How the EU Soil Observatory contributes to a stronger soil erosion community.

New policy developments have emerged in relation to soil conservation after 2020. The Common Agricultural Policy (CAP) 2023-2027, the proposal for a Soil Monitoring Law and the mission 'A Soil Deal for Europe' have shaped a new policy framework at EU level, which requires updated assessments on soil erosion and land degradation. The EU Soil Observatory (EUSO) successfully organised a scientific workshop on 'Soil erosion for the EU' in June 2022. The event has seen the participation of more than 330 people from 63 countries, addressing important topics such as (i) management practices, (ii) large scale modelling, (iii) the importance of sediments in nutrient cycle, (vi) the role of landslides and (v) laying the foundations for early career scientists. As a follow up, among the 120 abstracts submitted in the workshop, we received fifteen manuscripts, out of which nine were selected for publication in the present special issue. In this editorial, we summarize the major challenges that the soil erosion research community faces in relation to supporting the increasing role of soils in the EU Green Deal.

Occurrence and dissipation mechanism of organic pollutants during the composting of sewage sludge: A critical review.

Sewage sludge contains various classes of organic pollutants, limiting its land application. Sludge composting can effectively remove some organic pollutants. This review summarizesrecent researches on concentration changes and dissipation of different organic pollutants including persistent organic pollutants during sludge composting, and discusses their dissipation pathways and the current understanding on dissipation mechanism. Some organic pollutants like PAHs and phthalates were removed mainly through biodegradation or mineralization, and their dissipation percentages were higher than those of PCDD/Fs and PCBs. Nevertheless, some recalcitrant organic pollutants could be sequestrated in organic fractions of sludge mixtures, and their levels and ARG abundance even increased after sludge composting in some studies, posing potential risks for land application. This review demonstrated that microbial community and their corresponding degradation for organic pollutants were influenced by different pollutants, bulking agents, composting methods and processes. Further research perspectives on removing organic pollutants during sludge composting were highlighted.

Perfluoroalkyl substances (PFASs) in air-conditioner filter dust of indoor microenvironments in Greece: Implications for exposure.

The occurrence of perfluoroalkyl substances (PFASs) was for the first time investigated in various working microenvironments (internet cafes, electronics shops, coffee shops, restaurants, etc.) in Thessaloniki, Greece, using the dust trapped by central air conditioner (A/C) filters. Perfluorooctane sulfonic acid (PFOS) was found in the range from 16 to 227 ng g-1, however it was detectable in only 30% of samples. On the contrary, perfluorohexanoic acid (PFHxA) was found in 85% of samples in the range from 3.6 to 72.5 ng g-1, while 90-95% of samples exhibited perfluorooctanoic acid (PFOA), perfluorodecanoic acid (PFDcA) and perfluorododecanoic acid (PFDoDA) in the range from 10-653 ng g-1, 3.2-7.4 ng g-1 and 3.8-13.1 ng g-1, respectively. The PFAS profile varied largely among the different microenvironment categories suggesting different sources. Estimated daily intakes through dust ingestion were calculated.

Organic micropollutants in the surface riverine sediment along the lower stretch of the transboundary river Ganga: Occurrences, sources and ecological risk assessment.

The Hooghly River (HR) estuary is the first deltaic off-shoot of the perennial and transboundary river, Ganga, India. HR receives industrial and domestic waste along with storm-water run-off from Kolkata city and the adjoining districts. Organic micropollutants (OMPs) have been collectively termed for plasticizers, pharmaceuticals and personal care products, which are extensively consumed and disposed in the waste streams. Hence emerging OMPs were investigated to obtain the first baseline data from the Hooghly riverine sediment (HRS) along urban and suburban transects using gas chromatography mass spectrometry (GC-MS). The concentration range of OMPs in the HRS varied between 3 and 519 ng/g for carbamazepine, 5-407 ng/g for non-steroidal anti-inflammatory drugs (NSAIDs), 2-26 ng/g for musk ketone, 2-84 ng/g for triclosan, 2-199 ng/g for bisphenol A (BPA), 2-422 ng/g for plasticizers (phthalic acid esters (PAEs) and bis (2-ethylhexyl) adipate (DEHA)) and 87-593 ng/g for parabens. Carbamazepine concentration in sediment was an useful marker for untreated wastewater in urban waterways. High concentrations of BPA and PAEs in the suburban industrial corridor together with significant correlation between these two type of OMPs (r2 = 0.5; p < 0.01) likely reflect a common source, possibly associated with the plastic and electronic scrap recycling industries. Among all the categories of OMPs, plasticizers seems to exhibit maximum screening level ecological risk through out the study area.

