A direct method to quantify methanol-soluble organic carbon for brown carbon absorption studies.

The current research provides a newly developed method to quantify methanol-soluble organic carbon (MeS_OC) in aerosol samples. This analytical procedure allows an accurate separation of MeS-OC component, which is critical for the calculation of mass absorption efficiency (MAE) of ambient Brown Carbon (BrC) and consequently its climate relevant potential. The method includes extraction, filtering and condensation stages, leading to the preparation of a highly concentrated product in which MeS-OC can be precisely quantified by a Sunset Carbon Analyzer in a single analysis step. This method can be applied on aerosol collected using either high or low volume samplers, since a relatively small filter area is required for the determination. Furthermore, it eliminates any misestimation of the MeS-OC mass that may appear in other reported techniques that don't seem to include the precise separation of methanol-soluble fraction in their quantification process.•The mass quantification of methanol-soluble organic carbon is essential, contributing up to 50% to the absorptivity of organic aerosol (BrC) at shorter wavelengths.•The method provides a direct measurement of methanol-soluble aerosol components, resolving any potential uncertainties of previously applied methods.•The adoption of this direct quantification approach leads to a rationalization of past MAE estimates for BrC with implications for radiative transfer models.

Brown carbon absorption and radiative effects under intense residential wood burning conditions in Southeastern Europe: New insights into the abundance and absorptivity of methanol-soluble organic aerosols.

Biomass burning is a major source of Brown Carbon (BrC), strongly contributing to radiative forcing. In urban areas of the climate-sensitive Southeastern European region, where strong emissions from residential wood burning (RWB) are reported, radiative impacts of carbonaceous aerosols remain largely unknown. This study examines the absorption properties of water- and methanol-soluble organic carbon (WSOC, MeS_OC) in a city (Ioannina, Greece) heavily impacted by RWB. Measurements were performed during winter (December 2019 - February 2020) and summer (July - August 2019) periods, characterized by RWB and photochemical processing of organic aerosol (OA), respectively. PM2.5 filter extracts were analyzed spectrophotometrically for water- and methanol-soluble BrC (WS_BrC, MeS_BrC) absorption. WSOC concentrations were quantified using TOC analysis, while those of MeS_OC were determined using a newly developed direct quantification protocol, applied for the first time to an extended series of ambient samples. The direct method led to a mean MeS_OC/OC of 0.68 and a more accurate subsequent estimation of absorption efficiencies. The mean winter WS_BrC and MeS_BrC absorptions at 365 nm were 13.9 Mm-1 and 21.9 Mm-1, respectively, suggesting an important fraction of water-insoluble OA. Mean winter WS_BrC and MeS_BrC absorptions were over 10 times those observed in summer. MeS_OC was more absorptive than WSOC in winter (mean mass absorption efficiencies - MAE365: 1.81 vs 1.15 m2 gC-1) and especially in summer (MAE: 1.12 vs 0.27 m2 gC-1) due to photo-dissociation and volatilization of BrC chromophores. The winter radiative forcing (RF) of WS_BrC and MeS_BrC relative to elemental carbon (EC) was estimated at 8.7 % and 16.7 %, respectively, in the 300-2500 nm band. However, those values increased to 48.5 % and 60.2 % at 300-400 nm, indicating that, under intense RWB, BrC forcing becomes comparable to that of soot. The results highlight the consideration of urban BrC emissions in radiative transfer models, as a considerable climate forcing factor.

Mineralogical, geochemical, and textural characteristics of soil and airborne samples during dust storms in Khuzestan, southwest Iran.

