Effect of Mixed Morphology (Simple Cubic, Face-Centered Cubic, and Body-Centered Cubic)-Based Electrodes on the Electric Double Layer Capacitance of Supercapacitors.

Supercapacitors store energy due to the formation of an electric double layer (EDL) at the interface of the electrodes and electrolyte. The present article deals with the finite element study of equilibrium electric double layer capacitance (EDLC) in the mixed morphology electrodes comprising all three fundamental crystal structures, simple cubic (SC), body-centered cubic (BCC), and face-centered cubic morphologies (FCC). Mesoporous-activated carbon forms the electrode in the supercapacitor with (C2H5)4NBF4/propylene carbonate organic electrolyte. Electrochemical interference is clearly demonstrated in the supercapacitors with the formation of the potential bands, as in the case of interference theory due to the increasing packing factor. The effects of electrode thickness varying from a wide range of 50 nm to 0.04 mm on specific EDLC have been discussed in detail. The interfacial geometry of the unit cell in contact with the electrolyte is the most important parameter determining the properties of the EDL. The critical thickness of the electrodes is 1.71 µm in all the morphologies. Polarization increases the interfacial potential and leads to EDL formation. The Stern layer specific capacitance is 167.6 µF cm-2 in all the morphologies. The maximum capacitance is in the decreasing order of interfacial geometry, as FCC > BCC > SC, dependent on the packing factor. The minimum transmittance in all the morphologies is 98.35%, with the constant figure of merit at higher electrode thickness having applications in the chip interconnects. The transient analysis shows that the interfacial current decreases with increasing polarization in the EDL. The capacitance also decreases with the increase of the scan rate.

Effect of simple cubic, face-centered cubic, and body-centered cubic-electrodes on the electric double layer capacitance of supercapacitors.

The continuum theory has been used to analyze the polarization, ion crowding, and electrostatic forces of the electric double layer in the electrode materials having simple cubic (SC), body-centered cubic (BCC), and face-centered cubic (FCC) morphologies. The study manifests the effect of thickness of electrodes, electrode's particle size, and porosity on electric double-layer specific capacitance (EDLC). Electrochemical interference and the specific capacitance depend on the packing factor. The larger particle size decreases the specific capacitance, but porosity increases due to more surface area. Due to symmetry, SC, BCC, and FCC morphologies have 1, 3, and 5 spheres in a unit cell. The number of unit cells is varied from 1 to 100 in model 1 to analyze the effect of electrode thickness. Model 2 has three unit cells to understand the effect of porosity, and only pore lengths are varied. The critical thickness of the electrodes is the integer multiples of 1.71µm in all the morphologies. The Stern layer-specific capacitance is 167.6µF cm-2in all cases. The EDLC in BCC is around 5.6-7.6µF cm-2in the steady state that is intermediate between SC and FCC morphologies. The more dense packing of carbon particles in a unit cell increases the energy storage capabilities of electrodes. The average electrode permittivity slightly decreases due to the combined effect of the high electric field, status of polarization, and electrode particle size. The least optical transmission of electrodes is 98.35%.

A review on multi-synergistic transition metal oxide systems towards arsenic treatment: Near molecular analysis of surface-complexation (synchrotron studies/modeling tools).

The science and interface chemistry between the arsenic (As) anions and the different adsorbent systems have been gaining interest in recent years in environmental remediation applications. Metal-oxides and the corresponding hybrid systems have shown promising performance as novel adsorbents in various treatment technologies. The abundance, surface chemistry, high surface area (active-centres), various synthesis and functionalization methodologies, and good recyclability make these metal oxide-based nanomaterials as potential remediating agents for As oxyanions. This work critically reviews eight different platforms focused on the arsenic contamination issue, where the first classification describes the origin of arsenic contamination and presents geographical and demo-graphical considerations. The following section briefs the state-of-the-art remediation techniques for arsenic treatment with a comparative evaluation. An emphasized discussion has been provided regarding the adsorption and classification of various metal oxide adsorbents. In the next classification, various multi-synergism abilities like Redox activity, Surface functional groups, Surface area/morphology, Heterogeneous catalysis, Reactive oxygen species, Photo-catalytic/electro-catalytic reactions, and Electrosorption are detailed. The classification of various characterization tools for accessing the arsenic remediation qualitatively and quantitatively are given in the fifth chapter. The first-of-its-kind dedicated analysis has been given on the surface complexation aspects of the arsenic speciation onto various metal adsorbent systems using synchrotron results, surface-complexation modeling, and molecular simulation (e.g., DFT) in the sixth chapter. The current sensing applications of these novel nano-material systems for arsenic determination using colorimetric and electrochemical-based analytical tools and a note about the economic parameters, i.e., regeneration aspects of various adsorbent systems/the sustainable applications of the treated sludge materials, are provided in the final sections. This work makes a critical analysis of 'Environmental Nanotechnology' towards 'Arsenic Treatment'.