Soil erosion modelling: The new challenges as the result of policy developments in Europe.

New challenges and policy developments after 2015 (among others, the Common Agricultural Policy (CAP), Sustainable Development Goals (SDGs)) are opportunities for soil scientists and soil erosion modellers to respond with more accurate assessments and solutions as to how to reduce soil erosion and furthermore, how to reach Zero Net Land Degradation targets by 2030. This special issue includes papers concerning the use of fallout for estimating soil erosion, new wind erosion modelling techniques, the importance of extreme events (forest fires, intense rainfall) in accelerating soil erosion, management practices to reduce soil erosion in vineyards, the impact of wildfires in erosion, updated methods for estimating soil erodibility, comparisons between sediment distribution models, the application of the WaTEM/SEDEM model in Europe, a review of the G2 model and a proposal for a land degradation modelling approach. New data produced from field surveys such as LUCAS topsoil and the increasing availability of remote sensing data may facilitate the work of erosion modellers. Finally, better integration with other soil related disciplines (soil carbon, biodiversity, compaction and contamination) and Earth Systems modelling is the way forward for a new generation of erosion process models.

Polycyclic Aromatic Hydrocarbons Not Declining in Arctic Air Despite Global Emission Reduction.

Two decades of atmospheric measurements of polycyclic aromatic hydrocarbons (PAHs) were conducted at three Arctic sites, i.e., Alert, Canada; Zeppelin, Svalbard; and Pallas, Finland. PAH concentrations decrease with increasing latitude in the order of Pallas > Zeppelin > Alert. Forest fire was identified as an important contributing source. Three representative PAHs, phenanthrene (PHE), pyrene (PYR), and benzo[ a]pyrene (BaP) were selected for the assessment of their long-term trends. Significant decline of these PAHs was not observed contradicting the expected decline due to PAH emission reductions. A global 3-D transport model was employed to simulate the concentrations of these three PAHs at the three sites. The model predicted that warming in the Arctic would cause the air concentrations of PHE and PYR to increase in the Arctic atmosphere, while that of BaP, which tends to be particle-bound, is less affected by temperature. The expected decline due to the reduction of global PAH emissions is offset by the increment of volatilization caused by warming. This work shows that this phenomenon may affect the environmental occurrence of other anthropogenic substances, such as more volatile flame retardants and pesticides.

Seasonal soil/snow-air exchange of semivolatile organic pollutants at a coastal arctic site (Tromsø, 69°N).

Soils are a major reservoir of semivolatile organic pollutants such as polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs), and exert a control on their atmospheric occurrence. We present here an assessment of the atmospheric occurrence and seasonality of soil/snow-air partitioning and exchange of PCBs, PAHs, hexachlorobenzene (HCB), and hexachlorocyclohexanes (HCHs) in the arctic city Tromsø, northern Norway. The fugacities of the organic pollutants in soils and snow were determined using a soil fugacity sampler by equilibrating the air concentrations with those in the surface soil/snow. The concentrations in soils did not show a significant seasonality. Conversely, the ambient air concentrations and the soil (or snow) fugacity showed a clear seasonality for PCBs, HCH, HCB and some PAHs, related to temperature. Fugacities in soil/snow were correlated with those in the ambient gas phase, suggesting a close seasonal air-soil/snow coupling. Generally, there was a net deposition or close to equilibrium conditions during the winter, which contrasts with the net volatilization observed during the warmer periods. The chemicals with lower octanol-air partition coefficients showed a larger tendency for being volatilized and thus remobilized from this coastal arctic environment. Conversely, the more hydrophobic compounds were close to air-soil/snow equilibrium or showed a net deposition.

Soil contamination and sources of phthalates and its health risk in China: A review.

