Characterization of tars from recycling of PHA bioplastic and synthetic plastics using fast pyrolysis.

The aim of this study was to investigate the pyrolysis products of polyhydroxyalkanoates (PHAs), polyethylene terephthalate (PET), carbon fiber reinforced composite (CFRC), and block co-polymers (PS-b-P2VP and PS-b-P4VP). The studied PHA samples were produced at temperatures of 15 and 50 oC (PHA15 and PHA50), and commercially obtained from GlasPort Bio (PHAc). Initially, PHA samples were analyzed by nuclear magnetic resonance (NMR) spectroscopy and size exclusion chromatography (SEC) to determine the molecular weight, and structure of the polymers. Thermal techniques such as thermogravimetry (TG) and differential scanning calorimetry (DSC) analyses were performed for PHA, CFRC, and block co-polymers to investigate the degradation temperature range and thermal stability of samples. Fast pyrolysis (500 oC, ∼102 °C s-1) experiments were conducted for all samples in a wire mesh reactor to investigate tar products and char yields. The tar compositions were investigated by gas chromatography-mass spectrometry (GC-MS), and statistical modeling was performed. The char yields of block co-polymers and PHA samples (<2 wt. %) were unequivocally less than that of the PET sample (~10.7 wt. %). All PHA compounds contained a large fraction of ethyl cyclopropane carboxylate (~ 38-58 %), whereas PAH15 and PHA50 additionally showed a large quantity of 2-butenoic acid (~8-12 %). The PHAc sample indicated the presence of considerably high amount of methyl ester (~15 %), butyl citrate (~12.9 %), and tributyl ester (~17 %). The compositional analyses of the liquid fraction of the PET and block co-polymers have shown carcinogenic and toxic properties. Pyrolysis removed matrices in the CRFC composites which is an indication of potential recovery of the original fibers.

Development and Analysis of the Novel Hybridization of a Single-Flash Geothermal Power Plant with Biomass Driven sCO2-Steam Rankine Combined Cycle.

This study investigates the hybridization scenario of a single-flash geothermal power plant with a biomass-driven sCO2-steam Rankine combined cycle, where a solid local biomass source, olive residue, is used as a fuel. The hybrid power plant is modeled using the simulation software EBSILON®Professional. A topping sCO2 cycle is chosen due to its potential for flexible electricity generation. A synergy between the topping sCO2 and bottoming steam Rankine cycles is achieved by a good temperature match between the coupling heat exchanger, where the waste heat from the topping cycle is utilized in the bottoming cycle. The high-temperature heat addition problem, common in sCO2 cycles, is also eliminated by utilizing the heat in the flue gas in the bottoming cycle. Combined cycle thermal efficiency and a biomass-to-electricity conversion efficiency of 24.9% and 22.4% are achieved, respectively. The corresponding fuel consumption of the hybridized plant is found to be 2.2 kg/s.