Anti-bacterial and arsenic remediation insights in aqueous systems onto heterogeneous metal oxide (Cu0.52Al0.1Fe0.47O4)/rGO hybrid: an approach towards airborne microbial degradation.

Copper-based ternary metal oxide (i.e., Cu0.52Al0.01Fe0.47O4) impregnated reduced graphene oxide nanohybrid is verified for microbial and arsenic treatment. Growth inhibition of colonies are observed around 99.99% (E. coli), and 99.83% (S. aureus) at 10-20 µg/mL of hybrid dosage, respectively. The inhibition rates for both the colonies are increased to 99.9998% at 80 µg/mL. TEM images have shown insight of cell-content/lipid leakage behavior after inoculating with the hybrid. The efficient hindrance towards microbial colony growth is attributed to better charge transfer, reactive oxygen species generation, and metal-ion release. Maximum arsenic sorption capacities are observed around 248 and 314 mg/g for As(III), and As(V), respectively (Ci ~ 500 ppm). Surface morphology studies onto arsenic adsorption are reported with atomic force microscope, and FT-IR/Raman analysis. A detailed discussion onto individual spectra of As 3d spectra confirmed the occurrence of redox transformation in arsenic species [As(III)]. The variation in the quantity (at. %) of oxygen functional groups in O1s spectra (i.e., M-O, M-OH, and -OH2) onto the hybrid supported the ligand-exchange behavior. Cyclic voltammetry study in arsenic electrolytes (10 µM - 1 mM) provides the occurrence of various in-situ electrochemical reactions supporting the redox activity. A significant electromagnetic wave absorption characteristics of the present hybrid is proposed with plausible airborne antimicrobial-agent abilities.

Simulation Study of Electric Double-Layer Capacitance of Ordered Carbon Electrodes.

Supercapacitors are electrochemical energy storage devices having high capacitance, high power density, long cycle life, low cost, easy maintenance, and negligible environmental pollution. The formation of an electric double layer at the electrode-electrolyte interface is mostly responsible for supercapacitors' energy storage. The simulation study of equilibrium electric double-layer capacitance (EDLC) in 3D arranged mesoporous carbon electrodes with a simple cubic morphology and interdigitated electrodes has been done. Continuum theory has been utilized to study the underlying processes involved in EDLC. Interfacial polarization and ion crowding depend on the electrode's critical thickness. Porosity increases the capacitance due to the increase in the electrode surface area. The diffuse-layer specific capacitance of ordered mesoporous carbon electrodes in a (C2H5)4NBF4/propylene carbonate organic electrolyte is in the range of 3.2-13.3 µF cm-2, varying according to the electrode thickness. The Stern-layer specific capacitance is 167.6 µF cm-2, and total equilibrium EDLC is in the range of 3.1-12.3 µF cm-2. The effect of the electric field at the electrode-electrolyte interface on reducing electrolyte permittivity has also been discussed. The EDLC of carbonized interdigitated electrodes is analyzed in a 6 M KOH electrolyte. The diffuse-layer specific capacitance ranges from 118.7 to 352.0 µF cm-2 depending on the width of the interdigitated electrodes. The Stern-layer specific capacitance is 91.2 µF cm-2, and the total EDLC value is 51.6-72.4 µF cm-2. The modeling and simulation approach can be applied to different mesoporous electrodes by varying the supercapacitor component's parameters and geometry.

Ramifications of Vorticity on Aggregation and Activation of Platelets in Bi-Leaflet Mechanical Heart Valve: Fluid-Structure-Interaction Study.

