can easily use these unique relationships in efficient design, as the direct quantification of the secondary effect is possible.
ABSTRACT
The mechanism involved in the spectacular effects from cavitation phenomenon is very complex and there have been several proposed theories to explain the observed results. The experimental as well as the visual observations indicate that a single collapsing cavity is also influenced by the dynamics of the surrounding cavities, which are very near to the collapsing cavity. The observed effects and erosion patterns cannot be explained properly on the basis of a single cavity collapse and hence in this study a cavity cluster (group of cavities) has been considered to understand the mechanism of cavitational effects. The effect of intensity, frequency of ultrasound, initial size of the cluster and the fraction of energy transferred from the collapsing cavities to the surrounding cavities on the cavitational intensity quantified in terms of the pressure pulse generated at the collapse of cavities as well as the active zone of cavitation has been investigated using bubble/cavity dynamics equations, numerically. On the basis of the trends obtained, empirical correlations estimating the collapse pressure and active volume of cavitation, have been developed.