Dust storms are frequent phenomena in Khuzestan Province, southwest Iran, leading to environmental hazards and deleterious impacts on human health. This work analyzes mineralogic and geochemical characteristics of dust sediments at the source regions and in deposition areas in southwest Iran during three dust-storm events in winter and spring 2018. Twenty soil and airborne dust samples were collected and analyzed for compositions of dust at different distances from the source regions in Iraq and southwest Iran, aiming to assess the source characterization and possible mixing processes in the atmosphere. The grain size distributions were also analyzed at specific sites. The results show that about 50 % of the volume size distribution corresponds to particle sizes of above 20 µm, indicating local/regional dust storms of coarse to giant particles. XRD analysis indicates that calcite is the dominant mineral in all the samples, with a high quartz and dolomite fraction. The most abundant major compounds are SiO2 and CaO, while Cl, Ba, Sr, Pb, Ni, Zn, Cr, V are the main trace elements. The enrichment factor (EF) analysis showed that apart from Th, Nb, Ce, and V, all the other elements (Pb, Zn, Cr, etc.) have an anthropogenic origin or represent high amounts of pollutant contamination. High levels of elemental enrichment are attributable to intensive pollution in Khuzestan Province and at sampling sites due to fossil-fuel combustion, gas and petroleum drilling activities. Moreover, based on the geo-accumulation index (Igeo), all samples are found to be contaminated by heavy metals due to prior war-related materiel, oil and gas extraction, and emissions from polluting industries.

Apportionment of black and brown carbon spectral absorption sources in the urban environment of Athens, Greece, during winter.

This study examines the spectral properties and source characteristics of absorbing aerosols (BC: Black Carbon; BrC: Brown Carbon, based on aethalometer measurements) in the urban background of Athens during December 2016-February 2017. Using common assumptions regarding the spectral dependence of absorption due to BC (AAEBC = 1) and biomass burning (AAEbb = 2), and calculating an optimal AAEff value for the dataset (1.18), the total spectral absorption was decomposed into five components, corresponding to absorption of BC and BrC from fossil-fuel (ff) combustion and biomass burning (bb), and to secondary BrC estimated using the BC-tracer minimum R-squared (MRS) method. Substantial differences in the contribution of various components to the total absorption were found between day and night, due to differences in emissions and meteorological dynamics, while BrC and biomass burning aerosols presented higher contributions at shorter wavelengths. At 370 nm, the absorption due to BCff contributed 36.3% on average, exhibiting a higher fraction (58.1%) during daytime, while the mean BCbb absorption was estimated at 18.4%. The mean absorption contributions due to BrCff, BrCbb and BrCsec were 6.7%, 32.3% and 4.9%, respectively. The AbsBCff,370 component maximized during the morning traffic hours and was strongly correlated with NOx (R2 = 0.76) and CO (R2 = 0.77), while a similar behavior was seen for the AbsBrCff,370 component. AbsBCbb and AbsBrCbb levels escalated during nighttime and were highly associated with nss-K+ and with the organic aerosol (OA) components related to fresh and fast-oxidized biomass burning (BBOA and SV-OOA) as obtained from ACSM measurements. Multiple linear regression was used to attribute BrC absorption to five OA components and to determine their absorption contributions and efficiencies, revealing maximum contributions of BBOA (33%) and SV-OOA (21%). Sensitivity analysis was performed in view of the methodological uncertainties and supported the reliability of the results, which can have important implications for radiative transfer models.

Identification of key aerosol types and mixing states in the central Indian Himalayas during the GVAX campaign: the role of particle size in aerosol classification.

