Plasmon-Enhanced Light Absorption in (p-i-n) Junction GaAs Nanowire Solar Cells: An FDTD Simulation Method Study.

A finite-difference time-domain method is developed for studying the plasmon enhancement of light absorption from vertically aligned GaAs nanowire arrays decorated with Au nanoparticles. Vertically aligned GaAs nanowires with a length of 1 µm, a diameter of 100 nm and a periodicity of 165-500 nm are functionalized with Au nanoparticles with a diameter between 30 and 60 nm decorated in the sidewall of the nanowires. The results show that the metal nanoparticles can improve the absorption efficiency through their plasmonic resonances, most significantly within the near-bandgap edge of GaAs. By optimizing the nanoparticle parameters, an absorption enhancement of almost 35% at 800 nm wavelength is achieved. The latter increases the chance of generating more electron-hole pairs, which leads to an increase in the overall efficiency of the solar cell. The proposed structure emerges as a promising material combination for high-efficiency solar cells.

Anisotropic deformation of NiO nanoparticles embedded in silica under swift heavy ion irradiation.

We report on the ion-induced anisotropic deformation in nickel oxide nanoparticles prepared by conventional sol-gel technique. Colloidal-like NiO nanoparticles with an average diameter of about 40-50 nm embedded in a SiO2 layer change their shape dramatically under swift heavy ion irradiation with 32 MeV Cu+5 ions at room temperature and normal incidence. Transmission electron microscopy analysis show irradiation induced shape transformation from nearly spherical nanoparticles into oblate nanorods at a rate that increases with ion fluence. For low nanoparticle density, the apparent nanoparticle size aspect ratio increases gradually with increasing irradiation fluence to 5 × 1014 ions cm-2 while no significant volume change is observed upon irradiation. For higher density of the nanoparticles, Rutherford backscattering spectrometry analysis indicates collective growth of nanoparticles under irradiation with fluence above 5 × 1014 ions cm-2. Magnetization experiments of the NiO nanoparticles show that the film consisting the pristine NiO nanoaprticles has a small magnetic anisotropy with axis in the direction parallel to ion beam. However, after 32 MeV Cu+5 ion irradiation, the change in magnetic anisotropy is much larger, which can be correlated with the elongation of nanoparticles in the beam direction. Furthermore, a threshold fluence, under which no deformation takes place is observed.