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1.
Opt Express ; 27(13): 17868-17875, 2019 Jun 24.
Article in English | MEDLINE | ID: mdl-31252739

ABSTRACT

We demonstrated a bi-directional, Er-doped dual comb fiber laser consisting of all-polarization-maintaining fiber devices. Polyimide films in which single-wall carbon nanotubes (SWNTs) were dispersed were used as the in-line saturable absorber. In order to avoid synchronization of the two combs and associated damage to the SWNT film, a two-branch configuration with two SWNT films was employed. Soliton pulses with almost the same optical spectra were generated stably in each direction, and dual comb beats were observed simply by overlapping the two outputs. The repetition frequency was 28 MHz, and the frequency difference was 105-140 Hz. Thanks to the small frequency difference, dual comb beats corresponding to the whole optical spectrum were observed without any overlapping. Fourier transform spectroscopy using the developed dual comb source was examined, and the characteristics of an optical filter were successfully obtained.

2.
Nanoscale ; 9(17): 5389-5393, 2017 May 04.
Article in English | MEDLINE | ID: mdl-28422249

ABSTRACT

Clarification of the interactions between carbon nanotubes (CNTs) and proteinogenic amino acids is a key approach to understanding CNT-protein interactions. Previous studies have addressed the mechanism of the physical adsorption of amino acids onto CNTs. However, little is known about their chemical reactions in aqueous solutions. Here, we established dispersant-free systems to clarify intrinsic CNT-thiol interactions. We demonstrated that the redox reaction of CNTs with cysteine, containing a thiol group, leads to disulfide bond formation between cysteine molecules, even under acidic conditions. The generality of the redox reaction is validated using other thiols such as dithiothreitol and glutathione. The present results suggest that structures of proteins and peptides containing free thiol groups are chemically modified and misfolded on CNT surfaces by this disulfide bond formation in biological systems.

3.
Biomed Opt Express ; 5(3): 932-43, 2014 Mar 01.
Article in English | MEDLINE | ID: mdl-24688825

ABSTRACT

We developed a high power supercontinuum source at a center wavelength of 1.7 µm to demonstrate highly penetrative ultrahigh-resolution optical coherence tomography (UHR-OCT). A single-wall carbon nanotube dispersed in polyimide film was used as a transparent saturable absorber in the cavity configuration and a high-repetition-rate ultrashort-pulse fiber laser was realized. The developed SC source had an output power of 60 mW, a bandwidth of 242 nm full-width at half maximum, and a repetition rate of 110 MHz. The average power and repetition rate were approximately twice as large as those of our previous SC source [20]. Using the developed SC source, UHR-OCT imaging was demonstrated. A sensitivity of 105 dB and an axial resolution of 3.2 µm in biological tissue were achieved. We compared the UHR-OCT images of some biological tissue samples measured with the developed SC source, the previous one, and one operating in the 1.3 µm wavelength region. We confirmed that the developed SC source had improved sensitivity and penetration depth for low-water-absorption samples.

4.
Opt Lett ; 37(24): 5079-81, 2012 Dec 15.
Article in English | MEDLINE | ID: mdl-23258011

ABSTRACT

A high-power, passively mode-locked, Er-doped fiber laser with a single wall carbon nanotube polyimide film was demonstrated in dispersion-managed dissipative-soliton mode-locking operation. The average maximum power of 285 mW and a pulse energy of 8.1 nJ are the highest values yet achieved for single-pulse operation in a nanotube fiber laser. A high-power ultrashort pulse of 680 fs was generated by dispersion compensation at a repetition rate of 34.9 MHz. Passive mode-locking was numerically analyzed, and the dynamics and output properties are discussed.

5.
Opt Express ; 19(22): 21874-9, 2011 Oct 24.
Article in English | MEDLINE | ID: mdl-22109039

ABSTRACT

We investigated a dispersion-managed, passively mode-locked, ultrashort-pulse, Er-doped fiber laser using a polyimide film containing dispersed single-wall carbon nanotubes (SWNTs) and examined the dependence on net cavity dispersion and output coupling ratio using normal-dispersion fibers and a variable output coupler. For the dissipative soliton mode-locking condition, we achieved a pulse energy of 3.5 nJ and an average power of 114 mW, the highest values yet reported for an SWNT fiber laser under single-pulse operation.

