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1.
Bioresour Technol ; 403: 130835, 2024 Jul.
Article in English | MEDLINE | ID: mdl-38750827

ABSTRACT

Thermochemical treatment is significantly impacted by the physiochemical properties of lignocellulosic biomass. Traditional characterization methods lack granularity, requiring advanced analytical techniques for comprehensive biomass characterization. This study analyzed elemental composition and their distribution in untreated rice husk, rice straw, and bamboo chips at micron and sub-micron scales. Results reveal significant variations in composition and spatial distribution of metallic components among agro-residues. Thermogravimetric analysis shows divergent decomposition patterns, while spectroscopic analysis indicates structural complexities and distinct silica content. Surface mapping illustrates prevalent silica and alkali metals on rice husk and rice straw. Atomic force microscopy depicts distinctive surface morphologies, with rice straw exhibiting heightened roughness due to silica bodies. Inductively coupled plasma-mass-spectrometry identified the abundance of alkali and alkaline earth metals in rice waste. Time-of-flight secondary ion mass spectrometry elucidates elemental spatial localization, affirming heterogeneous distribution across rice waste and homogenous distribution across bamboo waste. This study bridges the gap between biomass composition and optimized thermochemical conversion outcomes.


Subject(s)
Biomass , Lignin , Oryza , Thermogravimetry , Oryza/chemistry , Lignin/chemistry , Metals , Sasa/chemistry , Microscopy, Atomic Force , Mass Spectrometry/methods , Waste Products , Temperature
2.
Bioresour Technol ; 387: 129634, 2023 Nov.
Article in English | MEDLINE | ID: mdl-37573981

ABSTRACT

Biochar production through thermochemical processing is a sustainable biomass conversion and waste management approach. However, commercializing biochar faces challenges requiring further research and development to maximize its potential for addressing environmental concerns and promoting sustainable resource management. This comprehensive review presents the state-of-the-art in biochar production, emphasizing quantitative yield and qualitative properties with varying feedstocks. It discusses the technology readiness level and commercialization status of different production strategies, highlighting their environmental and economic impacts. The review focuses on integrating machine learning algorithms for process control and optimization in biochar production, improving efficiency. Additionally, it explores biochar's environmental applications, including soil amendment, carbon sequestration, and wastewater treatment, showcasing recent advancements and case studies. Advances in biochar technologies and their environmental benefits in various sectors are discussed herein.


Subject(s)
Charcoal , Waste Management , Charcoal/chemistry , Soil/chemistry , Biomass
3.
Heliyon ; 8(10): e10943, 2022 Oct.
Article in English | MEDLINE | ID: mdl-36276756

ABSTRACT

Carbon nanotubes (CNTs) have been studied for more than twenty-five years due to their distinguishing features such as high tensile strength, high elastic module, high surface area, high thermal and electrical conductivity, making them ideal for a variety of applications. Nanotechnology and nanoscience researchers are working to develop CNTs with appropriate properties for possible future applications. New methodologies for their synthesis are clearly needed to be developed and refined. In this research, the authors look at the history and the recent developments of carbon nanotubes synthesis methods for CNTs, such as arc discharge, laser ablation, chemical vapour deposition and microwave irradiation. New immerging methods like microwave irradiation for the growth of CNTs and their composite was extensively reviewed. Low temperature and ultrafast growth of CNT through microwave irradiation technique were examined and discussed. In addition, all the techniques used for the CNTs characterization were also briefly discussed. Special attention was dedicated to the application of CNTs. This review has extensively explored future applications in the biomedical sector, industrial water purifications, CNTs composites, energy and storage devices.

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