Phthalates (PAEs) are extensively used as plasticizers and constitute one of the most frequently detected organic contaminants in the environment. With the deterioration of eco-environment in China during the past three decades, many studies on PAE occurrence in soils and their risk assessments have been conducted which allow us to carry out a fairly comprehensive assessment of soil PAE contamination on a nation-wide scale. This review combines the updated information available associated with PAE current levels, distribution patterns (including urban soil, rural or agricultural soil, seasonal and vertical variations), potential sources, and human health exposure. The levels of PAEs in soils of China are generally at the high end of the global range, and higher than the grade II limits of the Environmental Quality Standard for soil in China. The most abundant compounds, di-n-butyl phthalate (DBP) and di-(2-ethylhexyl) phthalate (DEHP), display obvious spatial distribution in different provinces. It is noted that urbanization and industrialization, application of plastic film (especially plastic film mulching in agricultural soil) and fertilizer are the major sources of PAEs in soil. Uptake of PAEs by crops, and human exposure to PAEs via ingestion of soil and vegetables are reviewed, with scientific gaps highlighted.

Polycyclic aromatic hydrocarbons (PAHs) in Chinese forest soils: profile composition, spatial variations and source apportionment.

Previous studies reported that forest ecosystems can play a vital role in scavenging anthropogenic polycyclic aromatic hydrocarbons (PAHs) and act as primary reservoirs of these environmental pollutants. The present study aimed to investigate the occurrence, spatial pattern and source apportionment of PAHs across Chinese background forest soils (O- & A-horizons). The 143 soils collected from 30 mountains showed significantly (p < 0.05) higher levels of ∑15PAHs (ng g-1 dw) in O-horizon (222 ± 182) than A-horizon (168 ± 161). A progressive increase in the levels of lighter PAHs was observed along altitudinal gradient, however heavier PAHs did not show any variations. Carbon contents (TOC & BC) of forest soils were found weakly correlated (p < 0.01) with low molecular weight (LMW)-PAHs but showed no relation with high molecular weight (HMW)-PAHs. Source apportionment results using PMF and PCA revealed that PAHs in forest soils mainly come from local biomass burning and/or coal combustion and attributed that forest soils may become a potential sink for PAHs in the region.

Microplastic in the surface waters of the Ross Sea (Antarctica): Occurrence, distribution and characterization by FTIR.

This is the first survey to investigate the occurrence and extent of microplastic (MPs) contamination in sub surface waters collected near-shore and off-shore the coastal area of the Ross Sea (Antarctica). Moreover, a non-invasive method to analyze MPs, consisting in filtration after water sampling and analysis of the dried filter through Fourier Transform Infrared Spectroscopy (FTIR) 2D Imaging, using an FPA detector, was proposed. The non-invasiveness of analytical set-up reduces potential bias and allows subsequent analysis of the filter sample for determination of other classes of contaminants. MPs ranged from 0.0032 to 1.18 particle per m3 of seawater, with a mean value of 0.17 ± 0.34 particle m-3, showing concentrations lower than those found in the oceans worldwide. MPs included fragments (mean 71.9 ± 21.6%), fibers (mean 12.7 ± 14.3%), and others (mean 15.4 ± 12.8%). The presence of different types of MPs was confirmed by FTIR spectroscopy, with predominant abundance of polyethylene and polypropylene. The potential environmental impact arising from scientific activities, such as marine activities for scientific purposes, and from the sewage treatment plant, was also evidenced.

A Review on the Abundance, Distribution and Eco-Biological Risks of PAHs in the Key Environmental Matrices of South Asia.

