ABSTRACT
The development trends in the energy sector clearly indicate an increase in the share of biomass and alternative fuels fed for combustion in power boilers, which results in the imposition of many unfavourable factors and a demanding working environment. During the operation of the energy system, this means a sharp increase in corrosion of the gas-tight pipe walls and coils by the destructive action of chlorine and sulphur. Implementing advanced surface protection in addition to the selection of materials of better quality and resistance to difficult working conditions would significantly reduce their wear by high temperature corrosion. Thermally sprayed coatings offer a great opportunity to protect machine components and energy systems against corrosion, erosion, impact load and abrasive wear. This article presents the test results of high-temperature corrosion resistance of coatings made with Ni-Cr-B-Si and Ni-B-Si alloy powders on a boiler steel substrate. Samples with sprayed coatings were exposed to an atmosphere with a composition of N2 + 9% O2 + 0.08% SO2 + 0.15% HCl at 800 °C for 250, 500, 750 and 1000 h. Tests results of coatings made of Ni-Cr-B-Si alloys subjected to the influence of a corrosive environment showed the formation of a layer of scale on the surface, composed mainly of Cr2O3 oxide, which was a passive layer, reducing the rate of corrosion. Coatings sprayed with Ni-B-Si alloys showed significantly lower corrosion resistance. It was found that the developed technology of subsonic flame spraying with powders of the Ni-Cr-B-Si type allows the production of coatings compliant with the requirements of the energy industry, which allows their use as anti-corrosion protection on boiler elements intended for waste disposal and biomass combustion.
ABSTRACT
This study discusses the effect of laser beam welding parameters on the structure, mechanical properties and corrosion resistance of 1.2 mm thick galvanized sheets made of low-carbon steel DC04 provided with a ZE36/36 GardoprotectOC2BU organic coating. The test laser beam butt welded joints were made without the filler metal, using a variable welding rate, where linear welding energy was restricted within the range of 30 J/mm to 90 J/mm. The joints were subjected to non-destructive tests, destructive tests and corrosion resistance tests. The tests revealed the possibility of making joints meeting the criteria specified in the ISO 15614-11 standard. Regardless of the value of linear welding energy applied in the process, all the joints were characterised by high mechanical and plastic properties. It was noticed that an increase in linear welding energy from 30 J/mm to 90 J/mm was accompanied by the widening of the weld and that of the heat-affected zone (HAZ). In addition, an increase in linear welding energy was accompanied by a decrease in the maximum weld hardness to approximately 250 HV0.2. In the HAZ, hardness was restricted within the range of 190 HV0.2 to 230 HV0.2 and decreased along with increasing linear welding energy. In the static tensile test, regardless of the value of linear welding energy, the test specimen ruptured in the base material. In the bend test, regardless of the value of linear welding energy, a bend angle of 180° was obtained without partial tear or scratches; unit elongation was restricted within the range of 29% to 42%. The electrochemical tests and experiments performed in the salt spray chamber revealed the very high effectiveness of the corrosion protections against aggressive chloride ions.
ABSTRACT
The article presents the results of the research on the influence of heat treatment conditions on corrosion resistance of newly developed HSLA-type (High Strength Low Alloy) steel in selected corrosive environments. Laboratory tests were carried out with using a salt spray chamber, enabling the continuous spraying of brine mist (5% NaCl) during 96 h under high humidity conditions. Additionally, as part of corrosion experiments, tests were carried out using the gravimetric method, in which the intensity of corrosive processes was measured by the linear corrosion rate. The research conducted revealed that the best corrosion resistance was noted for steel with a high-temperature tempered martensite microstructure. Investigated 0.28C-1.4Mn-0.3Si-0.26Cr steel with Nb, Ti, and V microadditions can be used in offshore drilling constructions and production platforms exposed to salts present in sea water, chlorides, sulfates, carbonates, and bromides, among others.