Bileaflet mechanical heart valves (BMHV) are widely implanted to replace diseased heart valves. Despite many improvements in design, these valves still suffer from various complications, such as valve dysfunction, tissue overgrowth, hemolysis, and thromboembolism. Thrombosis and thromboembolism are believed to be initiated by platelet activation due to contact with foreign surfaces and nonphysiological flow patterns. The implantation of the valve causes nonphysiological patterns of vortex shedding behind the leaflets. This study signifies the importance of vorticity in platelet activation and aggregation in BMHV implants. A two-phase model with the first Eulerian phase for blood and the second discrete phase for platelets is used here. The generalized cross model of viscosity has been used to simulate the non-Newtonian viscosity of blood. A fluid-structure-interaction model has been used to simulate the motion of leaflets. This study has also estimated the platelet activation state (PAS), which is the mathematical estimation of the degree of activation of platelets due to flow-induced shear stresses that cause thrombus formation. The regions in the fluid domain with a higher vorticity field have been found to contain platelets with relatively higher PAS than regions with relatively lower vorticity fields. Also, this study has quantitatively reported the effect of vorticity on platelet aggregation. Platelet densities in fluid areas with higher vorticity are higher than densities in fluid areas with lower vorticity, indicating that highly activated platelets aggregate in areas with stronger vorticity.

Microwave as a Tool for Synthesis of Carbon-Based Electrodes for Energy Storage.

This Spotlight on Applications highlights the significant impact of microwave-assisted methods for synthesis and modification of carbon materials with enhanced properties for electrodes in energy storage applications (supercapacitors and batteries). For the past few years, microwave irradiation has been increasingly used for the synthesis of carbon materials with different morphologies using various precursors. Microwave processing exhibits numerous advantages, such as short processing times, high yield, expanded reaction conditions, high reproducibility, and high purity of products. On this frontier research area, we have discussed microwave-assisted synthesis, defect creation, simultaneous reduction and exfoliation, and heteroatom doping in carbon materials. By careful manipulation of microwave irradiation parameters, the method becomes a powerful and efficient tool to generate different morphologies in carbon-based materials. Other important outcomes are the flexible control over the degree of reduction and exfoliation of graphene derivatives, the generation of defects in graphene-based materials by metals, the intercalation of metal oxides into graphene derivatives, and heteroatom doping of graphene materials. The Spotlight on Applications aims to provide a condensed overview of the current progress in carbon-based electrodes synthesized by microwave, pointing out outstanding challenges and offering a few suggestions to trigger more research endeavors in this important field.

Acid-directed preparation of micro/mesoporous heteroatom doped defective graphitic carbon as bifunctional electroactive material: Evaluation of trace metal impurity.

Extensive research to explore cost-effective carbon materials as electrocatalysts and electrode materials for energy conversion and storage has been conducted in the recent literature. This raised a crucial question regarding the origin of this electrocatalytic activity from the heteroatom doping/ hierarchical porous defect-rich architecture and/ or the trace metal impurities introduced during synthesis/ inherent to the precursor. In this work, an insight into this issue is provided by considering a lignocellulosic biowaste, Euryale Ferox (foxnut) shells as a precursor to derive micro/ mesoporous defective graphitic carbon sheets by the phosphoric acid (H3PO4) dictated in-situ carbonization for oxygen reduction reaction (ORR) and supercapacitor applications. The sample synthesized at 900 °C (FP900) shows an onset potential of 0.98 V vs. reversible hydrogen electrode (RHE), ORR current density of 5.5 mA cm-2, and current stability of 93% (in 10 h measurement) in 0.1 M KOH. In addition, a symmetric supercapacitor device is assembled using the prepared material and the specific capacitance of 207.5 F g-1 at 1 A g-1 is obtained. An attempt to explain the origin of the electrochemical performance is made by establishing parallels with the physicochemical characterizations. The inherently doped heteroatoms give rise to electroactive functionalities and the wide enough pore size distribution improves the active sites utilization efficiency by enhancing the accessibility to electrolytic ions resulting in better electrochemical performance. Furthermore, the contribution from the intrinsic trace metal impurities is evaluated using X-ray fluorescence (XRF) spectroscopy. The presented research clarifies the non-contributing nature of trace metal species owing to the inaccessibility of active sites and lower abundance in F900 and FP900, respectively.

Insights of arsenic (III/V) adsorption and electrosorption mechanism onto multi synergistic (redox-photoelectrochemical-ROS) aluminum substituted copper ferrite impregnated rGO.

