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1.
Materials (Basel) ; 15(21)2022 Nov 03.
Article in English | MEDLINE | ID: mdl-36363323

ABSTRACT

For the creation of healable cement concrete matrix, microbial self-healing solutions are significantly more creative and potentially successful. The current study investigates whether gram-positive "Bacillus subtilis" (B. subtilis) microorganisms can effectively repair structural and non-structural cracks caused at the nano- and microscale. By creating an effective immobilization strategy in a coherent manner, the primary challenge regarding the viability of such microbes in a concrete mixture atmosphere has been successfully fulfilled. The iron oxide nanoparticles were synthesized. The examined immobilizing medium was the iron oxide nanoparticles, confirmed using different techniques (XRD, SEM, EDX, TGA, and FTIR). By measuring the average compressive strength of the samples (ASTM C109) and evaluating healing, the impact of triggered B. subtilis bacteria immobilized on iron oxide nanoparticles was examined. The compressive strength recovery of cracked samples following a therapeutic interval of 28 days served as a mechanical indicator of the healing process. In order to accurately correlate the recovery performance as a measure of crack healing duration, the pre-cracking load was set at 80% of the ultimate compressive stress, or "f c," and the period of crack healing was maintained at 28 days. According to the findings, B. subtilis bacteria greatly enhanced the compressive strength and speed up the healing process in cracked cement concrete mixture. The iron oxide nanoparticles were proven to be the best immobilizer for keeping B. subtilis germs alive until the formation of fractures. The bacterial activity-driven calcite deposition in the generated nano-/micro-cracks was supported by micrographic and chemical investigations (XRD, FTIR, SEM, and EDX).

2.
Materials (Basel) ; 15(6)2022 Mar 08.
Article in English | MEDLINE | ID: mdl-35329449

ABSTRACT

Preplaced aggregate concrete (PAC) is prepared in two steps, with the coarse aggregate being initially laid down in the formwork, after which a specialised grout is injected into it. To enhance the properties of concrete and to reduce the emission of CO2 produced during the production of cement, supplementary cementitious materials (SCMs) are used to partially substitute ordinary Portland cement (OPC). In this study, 100 mm × 200 mm (diameter x height) PAC cylinders were cast with 10 per cent of cement being substituted with silica fume; along with that, 1.5% dosage of Macro polypropylene fibres were also introduced into the coarse aggregate matrix. Compressive strength test, splitting tensile strength test, mass loss at 250 °C, and compressive strength at 250 °C were performed on the samples. PAC samples with 10% of cement replaced with Silica Fume (SPAC) were used as control samples. The primary objective of this study was to observe the effect of the addition of Polypropylene fibres to PAC having Silica fume as SCM (FRPAC). The aforementioned tests showed that FRPAC had a lower compressive strength than that of the control mix (SPAC). FRPAC had greater tensile strength than that of NPAC and SPAC. Mass loss at 250 °C was greater in SPAC compared to FRPAC. The compressive strength loss at 250 °C was significantly greater in FRPAC compared to SPAC. FRPAC exhibited a greater strain for the applied stress, and their stress-strain curve showed that FRPAC was more ductile than SPAC.

3.
Nanomaterials (Basel) ; 10(10)2020 Oct 21.
Article in English | MEDLINE | ID: mdl-33096675

ABSTRACT

Extensive research on functionalized graphene, graphene oxide, and carbon nanotube based cement composites has been carried out to strengthen and overcome the shortcomings of construction materials. However, less literature is available on the pure graphene based cement composite. In this review paper, an in-depth study on a graphene-based cement composite was performed. Various structural forms of graphene and classifications of graphene-based nanomaterial have been presented. The dispersion mechanism and techniques, which are important for effective utilization in the construction industry, are reviewed critically. Micro-scale characterization of carbon-based cement composite using thermogravimetric analysis (TGA), infrared (IR) spectroscopic analysis, x-ray diffractometric (XRD) analysis, and morphological analysis has also been reviewed. As per the authors' knowledge, for the first time, a review of flow, energy harvesting, thermoelectrical, and self-sensing properties of graphene and its derivatives as the bases of cement composite are presented. The self-sensing properties of the composite material are reported by exploring physical applications by reinforcing graphene nanoplatelets (GNPs) into concrete beams.

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