Polycyclic aromatic hydrocarbons (PAHs) are consistently posing high risks to human/biota in developing countries of South Asia where domestic areas are exposed to biomass burning and commercial/industrial activities. This review article summarized the available data on PAHs occurrence, distribution, potential sources and their possible risks in the key environmental matrices (i.e., Air, Soil/Sediments, Water) from South Asian Region (SAR). Available literature reviewed suggested that PAHs concentration levels were strongly influenced by the monsoonal rainfall system in the region and it has been supported by many studies that higher concentrations were measured during the winter season as compared to summer. Biomass burning (household and brick kilns activities), open burning of solid wastes and industrial and vehicular emissions were categorized as major sources of PAHs in the region. Regional comparison revealed that the contamination levels of PAHs in the water bodies and soil/sediments in SAR remained higher relatively to the reports from other regions of the world. Our findings highlight that there is still a general lack of reliable data, inventories and research studies addressing PAHs related issues in the context of environmental and human health in SAR. There is therefore a critical need to improve the current knowledge base, which should build upon the research experience from other regions which have experienced similar situations in the past. Further research into these issues in South Asia is considered vital to help inform future policies/control strategies as already successfully implemented in other countries.

Legacy and emerging flame retardants (FRs) in the freshwater ecosystem: A review.

In this review article, we have compiled and reviewed the previously published available literature on environmental distribution, behaviour, fate and regional trends of legacy and emerging flame retardants (FRs) including brominated (BFRs), organo-phosphate (OPFRs), novel brominated flame retardants (NBFRs) and dechlorane plus (DP) in the freshwater ecosystem. Transport and fate is discussed briefly with the evidences of de-bromination, sedimentation and accumulation in biota. De-bromination of BDE-209 is considered of concern because the lower brominated congeners are more toxic and mobile thus posing increased risk to the freshwater ecosystem. The available data on temporal and spatial trends as yet, is too few to show any consistent trends, enabling only general conclusions to be drawn. There is a lack of temporal studies in Asia, while, overall the trends are mixed, with both increasing and decreasing concentrations of BFRs and OPFRs. OPFRs and NBFRs have replaced classical BFRs (polybrominated diphenyl ethers (PBDEs)) in some countries but the amount of PBDEs in the environment is still considerable. Knowledge gaps and recommendations for future research are discussed emphasizing on further monitoring, advanced analytical methodologies, and risk assessment studies to completely understand the science of flame retardants in the freshwater ecosystem.

Polychlorinated biphenyls and organochlorine pesticides in River Brahmaputra from the outer Himalayan Range and River Hooghly emptying into the Bay of Bengal: Occurrence, sources and ecotoxicological risk assessment.

River Brahmaputra (RB) from the outer Himalayan Range and River Hooghly (RH), a distributary of River Ganga, are the two largest transboundary perennial rivers supplying freshwater to the northeastern and eastern states of India. Given the history of extensive usage of organochlorine pesticides and increasing industrialization along the banks of these rivers we investigated selected organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in the surface water of River Brahmaputra and River Hooghly. Geomean of ΣOCPs (53 ng L-1) and Σ19PCBs (108 ng L-1) was higher in RH compared with geomean of ΣOCPs (24 ng L-1) and Σ19PCBs (77 ng L-1) in RB. Among OCPs, γ-HCH showed maximum detection frequency in both the rivers reflecting ongoing lindane usage. DDT and endosulfan residues were observed at specific locations where past or ongoing sources exist. Elevated concentrations of heavier congeners (penta-hepta) were observed in those sites along RH where port and industrial activities were prevalent including informal electronic waste scrap processing units. Furthermore along River Hooghly PCB-126 was high in the suburban industrial belt of Howrah district. PCBs were found to be ubiquitously distributed in RB. Atmospheric transport of tri- and tetra-PCB congeners from the primary source regions might be a major contributor for PCBs in RB. Heavier congeners (penta-nona) in the urban centers of RB were likely due to industrial wastewater runoff from the oil refineries in the Brahmaputra valley. Σ19PCBs concentrations in this study exceeded the USEPA recommended limit for freshwater. Ecotoxicological risk assessment showed the possibility of adverse impact on the organisms in the lower trophic level due to DDT and lindane contamination. Impact of endosulfan on fishes might be of considerable concern for aquatic environment.

Ten years after entry into force of the Stockholm Convention: What do air monitoring data tell about its effectiveness?