The understanding of mechanistic insights in environmental remediation and mitigation systems is attracting larger attention, in recent days. Here in, aluminium substituted copper ferrite impregnated rGO hybrid (CAF-rGO) is verified to understand the adsorption/electrosorption mechanism of arsenic in aqueous systems. Near-surface study (XPS: As 3d, Cu 2p, Fe 2p, Al 2p, O 1s, C 1s) proposes redox, and ligand exchange reactions between contaminant, and CAF-rGO. Adsorption capacities are observed around 128.8 mg g-1 [As(III)], 153.5 mg g-1 [As(V)] with Freundlich model isotherms. Kinetics study follows the PSO model with influence of solar light (> 420 nm). Cyclic voltammetry (CV) analysis in different molarity conditions observed with signals around +0.1 and -0.6 V confirm the redox abilities, and N2/O2 purged environments understood that electrosorption occurred through both reduction and sorption. Electrosorption study with pH variation shows the effect of protonation on the redox activity of individual arsenic species. Consistent signal around -0.6 ± 0.05 V in all the CV plots (i.e., Molarity, Environment, pH) recommends the usage of CAF-rGO for arsenic mitigation. Possible influence of photo-current (∼40 µA/cm2 at âˆ¼ 0 V) towards As(III/V) decontamination is understood though photoelectrochemical analysis. Impedance plot shows low-resistance and better diffusion of arsenic oxy-anions during light irradiation. Synergistic nature of CAF-rGO generates reactive oxygen species (i.e., ●OH/●O2-/1O2) in mitigating highly toxic As(III) species is also detailed in the present work.

Atomically dispersed Ni/NixSy anchored on doped mesoporous networked carbon framework: Boosting the ORR performance in alkaline and acidic media.

Rational and strategic fabrication of cost-effective, active and durable oxygen reduction reaction (ORR) electrocatalyst is the bottle-neck for the commercialization of fuel cells and metal-air batteries. Atomically dispersed nickel (Ni)/nickel sulfide (NixSy) anchored on heteroatom doped networked hierarchical porous carbonaceous sheets are synthesized from nickel nitrate and guanidine thiocyanate. The sample annealed at 750 °C followed by acid-treatment (Ni-GT-750-A) emerges as the best performing pH-universal ORR catalyst with an onset potential of 0.91 (0.1 M KOH) and 0.89 V (0.1 M HClO4) vs. reversible hydrogen electrode (RHE). It also exhibits better current durability (95.0 and 60%) and methanol tolerance (90.6 and 80.3%) in comparison to the commercial catalyst (65.0, 27, -33.0 and 16.5%) in alkaline and acidic media, respectively. An insight into the microstructure and ORR-active chemical sites is obtained with the aid of electron microscopic (FE-SEM and HR-TEM) and physiochemical (sorption isotherm, XRD, Raman and XPS) studies, respectively. The enhanced activity results from the synergistic influence of metallic ORR-active sites in hierarchical porous doped defective carbon support, which provides the well-interlinked conducting channel for electron transfer and additional ORR-active sites. The introduced electrocatalyst establishes Ni decorated doped carbon systems as potential revolutionary substitutes for commercial systems.

Facile Development Strategy of a Single Carbon-Fiber-Based All-Solid-State Flexible Lithium-Ion Battery for Wearable Electronics.

Microsized and shape-versatile flexible and wearable lithium-ion batteries (LIBs) are promising and smart energy storage devices for next-generation electronics. In the present work, we design and fabricate the first prototype of microsized fibrous LIBs (thickness ≈ 22 µm) based on multilayered coaxial structure of solid-state battery components over flexible and electrically conductive carbon fibers (CFs). The micro coaxial batteries over the CF surface were fabricated via electrophoretic deposition and dip-coating methods. The microfiber battery showed a stable potential window of 2.5 V with an areal discharge capacity of ∼4.2 µA h cm-2 at 13 µA cm-2 of the current density. The as-assembled battery fiber delivered a comparable energy density (∼0.006 W h cm-3) with solid-state lithium thin-film batteries at higher power densities (∼0.0312 W cm-3). The fibrous batteries were also connected in parallel and in series to deliver large current and high voltage, respectively. The fibrous battery also retains up to 85% discharge capacity even after 100 charge-discharge cycles. Furthermore, these battery fibers performed well under both static and bending conditions, which shows the robustness of the battery fiber. Therefore, this type of fibrous microbattery can be used in advanced flexible and wearable microelectronics, bioelectronics, robotics, and textile applications.

