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Carbohydr Res
; 338(16): 1641-50, 2003 Jul 29.
Article
in English
| MEDLINE
| ID: mdl-12873420
ABSTRACT
The addition of dimethyl phosphonate to six different hexofuranos-5-uloses in the presence of DBU, followed by esterification with methoxalyl chloride and then radical reduction, afforded 5-deoxy-5-dimethoxyphosphinyl-D- and L-hexofuranoses. The stereoselectivity of the deoxygenation and possible transition-state models are discussed.