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Org Lett ; 3(20): 3125-7, 2001 Oct 04.
Article in English | MEDLINE | ID: mdl-11574011

ABSTRACT

[reaction: see text] The pharmacologically important tetracyclic berbane and pentacyclic alloyohimbane structures were prepared efficiently in four steps including a stereoselective 6-exo radical cyclization using xanthates as the radical source.


Subject(s)
Berberine Alkaloids/chemical synthesis , Secologanin Tryptamine Alkaloids/chemical synthesis , Stereoisomerism
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