More than a decade ago, the Stockholm Convention on Persistent Organic Pollutants (POPs), one of the multilateral environmental agreements administered by the United Nations Environment Programme (UNEP), entered into force. The objective of this Convention is to protect human health and the environment by controlling the releases of POPs. According to its Article 16, the effectiveness of the Stockholm Convention shall be evaluated using comparable monitoring data on the presence of POPs as well as their regional and global environmental transport. Here, we present a time series analysis on atmospheric POP concentrations from 15 monitoring stations in North America and Europe that provide long-term data and have started operations between 1990 and 2003. We systematically searched for temporal trends and significant structural changes in temporal trends that might result from the provisions of the Stockholm Convention. We find that such structural changes do occur, but they are related mostly to effects of national regulations enforced prior to the implementation of the Stockholm Convention, rather than to the enforcement of the provisions laid out in the Convention. One example is that concentrations of polychlorinated biphenyls, many of which started to decrease rapidly during the 1990s. Also effects of chemical transport and fate, for instance the re-volatilization of POPs from secondary sources, are thought to be a cause of some of the observed structural changes. We conclude that a decade of air monitoring data has not been sufficient for detecting general and statistically significant effects of the Stockholm Convention. Based on these lessons, we present recommendations for the future operation of existing monitoring programs and advocate for a stricter enforcement of the provisions of the Stockholm Convention, in the current absence of proof for its effectiveness.

The TOMPs ambient air monitoring network - Continuous data on UK air quality for over 20 years.

Long-term air monitoring datasets are needed for persistent organic pollutants (POPs) to assess the effectiveness of source abatement measures and the factors controlling ambient levels. The Toxic Organic Micro Pollutants (TOMPs) Network, which has operated since 1991, collects ambient air samples at six sites across England and Scotland, using high-volume active air samplers. The network provides long-term ambient air trend data for a range of POPs at both urban and rural locations. Data from the network provides the UK Government, regulators and researchers with valuable information on emission/source controls and on the effectiveness of international chemicals regulation such as the Stockholm Convention and UN/ECE Protocol on POPs. The target chemicals of TOMPs have been polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and, since 2010, polybrominated diphenyl ethers (PBDEs). The continuous monitoring of these compounds demonstrates the constant decline in UK air concentrations over the last two decades, with average clearance rates for PCDD/Fs in urban locations of 5.1 years and for PCBs across all sites 6.6 years. No significant declines in rural locations for PCDD/Fs have been observed. There is a strong observable link between the declining ambient air concentrations and the emission reductions estimated in the annually produced National Atmospheric Emission Inventory (NAEI) dataset. These findings clearly demonstrate the unique strengths of long-term consistent datasets for the evaluation of the success of chemical regulation and control.

Temporal trends of Persistent Organic Pollutants (POPs) in arctic air: 20 years of monitoring under the Arctic Monitoring and Assessment Programme (AMAP).

Temporal trends of Persistent Organic Pollutants (POPs) measured in Arctic air are essential in understanding long-range transport to remote regions and to evaluate the effectiveness of national and international chemical control initiatives, such as the Stockholm Convention (SC) on POPs. Long-term air monitoring of POPs is conducted under the Arctic Monitoring and Assessment Programme (AMAP) at four Arctic stations: Alert, Canada; Stórhöfði, Iceland; Zeppelin, Svalbard; and Pallas, Finland, since the 1990s using high volume air samplers. Temporal trends observed for POPs in Arctic air are summarized in this study. Most POPs listed for control under the SC, e.g. polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethanes (DDTs) and chlordanes, are declining slowly in Arctic air, reflecting the reduction of primary emissions during the last two decades and increasing importance of secondary emissions. Slow declining trends also signifies their persistence and slow degradation under the Arctic environment, such that they are still detectable after being banned for decades in many countries. Some POPs, e.g. hexachlorobenzene (HCB) and lighter PCBs, showed increasing trends at specific locations, which may be attributable to warming in the region and continued primary emissions at source. Polybrominated diphenyl ethers (PBDEs) do not decline in air at Canada's Alert station but are declining in European Arctic air, which may be due to influence of local sources at Alert and the much higher historical usage of PBDEs in North America. Arctic air samples are screened for chemicals of emerging concern to provide information regarding their environmental persistence (P) and long-range transport potential (LRTP), which are important criteria for classification as a POP under SC. The AMAP network provides consistent and comparable air monitoring data of POPs for trend development and acts as a bridge between national monitoring programs and SC's Global Monitoring Plan (GMP).