Characteristic of phosphorus rich compounds in the incinerated sewage sludge ashes: a case for sustainable waste management.

Growing concern over mineral resources supply forces us to search for alternative sources of Phosphorus. The possibility to recover phosphorus from incinerated sewage sludge ashes appears to be an important aspect in anthropogenic phosphorus cycle and sustainable economy. To make phosphorus recovery efficient it is important to learn the chemical and mineral composition of ash and phosphorus speciation. The phosphorus content in the ash was over 7%, what corresponds to medium rich phosphorus ores. The main phosphorus rich mineral phases were phosphate minerals. The most widespread was tri-calcium phosphate Whitlockite with various Fe, Mg and Ca proportions. In minority Fe-PO4 and Mg-PO4 were detected. Whitlockite commonly overgrown with hematite, influences negatively mineral solubility and thus recovery potential and indicates low bioavailability of phosphorus. Considerable amount of phosphorus was found in the low crystalline matrix where phosphorus content was around 10 wt% however low crystallinity and dispersed phosphorus also does not strengthen the potential to recover this element.

The assessment of phosphorus recovery potential in sewage sludge incineration ashes - a case study.

A sewage sludge incineration ash contains large amounts of phosphorus, which are considered as a novel anthropogenic waste-based substitute for phosphorus natural resources. Phosphorus is accumulated at most in phosphate minerals of whitlockite structure, that contain Fe, Ca, and Mg and in the matrix composed of Si, Al, Fe, Ca, P, Mg, K, Na in various proportions. The goal of this study was to estimate phosphorus recovery potential. A four-stage sequential extraction, following the modified Golterman procedure, was applied. Separation of four independent fractions enabled to understand better the manner of phosphorus occurrence in the studied ash. The results of the extraction indicated the greatest release of phosphorus combined with organic matter using sulfuric acid. The release was on average at the level of 64%. The chelating Na-EDTA compound indicated lower ability to extract phosphorus (at the level of 35%), and the highest ability to extract heavy metals and potentially toxic elements (As, Zn, Mo). The sequential extraction led to the total recovery of phosphorus of around 40-60.

The leaching potential of sewage sludge and municipal waste incineration ashes in terms of landfill safety and potential reuse.

Incinerations residues from different types of materials (sewage sludge incineration ash and municipal waste incineration ashes) can either be by-products used in industry, or can pose a serious environmental problem related to their composition and the presence of potentially hazardous elements. State regulations and standards indicate whether material is inert, non-hazardous or hazardous. These standards, however, do not provide a complete overview on the leaching behavior of potentially hazardous elements in the environment. This study presents the result of batch experiment performed in accordance with the PN-EN 12457-2 (2006) and PN-EN 12457-4 (2006) standards. The results indicated that the leachability of elements is strongly dependent on the mineral composition of the waste product (the concentration and composition of soluble phase), the chemical composition (the mobility of hazardous elements and their affinity to soluble minerals), and the pH. To ensure environmental safety a thorough characterization of the waste is required followed by qualitative assignment to a particular waste type based on available guidance. Furthermore, to avoid leaching of potentially harmful elements into soils or surface water, it is also paramount to perform environmental impact assessment of wastes used as by-product in industry e.g., as building or road construction materials (aggregate) and fertilizers.

Process Recovery after CaO Addition Due to Granule Formation in a CSTR Co-Digester-A Tool to Influence the Composition of the Microbial Community and Stabilize the Process?

The composition, structure and function of granules formed during process recovery with calcium oxide in a laboratory-scale fermenter fed with sewage sludge and rapeseed oil were studied. In the course of over-acidification and successful process recovery, only minor changes were observed in the bacterial community of the digestate, while granules appeared during recovery. Fluorescence microscopic analysis of the granules showed a close spatial relationship between calcium and oil and/or long chain fatty acids. This finding further substantiated the hypothesis that calcium precipitated with carbon of organic origin and reduced the negative effects of overloading with oil. Furthermore, the enrichment of phosphate minerals in the granules was shown, and molecular biological analyses detected polyphosphate-accumulating organisms as well as methanogenic archaea in the core. Organisms related to Methanoculleus receptaculi were detected in the inner zones of a granule, whereas they were present in the digestate only after process recovery. This finding indicated more favorable microhabitats inside the granules that supported process recovery. Thus, the granule formation triggered by calcium oxide addition served as a tool to influence the composition of the microbial community and to stabilize the process after overloading with oil.