Studies in aerosol properties, types and sources in the Himalayas are important for atmospheric and climatic issues due to high aerosol loading in the neighboring plains. This study uses in situ measurements of aerosol optical and microphysical properties obtained during the Ganges Valley Aerosol eXperiment (GVAX) at Nainital, India over the period June 2011-March 2012, aiming to identify key aerosol types and mixing states for two particle sizes (PM1 and PM10). Using a classification matrix based on SAE vs. AAE thresholds (scattering vs. absorption Ångström exponents, respectively), seven aerosol types are identified, which are highly dependent on particle size. An aerosol type named "large/BC mix" dominates in both PM1 (45.4%) and PM10 (46.9%) mass, characterized by aged BC mixed with other aerosols, indicating a wide range of particle sizes and mixing states. Small particles with low spectral dependence of the absorption (AAE < 1) account for 31.6% and BC-dominated aerosols for 14.8% in PM1, while in PM10, a large fraction (39%) corresponds to "large/low-absorbing" aerosols and only 3.9% is characterized as "BC-dominated". The remaining types consist of mixtures of dust and local emissions from biofuel burning and display very small fractions. The main optical properties e.g. spectral scattering, absorption, single scattering albedo, activation ratio, as well as seasonality and dependence on wind speed and direction of identified types are examined, revealing a large influence of air masses originating from the Indo-Gangetic Plains. This indicates that aerosols over the central Himalayas are mostly composed by mixtures of processed and transported polluted plumes from the plains. This is the first study that identifies key aerosol populations in the central Indian Himalayas based on in situ measurements and the results are highly important for aerosol-type inventories, chemical transport models and reducing the uncertainty in aerosol radiative forcing over the third pole.

Silver linings in the dark clouds of COVID-19: Improvement of air quality over India and Delhi metropolitan area from measurements and WRF-CHIMERE model simulations.

The current study examines the impact of the COVID-19 lockdown (25th March until May 17, 2020) period in particulate matter (PM) concentrations and air pollutants (NOx, SO2, CO, NH3, and O3) at 63 stations located at Delhi, Uttar Pradesh and Haryana states within the Delhi-NCR, India. Large average reductions are recorded between the stations in each state such as PM10 (-46 to -58%), PM2.5 (-49 to -55%), NO2 (-27 to -58%), NO (-54% to -59%), CO (-4 to -44%), NH3 (-2 to -38%), while a slight increase is observed for O3 (+4 to +6%) during the lockdown period compared to same periods in previous years. Furthermore, PM and air pollutants are significantly reduced during lockdown compared to the respective period in previous years, while a significant increase in pollution levels is observed after the re-opening of economy. The meteorological changes were rather marginal between the examined periods in order to justify such large reductions in pollution levels, which are mostly attributed to traffic-related pollutants (NOx, CO and road-dust PM). The WRF-CHIMERE model simulations reveal a remarkable reduction in PM2.5, NO2 and SO2 levels over whole Indian subcontinent and mostly over urban areas, due to limitation in emissions from the traffic and industrial sectors. A PM2.5 reduction of -48% was simulated in Delhi in great consistency with measurements, rendering the model as a powerful tool for simulations of lower pollution levels during lockdown period.

Human health risk assessment for toxic elements in the extreme ambient dust conditions observed in Sistan, Iran.

This study evaluates the bioaccessibility and health risks related to heavy metals (Cd, Cr, Co, Cu, Mn, Ni, Pb, Zn and metalloid As) in airborne dust samples (TSP and PM2.5) in Zabol, Iran during the summer dust period, when peak concentration levels of PM are typically observed. High bioaccessibilities of carcinogenic metals in PM2.5 (i.e. 53.3%, 48.6% and 47.6% for Ni, Cr and As, respectively) were calculated. The carcinogenic and non-carcinogenic health risks were assessed for three exposure pathways (inhalation, ingestion and dermal contact), separately for children and adults. Non-carcinogenic inhalation risks were very high (Hazard Index: HI > 1) both for children and adults, while the carcinogenic risks were above the upper acceptable threshold of 10-4 for adults and marginally close (5.0-8.4 × 10-5) for children. High carcinogenic risks (>10-4) were found for the ingestion pathway both for children and adults, while HI values > 1 (8.2) were estimated for children. Carcinogenic and non-carcinogenic risk estimates for dermal contact were also above the limits considered acceptable, except for the carcinogenic risk for children (7.6 × 10-5). Higher non-carcinogenic and carcinogenic risks (integrated for all elements) were associated with the inhalation pathway in adults and children with the exception of carcinogenic risk for children, where the ingestion route remains the most important, while As was linked with the highest risks for nearly all exposure pathways. A comparative evaluation shows that health risks related with toxic elements in airborne particles in Sistan are among the highest reported in the world.