6.
Opt Express ; 18(20): 20673-80, 2010 Sep 27.
Article in English | MEDLINE | ID: mdl-20940963

ABSTRACT

An ultralow-repetition-rate, all-polarization-maintaining (PM), Er-doped, ultrashort-pulse fiber laser was demonstrated using a single-wall-carbon-nanotube polyimide film. Using a ring cavity configuration, output pulses with pulse energy of 0.7-2.6 nJ were obtained at an ultralow repetition rate of 943-154 kHz for a fiber length of 0.1-1.3 km. A novel θ (theta) cavity configuration was proposed, which enabled us to reduce the required fiber length by half. A repetition rate of 132 kHz was achieved using this configuration with 909 m of PM fiber.

7.
Opt Express ; 17(22): 20233-41, 2009 Oct 26.
Article in English | MEDLINE | ID: mdl-19997248

ABSTRACT

A high-energy, wavelength-tunable, all-polarization-maintaining Er-doped ultrashort fiber laser was demonstrated using a polyimide film dispersed with single-wall carbon nanotubes. A variable output coupler and wavelength filter were used in the cavity configuration, and high-power operation was demonstrated. The maximum average power was 12.6 mW and pulse energy was 585 pJ for stable single-pulse operation with an output coupling ratio as high as 98.3%. Wide wavelength-tunable operation at 1532-1562 nm was also demonstrated by controlling the wavelength filter. The RF amplitude noise characteristics were examined in terms of their dependence on output coupling ratio and oscillation wavelength.


Subject(s)
Fiber Optic Technology/instrumentation , Lasers, Solid-State , Lasers , Membranes, Artificial , Nanotubes, Carbon/chemistry , Nanotubes, Carbon/ultrastructure , Resins, Synthetic/chemistry , Computer-Aided Design , Equipment Design , Equipment Failure Analysis , Refractometry/instrumentation , Reproducibility of Results , Sensitivity and Specificity
8.
Phys Rev Lett ; 102(4): 046804, 2009 Jan 30.
Article in English | MEDLINE | ID: mdl-19257457

ABSTRACT

The excitement of nano-test-tube chemistry in a single-walled carbon nanotube is exemplified in our study on electron doping in carbon nanotubes. Electron doping through the 1D van Hove singularity of single-walled carbon nanotubes is realized via a chemical reaction of an encapsulated organocerium compound, CeCp3. The decomposition of CeCp3 inside the carbon nanotubes increases the doping level and greatly enhances the density of conduction electrons. The transition of the cerium encapsulating semiconducting tubes to metallic results in enhanced screening of the photoexcited core hole potential. This fact illustrates the importance of many body effects in understanding core-level excitation process in carbon nanotubes.

9.
Phys Rev Lett ; 101(6): 065507, 2008 Aug 08.
Article in English | MEDLINE | ID: mdl-18764476

ABSTRACT

The dynamics of confined systems is of major concern for both fundamental physics and applications. In this Letter, the dynamics of C60 fullerene molecules inside single walled carbon nanotubes is studied using inelastic neutron scattering. We identify the C60 vibrations and highlight their sensitivity to temperature. Moreover, a clear signature of rotational diffusion of the C60 is evidenced, which persists at lower temperature than in 3D bulk C60. It is discussed in terms of confinement and of reduced dimensionality of the C60 chain.

10.
Opt Express ; 16(13): 9429-35, 2008 Jun 23.
Article in English | MEDLINE | ID: mdl-18575508

ABSTRACT

We present an all-polarization-maintaining Er-doped ultrashort-pulse fiber laser using a single-wall carbon nanotube polyimide nanocomposite saturable absorber. The maximum average power for single-pulse operation is 4.8 mW, and the repetition frequency is 41.3 MHz. Self-start and stable mode-locking operation is achieved. The RF amplitude noise is also examined and it is confirmed that the noise figure is as low as that of a solid-state laser. Using a polarization-maintaining anomalous dispersive fiber, a 314 fs output pulse is compressed to 107 fs via higher-order soliton compression. The peak power of the compressed pulse is up to 1.1 kW.