Arsenic surface complexation behavior in aqueous systems onto Al substituted Ni, Co, Mn, and Cu based ferrite nano adsorbents.

The present study is about surface complexation behavior of arsenic species adsorbed onto ternary metal oxide adsorbents (Ni-Al-Fe, Co-Al-Fe, Mn-Al-Fe, and Cu-Al-Fe). The analysis is carried out by X-ray absorption spectroscopy (XAS) tool. XANES (µ(E) vs. E) spectra close to the absorption edge (i.e., As K-edge) of all samples are observed along with the As(III) and As(V) standards. The first derivative of XANES for Ni-As(V), and Cu-As(V) samples agree with that of As(V) standards, respectively. Whereas, As(III) adsorbed adsorbent systems (i.e., Ni, Co, Mn, and Cu) are observed with mixed oxidation state of arsenic. A total of 65-85 % is observed with initial oxidation state (As(III) or As(V)), and remaining 15-35 % is observed with modified oxidation state (As(V) or As(III)) that explains the occurrence of possible charge transfer. EXAFS analysis shows the As-O bond distances in the range of 1.7-1.8 Å. The corresponding As-M bond distances are around 2.7, 3.2, and 3.6 Å which confirms the formation various edge sharing (2E), and corner sharing (2C, 1V) surface complexes. Surface coverage is understood as an important parameter as bidentate attachments (2E, 2C) are evident in As(III), and As(V), but monodentate attachments (1V) are only observed in As(V).

Redox synergistic Mn-Al-Fe and Cu-Al-Fe ternary metal oxide nano adsorbents for arsenic remediation with environmentally stable As(0) formation.

Arsenic mitigation behavior in aqueous systems is being evaluated for Mn-Al-Fe, Cu-Al-Fe nano adsorbents. Morphological, and vibrational spectroscopy analysis are observed with As-OH, and As-O surface complexes. XPS study of individual As(3d) spectra at different parameters is observed with multiplet peak behavior attributed to redox behavior of Mn-Al-Fe, Cu-Al-Fe. Significant proportions of As(0) signal (∼25 at.% in pH 7, ∼78 at.% in pH 2, ∼58 at.% in pH 12) implicate an environmentally stable behavior of these adsorbents to address the arsenic leaching issue. Adsorption kinetics are observed with Pseudo Second Order (PSO) model, and Freundlich model supported multilayer adsorption behavior is observed for adsorption isotherms. Trace metal voltammetry studies are observed with 75-90 % of As(III) mitigation in aliquot samples. Detailed study of Mn(2p), Cu(2p), Fe(2p), and O(1 s) spectra explains redox active, and surface ligand exchange synergism in arsenic adsorption. Low equilibrium concentrations (Ce < 10 ppb) in As(V) systems (Ci ∼ 100 and 500 ppb) indicate the drinking water application of these systems. Cyclic-voltammetry (CV) studies implicate the mitigation and immobilization of arsenic species onto adsorbent by both reduction, and sorption phenomenon.

Hierarchical Carbon Nanotube-Coated Carbon Fiber: Ultra Lightweight, Thin, and Highly Efficient Microwave Absorber.

Strong EM wave absorption and lightweight are the foremost important factors that drive the real-world applications of the modern microwave absorbers. This work mainly deals with the design of highly efficient microwave absorbers, where a hierarchical carbon nanotube (CNT) forest is first grown on the carbon fiber (CF) through the catalytic chemical vapor deposition method. The hierarchical carbon nanotube grown on the carbon fiber (CNTCF) is then embedded in the epoxy matrix to synthesize lightweight nanocomposites for their use as efficient microwave absorbers. The morphological study shows that carbon nanotubes (CNTs) self-assemble to form a trapping center on the carbon fiber. The electromagnetic characteristics of resultant nanocomposites are investigated exclusively in the X-band (8.2-12.4 GHz) using the network analyzer. The synthesized nanocomposites, containing 0.35 and 0.50 wt % CNTCFs, exhibit excellent microwave absorption properties, which could be attributed to the better impedance matching conditions and high dielectric losses. The reflection loss (RL) of -42.0 dB (99.99% absorption) with -10 dB (90% absorption) and -20 dB (99% absorption) bandwidths of 2.7 and 1.16 GHz, respectively, is achieved for 0.35 wt % CNTCF loading at 2.5 mm thickness. The composite with 0.50 wt % CNTCF loading illustrates substantial absorption efficiency with the RL reaching -24.5 dB (99.65% absorption) at 9.8 GHz and -10 dB bandwidth comprising 84.5% of the entire X band. The excellent microwave properties obtained here are primarily due to the electric dipole polarization, interfacial polarization, and unique trapping center. These trapping centers basically induce multiple reflections and scatterings, which attenuate more microwave energy. This investigation opens a new approach for the development of extremely lightweight, small-thickness, and highly efficient microwave absorbers for X-band applications.