Long-term (2008-2018) aerosol properties and radiative effect at high-altitude sites over western trans-Himalayas.

Analysis of the climatology of aerosol properties is performed over Hanle (4500 m) and Merak (4310 m), two remote-background sites in the western trans-Himalayas, based on eleven years (2008-2018) of sun/sky radiometer (POM-01, Prede) measurements. The two sites present very similar atmospheric conditions and aerosol properties allowing us to examine them as continuous single-data series. The annual average aerosol optical depth at 500 nm (AOD500) is 0.04 ± 0.03, associated with an Ångström exponent (AE440-870) of 0.58 ± 0.35 and a single scattering albedo (SSA500) of 0.95 ± 0.05. AOD500 exhibits higher values in May (~0.07) and lower in winter (~0.03), while AE400-870 minimizes in spring, indicating influence by coarse-mode dust aerosols, either emitted regionally or long-range transported. The de-convolution of AOD500 into fine and coarse modes justifies the aerosol seasonality and sources, while the marginal diurnal variation in all aerosol properties reveals a weak influence from local sources, except for some few aerosol episodes. The aerosol-volume size distribution presents a mode value at ~10 µm with secondary peaks at accumulation (~ 2 µm) and fine modes (~0.03 µm) and low variability between the seasons. A classification of the aerosol types based on the fine-mode fraction (FMF) vs. SSA500 relationship reveals the dominance of aerosols in the FMF range of 0.4-0.6, characterized as mixed (39%), followed by fine aerosols with high scattering efficiency (26%), while particles related to dust contribute ~21%, with low fractions of fine-absorbing aerosols (~13%). The aerosol radiative forcing (ARF) estimates reveal a small cooling effect at the top of the atmosphere (-1.3 Wm-2), while at the surface, the ARF ranges from -2 Wm-2 to -6 Wm-2 on monthly basis. The monthly-mean atmospheric radiative forcing (~1 to 4 Wm-2) leads to heating rates of 0.04 to 0.13 K day-1. These ARF values are higher than the global averages and may cause climate implications over the trans-Himalayan region.

Long-term brown carbon spectral characteristics in a Mediterranean city (Athens).

This study analyses 4-years of continuous 7-λ Aethalometer (AE-33) measurements in an urban-background environment of Athens, to resolve the spectral absorption coefficients (babs) for black carbon (BC) and brown carbon (BrC). An important BrC contribution (23.7 ± 11.6%) to the total babs at 370 nm is estimated for the period May 2015-April 2019, characterized by a remarkable seasonality with winter maximum (33.5 ± 13.6%) and summer minimum (18.5 ± 8.1%), while at longer wavelengths the BrC contribution is significantly reduced (6.8 ± 3.6% at 660 nm). The wavelength dependence of the total babs gives an annual-mean AAE370-880 of 1.31, with higher values in winter night-time. The BrC absorption and its contribution to babs presents a large increase reaching up to 39.1 ± 13.6% during winter nights (370 nm), suggesting residential wood burning (RWB) emissions as a dominant source for BrC. This is supported by strong correlations of the BrC absorption with OC, EC, the fragment ion m/z 60 derived from ACSM and PMF-analyzed organic fractions related to biomass burning (e.g. BBOA). In contrast, BrC absorption decreases significantly during daytime as well as in the warm period, reaching to a minimum during the early-afternoon hours in all seasons due to photo-chemical degradation. Estimated secondary BrC absorption is practically evident only during winter night-time, implying the fast oxidation of BrC species from RWB emissions. Changes in mixing-layer height do not significantly affect the BrC absorption in winter, while they play a major role in summer.

First results from light scattering enhancement factor over central Indian Himalayas during GVAX campaign.