Subject(s)
Amplifiers, Electronic , Fiber Optic Technology/instrumentation , Lasers, Solid-State , Models, Theoretical , Nanotubes, Carbon/chemistry , Oscillometry/instrumentation , Computer Simulation , Equipment Design , Equipment Failure Analysis , Light , Nanotubes, Carbon/ultrastructure , Scattering, Radiation
11.
J Nanosci Nanotechnol ; 5(2): 204-8, 2005 Feb.
Article in English | MEDLINE | ID: mdl-15853138

ABSTRACT

A novel, artificial neural network-based method is now available for obtaining the mean diameter of single wall carbon nanotube (SWCNT) samples from the diameter dispersive features of their Raman G-band. The method is demonstrated here for six different diameter SWCNT samples and 14 different excitation wavelengths. With an adequately large pool of standard nanotube samples, the suggested method is a useful complementary technique for SWCNT diameter analysis as it is capable of rapid diameter evaluation without prior knowledge of the relevant phonon dispersion relations.


Subject(s)
Artificial Intelligence , Carbon/chemistry , Nanotubes, Carbon/chemistry , Neural Networks, Computer , Spectrum Analysis, Raman , Feasibility Studies , Nanotechnology/methods
12.
Opt Express ; 13(20): 8025-31, 2005 Oct 03.
Article in English | MEDLINE | ID: mdl-19498832

ABSTRACT

We demonstrate passive mode locking of solid-state lasers by saturable absorbers based on carbon nanotubes (CNT). These novel absorbers are fabricated by spin-coating a polymer doped with CNTs onto commercial dielectric laser-mirrors. We obtain broadband artificial saturable absorber mirrors with ultrafast recovery times without the use of epitaxial growth techniques and the well-established spin-coating process allows the fabrication of devices based on a large variety of substrate materials. First results on passive mode locking of Nd:glass and Er/Yb:glass lasers are discussed. In the case of Er/Yb:glass we report the to our knowledge shortest pulse generated in a self-starting configuration based on Er/Yb:bulk-glass: 68 fs (45 fs Fourier-limit) at 1570 nm wavelength at a pulse-repetition rate of 85 MHz.

13.
Phys Rev Lett ; 93(9): 096805, 2004 Aug 27.
Article in English | MEDLINE | ID: mdl-15447126

ABSTRACT

We report on the first direct observation of a transition from a Tomonaga-Luttinger liquid to a Fermi-liquid behavior in potassium-intercalated mats of single-wall carbon nanotubes. Using high resolution photoemission spectroscopy, an analysis of the spectral shape near the Fermi level reveals a Tomonaga-Luttinger liquid power law scaling in the density of states for the pristine sample and for low dopant concentration. As soon as the doping is high enough to achieve a filling of the conduction bands of the semiconducting tubes, a distinct transition to metallic single-wall carbon nanotube bundles with the scaling behavior of a normal Fermi liquid occurs.

14.
Phys Rev Lett ; 90(22): 225501, 2003 Jun 06.
Article in English | MEDLINE | ID: mdl-12857318

ABSTRACT

Double wall carbon nanotubes were prepared by vacuum annealing of single wall carbon nanotubes filled with C60. Strong evidence is provided for a highly defect free and unperturbed environment in the interior of the tubes. This is concluded from unusual narrow Raman lines for the radial breathing mode of the inner tubes. Lorentzian linewidths scale down to 0.35 cm(-1) which is almost 10 times smaller than linewidths reported so far for this mode. A splitting is observed for the majority of the Raman lines. It is considered to originate from tube-tube interaction between one inner tube and several different outer tubes. The highest RBM frequency detected is 484 cm(-1) corresponding to a tube diameter of only 0.50 nm. Labeling of the Raman lines with the folding vector is provided for all inner tubes. This labeling is supported by density functional calculations.

15.
Phys Rev Lett ; 87(26): 267401, 2001 Dec 24.
Article in English | MEDLINE | ID: mdl-11800854

ABSTRACT

Doping induced polymerization of C(60) inside single-walled carbon nanotubes is reported using Raman spectroscopy and resistivity measurements as a probe. The resistivity changes from semiconducting for the undoped system to metallic for the doped system. For full intercalation, we observe a chemical reaction inside the nanotubes which leads to a one-dimensional polymeric C(60)(-6) chain which has metallic character. The resonance and the oscillations of the radial breathing mode are lost suggesting an up-shift of the Fermi level to beyond the third Van Hove singularity in the semiconducting tubes. The linewidth of the radial breathing mode now represents directly the Gaussian distribution of tube diameters.

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