Microwave-assisted synthesis of palladium nanoparticles intercalated nitrogen doped reduced graphene oxide and their electrocatalytic activity for direct-ethanol fuel cells.

Palladium nanoparticles decorated reduced graphene oxide (Pd-rGO) and palladium nanoparticles intercalated inside nitrogen doped reduced graphene oxide (Pd-NrGO) hybrids have been synthesized by applying a very simple, fast and economic route using microwave-assisted in-situ reduction and exfoliation method. The Pd-NrGO hybrids materials show good activity as catalyst for ethanol electro oxidation for direct ethanol fuel cells (DEFCs) as compared to Pd-rGO hybrids. The enhanced direct ethanol fuel cell can serve as alternative to fossil fuels because it is renewable and environmentally-friendly with a high energy conversion efficiency and low pollutant emission. As proof of concept, the electrocatalytic activity of Pd-NrGO hybrid material was accessed by cyclic voltammetry in presence of ethanol to evaluate its applicability in direct-ethanol fuel cells (DEFCs). The Pd-NrGO catalyst presented higher electro active surface area (∼6.3 m2 g-1) for ethanol electro-oxidation when compared to Pd-rGO hybrids (∼3.7 m2 g-1). Despite the smaller catalytic activity of Pd-NrGO, which was attributed to the lower exfoliation rate of this material in relation to the Pd-rGO, Pd-NrGO showed to be very promising and its catalytic activity can be further improved by tuning the synthesis parameters to increase the exfoliation rate.

A Facile Methodology for the Development of a Printable and Flexible All-Solid-State Rechargeable Battery.

Development of printable and flexible energy storage devices is one of the most promising technologies for wearable electronics in textile industry. The present work involves the design of a printable and flexible all-solid-state rechargeable battery for wearable electronics in textile applications. Copper-coated carbon fiber is used to make a poly(ethylene oxide) (PEO)-based polymer nanocomposite for a flexible and conductive current collector layer. Lithium iron phosphate (LiFePO4) and titanium dioxide (TiO2) are utilized to prepare the cathode and anode layers, respectively, with PEO and carbon black composites. The PEO- and Li salt-based solid composite separator layer is utilized for the solid-state and safe electrolyte. Fabrication of all these layers and assembly of them through coating on fabrics are performed in the open atmosphere without using any complex processing, as PEO prevents the degradation of the materials in the open atmosphere. The performance of the battery is evaluated through charge-discharge and open-circuit voltage analyses. The battery shows an open-circuit voltage of ∼2.67 V and discharge time ∼2000 s. It shows similar performance at different repeated bending angles (0° to 180°) and continuous bending along with long cycle life. The application of the battery is also investigated for printable and wearable textile applications. Therefore, this printable, flexible, easily processable, and nontoxic battery with this performance has great potential to be used in portable and wearable textile electronics.

Aluminum Substituted Cobalt Ferrite (Co-Al-Fe) Nano Adsorbent for Arsenic Adsorption in Aqueous Systems and Detailed Redox Behavior Study with XPS.

Arsenic [As(III) and As(V)] adsorption on aluminum substituted cobalt ferrite (Co-Al-Fe) ternary metal oxide adsorbent is reported by means of qualitative and quantitative spectroscopy tools. IR and Raman active signals were observed around 810-920 cm-1 band indicate different As-OHcomplexed and As-Ouncomplexed stretching vibrations on to the adsorbent. The adsorption behavior of arsenic (III and V) onto these adsorbents is studied as a function of contact time, different concentrations, and pH conditions. The kinetics study on adsorption were performed to understand nature of adsorption which supports the Pseudo Second Order (PSO) model. The adsorption isotherms study indicates Freundlich type of adsorption. The maximum adsorption capacity of Co-Al-Fe adsorbent is observed around 130 and 76 mg g-1 for As(III) and As(V) systems, respectively. Detailed XPS study of As 3d, Fe 2p, Co 2p, and O 1s spectra has been reported in explaining the redox behavior and ligand exchange reactions in supporting arsenic adsorption mechanism.

