Influence of nanotips on the hydrophilicity of metallic nanorod surfaces.

The hydrophilicity of vertically aligned metal nanorods with sharp nanotips were investigated experimentally. Ruthenium and platinum nanorod arrays were deposited on flat silicon substrates using oblique angle sputter deposition. We show that the effects of nanotips on nanorods should be considered in the "hemiwicking" model for hydrophilic metallic samples. With the influence of nanotips, we successfully explained the experimental contact angles of water sessile drops on metallic nanorod surfaces. Our experiments confirm that the shape of the nanorods is an important parameter in determining the hydrophilicity of the nanostructured surfaces.

Cyclooxygenase-2 expression in primary and recurrent pterygium.

PURPOSE: Pterygium is a proliferative, inflammatory, and invasive ocular surface disease associated with excessive ultraviolet radiation exposure and has several tumor-like characteristics. Cyclooxygenase-2 (COX-2) is an inducible enzyme and recently increased expression of the enzyme was found in many cancers and premalign lesions. This study was conducted to identify the COX-2 expression in pterygium tissues. METHODS: Immunohistochemical staining using a primary antibody for COX-2 was performed on 30 specimens with primary pterygium (20 pterygium without recurrence and 10 pterygium which recurred during a 12-month follow-up), 11 specimens with recurrent pterygium, and 8 specimens of conjunctival tumor. As a control we used 10 specimens of normal conjunctiva. Extent and intensity of cytoplasmic and membranous staining in epithelial cells were evaluated. RESULTS: Higher expression of COX-2 was detected in conjunctival tumor (87.5%) specimens and recurrent pterygium specimens (72.7%) compared to the both normal conjunctiva (30%) and primary pterygium without recurrence (30%). COX-2 expression in primary pterygium tissues with recurrence (60%) was not different from primary pterygium without recurrence (p=0.114) and recurrent pterygium (p=0.537). However, recurrent pterygium tissues were found to express higher COX-2 than primary pterygium without recurrence (p=0.022). CONCLUSIONS: COX-2 expression is increased in recurrent pterygium tissues and COX-2 expression may be a marker for the prediction of recurrence.

Preferred orientation in Ru nanocolumns induced by residual oxygen.

Ru nanocolumns were grown on a native oxide covered Si(100) substrate using an oblique angle sputter deposition technique with substrate rotation at room temperature. Scanning tunneling microscopy images of conventional Ru film show the presence of straight columnar features on the film surface, which are very different from the nearly circular features observed on the nanocolumns surface. X-ray diffraction spectra confirm that these nanocolumns have (100) as the preferred orientation instead of the (002) orientation observed for a conventional film. The oxygen to Ru atomic ratio was determined for both the nanocolumns and the conventional film by using X-ray photoelectron spectroscopy. The nanocolumns were observed to incorporate about 6 times more oxygen than the conventional film near the surface region. We argue that the oxygen segregates onto the high-density (002) plane whereas it permeates through comparatively open planes like (100) and (101). The adsorbed oxygen atoms serve as a diffusion barrier for the landing Ru adatoms and inhibit the growth of the (002) plane. This results in the absence of the (002) plane and development of (100) and (101) planes in the nanocolumns. The oxygen plays a decisive role in determining the crystallographic orientation and the feature size/shape over the nanocolumns and conventional film surfaces.

Breakdown of dynamic scaling in surface growth under shadowing.

Using Monte Carlo simulations and experimental results, we show that for common thin film deposition techniques, such as sputter deposition and chemical vapor deposition, a mound structure can be formed with a characteristic length scale, or "wavelength" lambda, that describes the separation of the mounds. We show that the temporal evolution of lambda is distinctly different from that of the mound size, or lateral correlation length xi. The formation of a mound structure is due to nonlocal growth effects, such as shadowing, that lead to the breakdown of the self-affinity of the morphology described by the well-established dynamic scaling theory. We show that the wavelength grows as a function of time in a power law form, lambda approximately t(p), where p approximately equals 0.5 for a wide range of growth conditions, while the mound size grows as xi approximately t(1-z), where 1/z varies depending on growth conditions.

Küttner's tumour of the submandibular gland.

Küttner's tumour (chronic sclerosing sialadenitis) is a chronic inflammatory disease of the salivary glands that produces a firm and relatively painful swelling of the glands. Although Küttner's tumour is a common submandibular disease, many clinicians and pathologists have under-recognized this entity because of its superficial resemblance to neoplasia and the presence of only a few reports in the English literature. We report a case of Küttner's tumour in a 41-year-old male who presented with a painless submandibular mass, and discuss its histological and clinical characteristics.

Large-angle in-plane light scattering from rough surfaces.

An in-plane light scattering setup that is capable of measuring large azimuthal scattering angles is presented. This type of measurement makes it easier to probe large k(parallel) at a fixed k(perpendicular) value (k(parallel) and k(perpendicular) are momentum transfer vectors parallel and perpendicular to the surface, respectively). Therefore the system allows us to explore small lateral scale and large vertical roughness (approximately lambda, the wavelength of the probe beam) of a rough surface. In-plane intensity measurements from a rough backside Si wafer and a Cu thin-film surface are reported. The structure factor that is related to surface roughness parameters is obtained from the measured in-plane intensity profiles. Both scalar (Beckmann-Kirchhoff) and vector (Rayleigh-Rice) theories have been applied to interpret the experimental data. The roughness parameters obtained from the scattering measurements are compared with those measured by atomic-force microscopy.