The present work examines the influence of relative humidity (RH), physical and optical aerosol properties on the light-scattering enhancement factor [f(RH=85%)] over central Indian Himalayas during the Ganges Valley Aerosol Experiment (GVAX). The aerosol hygroscopic properties were measured by means of DoE/ARM (US Department of Energy, Atmospheric Radiation Measurement) mobile facility focusing on periods with the regular instrumental operation (November-December 2011). The measured optical properties include aerosol light-scattering (σsp) and absorption (σap) coefficients and the intensive parameters i.e., single scattering albedo (SSA), scattering Ångström exponent (SAE), absorption Ångström exponent (AAE) and light scattering enhancement factor (f(RH)=σsp(RH, λ)/σsp(RHdry, λ)). The measurements were separated for sub-micron (<1µm, D1µm) and particles with diameter<10µm (D10µm) in order to examine the influence of particle size on f(RH) and enhancement rate (γ). The particle size affects the aerosol hygroscopicity since mean f(RH=85%) of 1.27±0.12 and 1.32±0.14 are found for D10µm and D1µm, respectively. These f(RH) values are relatively low suggesting the enhanced presence of soot and carbonaceous particles from biomass burning activities, which is verified via backward air-mass trajectories. Similarly, the light-scattering enhancement rates are ~0.20 and 0.17 for the D1µm and D10µm particles, respectively. However, a general tendency for increasing f(RH) and γ is shown for higher σsp and σap values indicating the presence of rather aged smoke plumes, coated with industrial aerosols over northern India, with mean SSA, SAE and AAE values of 0.92, 1.00 and 1.15 respectively. On the other hand, a moderate-to-small dependence of f(RH) and γ on SAE, AAE, and SSA was observed for both particle sizes. Furthermore, f(RH) exhibits an increasing tendency with the number of cloud condensation nuclei (NCCN) indicating larger particle hygroscopicity but without significant dependence on the activation ratio.

Optical and radiative properties of aerosols over Desalpar, a remote site in western India: Source identification, modification processes and aerosol type discrimination.

Aerosol optical properties are analyzed for the first time over Desalpar (23.74°N, 70.69°E, 30m above mean sea level) a remote site in western India during October 2014 to August 2015. Spectral aerosol optical depth (AOD) measurements were performed using the CIMEL CE-318 automatic Sun/sky radiometer. The annual-averaged AOD500 and Ångström exponent (α440-870) values are found to be 0.43±0.26 and 0.69±0.39, respectively. On the seasonal basis, high AOD500 of 0.45±0.30 and 0.61±0.34 along with low α440-870 of 0.41±0.27 and 0.41±0.35 during spring (March-May) and summer (June-August), respectively, suggest the dominance of coarse-mode aerosols, while significant contribution from anthropogenic sources is observed in autumn (AOD500=0.47±0.26, α440-870=1.02±0.27). The volume size distribution and the spectral single-scattering albedo also confirm the presence of coarse-mode aerosols during March-August. An overall dominance of a mixed type of aerosols (~56%) mostly from October to February is found via the AOD500 vs α440-870 relationship, while marine aerosols contribute to ~18%. Spectral dependence of α and its second derivative (α') are also used for studying the aerosol modification processes. The average direct aerosol radiative forcing (DARF) computed via the SBDART model is estimated to range from -27.08Wm-2 to -10.74Wm-2 at the top of the atmosphere, from -52.21Wm-2 to -21.71Wm-2 at the surface and from 10.97Wm-2 to 26.54Wm-2 within the atmosphere. This atmospheric forcing translates into heating rates of 0.31-0.75Kday-1. The aerosol properties and DARF are also examined for different trajectory clusters in order to identify the sources and to assess the influence of long-range transported aerosols over Desalpar.

Columnar aerosol characteristics and radiative forcing over the Doon Valley in the Shivalik range of northwestern Himalayas.