Hierarchical carbon nanopetal/polypyrrole nanocomposite electrodes with brush-like architecture for supercapacitors.

Hierarchical 3D nanocomposite electrodes with tube brush-like morphology are synthesized by electrochemically depositing polypyrrole (PPY) on carbon nanopetal (CNP) coated carbon fibers (CFs). Initially CNPs are synthesized on CF substrate by chemical vapour deposition. The CNPs synthesized on CF (CNPCF) are further used as an electrically conducting large surface area bearing template for the electropolymerization of PPY in order to fabricate CNPCF-PPY nanocomposite electrodes for supercapacitors (SCs). The CF in CNPCF-PPY nanocomposite functions as (i) a mechanical support for the CNPs, (ii) a current collector for the SC cell and also (iii) to prevent the agglomeration of CNPs within the CNPCF-PPY nanocomposite. Transmission electron microscopy and scanning electron microscopy are used to examine the surface morphology of CNPCF-PPY nanocomposites. The chemical structure of the nanocomposites is analysed by Fourier transform infrared spectroscopy. X-Ray photoelectron spectroscopy has been used to understand the chemical bonding states of the hierarchical CNPCF-PPY nanocomposites. The electrochemical properties of symmetric type CNPCF-PPY SC cells are examined by electrochemical impedance spectroscopy, cyclic voltammetry and galvanostatic charge-discharge measurements. The hierarchical CNPCF-PPY SC exhibits a maximum gravimetric capacitance of 280.4 F g(-1) and an area specific capacitance of 210.3 mF cm(-2) at a current density of 0.42 mA cm(-2). The CNPCF-PPY SC cell exhibits good cycling stability of more than 5000 cycles. The present study proclaims the development of a novel lightweight SC with high-performance.

The fabrication of carbon-nanotube-coated electrodes and a field-emission-based luminescent device.

Tungsten substrates were coated with an Ni or Ni-Co catalyst by the electroless dip coating technique. Various carbon nanotubes were synthesized by the catalytic chemical vapor deposition (CVD) method under different growth conditions. It was observed that Ni-and Ni-Co-coated tungsten substrates give very good growth of carbon nanotubes (CNT) in terms of yield, uniformity and alignment at a growth temperature of 600 degrees C. We fabricated a field-emission-based luminescent light bulb where a tungsten wire coated with carbon nanotubes served as a cathode. Results show lower threshold voltage, better emission stability and higher luminescence for CNT cathodes in comparison with uncoated tungsten cathodes. We found that aligned-coiled carbon nanotubes are superior to straight CNTs in terms of field emission characteristics and luminescence properties.

Synthesis and characterization of elastic and macroporous chitosan-gelatin cryogels for tissue engineering.

Elastic chitosan-gelatin cryogels of varying concentration of polymer precursors have been synthesized using glutaraldehyde as a crosslinking agent. The optimum co-polymer ratio of chitosan to gelatin was found to be 1:4 at the temperature of -12 degrees C for synthesis of chitosan-gelatin hybrid cryogels. chitosan-gelatin cryogels synthesized with low viscosity chitosan were morphologically better than those formed with medium and high viscosity chitosan. Pore diameters of chitosan-gelatin cryogels as measured by scanning electron microscopy (SEM) was in the range of 30-100microm. While mercury porosimetry analysis revealed the majority of pores of the scaffold lying in the range of 30-50microm. Porosity of chitosan-gelatin cryogels was found to be greater than 90% using Archimedes's principle. Unconfined compression tests showed significant elasticity of chitosan-gelatin cryogels and maintained their physical integrity even after compressing them up to 80% of their original length. The elastic modulus varied in the range of 36-39kPa. Cyclic deformation analysis performed by compression of chitosan-gelatin cryogels with varying strains (10, 20 and 40%) showed no cracking or any significant deformation. The degradation of chitosan-gelatin cryogels was found up to 13.58+/-1.52% at 37 degrees C within 8 weeks of incubation under sterile conditions and the cryogels swelled up to 90% of their capacity within two min. Efficient cell adherence, proliferation and extracellular matrix (ECM) secretion was observed by growing fibroblast (Cos-7) cell line on chitosan-gelatin hybrid cryogels which indicate potential of the material for tissue engineering applications.