Spectral aerosol optical depth (AOD) measurements obtained from multi-wavelength radiometer under cloudless conditions over Doon Valley, in the foothills of the western Himalayas, are analysed during the period January 2007 to December 2012. High AOD values of 0.46 ± 0.08 and 0.52 ± 0.1 at 500 nm, along with low values of Ångström exponent (0.49 ± 0.01 and 0.44 ± 0.03) during spring (March-May) and summer (June-August), respectively, suggest a flat AOD spectrum indicative of coarse-mode aerosol abundance compared with winter (December-February) and autumn (September-November), which are mostly dominated by fine aerosols from urban/industrial emissions and biomass burning. The columnar size distributions (CSD) retrieved from the King's inversion of spectral AOD exhibit bimodal size patterns during spring and autumn, while combinations of the power-law and unimodal distributions better simulate the retrieved CSDs during winter and summer. High values of extinction coefficient near the surface (∼0.8-1.0 km-1 at 532 nm) and a steep decreasing gradient above are observed via CALIPSO profiles in autumn and winter, while spring and summer exhibit elevated aerosol layers between ∼1.5 and 3.5 km due to the presence of dust. The particle depolarisation ratio shows a slight increasing trend with altitude, with higher values in spring and summer indicative of non-spherical particles of dust origin. The aerosol-climate implications are evaluated via the aerosol radiative forcing (ARF), which is estimated via the synergy of OPAC and SBDART models. On the monthly basis, the ARF values range from ∼ -30 to -90 W m-2 at the surface, while aerosols cause an overall cooling effect at the top of atmosphere (approx. -5 to -15 W m-2). The atmospheric heating via aerosol absorption results in heating rates of 1.2-1.6 K day-1 during March-June, which may contribute to changes in monsoon circulation over northern India and the Himalayas.

Carbonaceous aerosols and pollutants over Delhi urban environment: Temporal evolution, source apportionment and radiative forcing.

Particulate matter (PM2.5) samples were collected over Delhi, India during January to December 2012 and analysed for carbonaceous aerosols and inorganic ions (SO4(2-) and NO3(-)) in order to examine variations in atmospheric chemistry, combustion sources and influence of long-range transport. The PM2.5 samples are measured (offline) via medium volume air samplers and analysed gravimetrically for carbonaceous (organic carbon, OC; elemental carbon, EC) aerosols and inorganic ions (SO4(2-) and NO3(-)). Furthermore, continuous (online) measurements of PM2.5 (via Beta-attenuation analyser), black carbon (BC) mass concentration (via Magee scientific Aethalometer) and carbon monoxide (via CO-analyser) are carried out. PM2.5 (online) range from 18.2 to 500.6µgm(-3) (annual mean of 124.6±87.9µgm(-3)) exhibiting higher night-time (129.4µgm(-3)) than daytime (103.8µgm(-3)) concentrations. The online concentrations are 38% and 28% lower than the offline during night and day, respectively. In general, larger night-time concentrations are found for the BC, OC, NO3(-)and SO4(2-), which are seasonally dependent with larger differences during late post-monsoon and winter. The high correlation (R(2)=0.74) between OC and EC along with the OC/EC of 7.09 (day time) and 4.55 (night-time), suggest significant influence of biomass-burning emissions (burning of wood and agricultural waste) as well as secondary organic aerosol formation during daytime. Concentrated weighted trajectory (CWT) analysis reveals that the potential sources for the carbonaceous aerosols and pollutants are local emissions within the urban environment and transported smoke from agricultural burning in northwest India during post-monsoon. BC radiative forcing estimates result in very high atmospheric heating rates (~1.8-2.0Kday(-1)) due to agricultural burning effects during the 2012 post-monsoon season.

Dryness of ephemeral lakes and consequences for dust activity: the case of the Hamoun drainage basin, southeastern Iran.

This study examines the influence of changes in the water coverage in the Hamoun dry-bed lakes on visibility, dust outbreaks, aerosol loading and land-atmospheric fluxes over the region covering the period 1985-2005. The Hamoun basin, located on the southeastern Iran and western Afghanistan borders, has been recognized as one of the major dust source regions in south Asia and is covered by shallow, marshy lakes that are fed by the Helmand and Farahrood rivers. When the water in watersheds that support the lakes is drawn down for natural or human-induced reasons, the end result is a decrease in the water coverage in the basin, or even complete dryness as occurred in 2001. Then, strong seasonal winds, mainly in summer, blow fine sand and silt off the exposed lakebed, enhancing dust activity and aerosol loading over the region. Satellite (Landsat) and meteorological observations reveal that the water levels in the Hamoun lakes exhibit considerable inter-annual variability during the period 1985-2005 strongly related to anomalies in precipitation. This is the trigger for concurrent changes in the frequency of the dusty days, aerosol loading and deterioration of visibility over the region, as satellite (TOMS, MODIS, MISR) observations reveal. On the other hand, soil moisture and latent heat, obtained via model (GLDAS_noah-10) simulations are directly linked with water levels and precipitation over the region. The desiccation of the Hamoun lakes in certain years and the consequent increase in frequency and intensity of dust storms are serious concerns for the regional climate, ecosystems and human health.

Assessment of chemical and mineralogical characteristics of airborne dust in the Sistan region, Iran.

Windblown transport and deposition of dust is widely recognized as an important physical and chemical concern to climate, human health and ecosystems. Sistan is a region located in southeast Iran with extensive wind erosion, severe desertification and intense dust storms, which cause adverse effects in regional air quality and human health. To mitigate the impact of these phenomena, it is vital to ascertain the physical and chemical characteristics of airborne and soil dust. This paper examines for the first time, the mineralogical and chemical properties of dust over Sistan by collecting aerosol samples at two stations established close to a dry-bed lake dust source region, from August 2009 to August 2010. Furthermore, soil samples were collected from topsoil (0-5 cm depth) at several locations in the dry-bed Hamoun lakes and downwind areas. These data were analyzed to investigate the chemical and mineralogical characteristics of dust, relevance of inferred sources and contributions to air pollution. X-ray Diffraction (XRD) analysis of airborne and soil dust samples shows that the dust mineralogy is dominated mainly by quartz (30-40%), calcite (18-23%), muscovite (10-17%), plagioclase (9-12%), chlorite (~6%) and enstatite (~3%), with minor components of dolomite, microcline, halite and gypsum. X-ray Fluorescence (XRF) analyses of all the samples indicate that the most important oxide compositions of the airborne and soil dust are SiO(2), CaO, Al(2)O(3), Na(2)O, MgO and Fe(2)O(3), exhibiting similar percentages for both stations and soil samples. Estimates of Enrichment Factors (EFs) for all studied elements show that all of them have very low EF values, suggesting natural origin from local materials. The results suggest that a common dust source region can be inferred, which is the eroded sedimentary environment in the extensive Hamoun dry lakes lying to the north of Sistan.

Case study of a dust storm over Hyderabad area, India: its impact on solar radiation using satellite data and ground measurements.

According to the Earth Observatory dust outbreaks are considered as natural hazards, which affect the ecosystems and human life. The main objective of this study is to assess and monitor the movement of aerosols and pollutants from local or other sources, both natural and anthropogenic, using a combination of ground-based monitoring and satellite data. The turbid and polluted atmosphere in the densely-populated area of Hyderabad, India is further degradated from dust outbreaks originated from Thar desert. A dust event occurred during 10th to 11th April 2006 in the northwest region of India; its plume substantially spreaded across the downwind direction affecting the study region. Using both irradiance measurements and satellite data this dust event is investigated. The analysis shows a significant change in Aerosol Optical Depth (AOD), Aerosol Index (AI) and aerosol-particle size during the dust event. The Aerosol Optical Depth in the dusty day is about 0.2 higher than the previous non-dusty days, while the Angström exponent rapidly decreases when the dust plume affected the study area. The surface PM concentrations show enhanced values during the dusty day directly influenced by the dust deposition. There is also a remarkable decrease in ground-reaching global radiation, UV erythemal (UV(ery)) and other irradiance components. The analysis suggested that the use of the diffuse-to-direct-beam ratio is the most appropriate parameter for the dust monitoring since its values at the longer wavelengths are not affected by the solar zenith angle.