ABSTRACT
The aggregation of dipolar chains driven by thermal fluctuations in an external strong (electric or magnetic) field is investigated theoretically. We discover a new simple electrostatic mechanism that rationalizes the counter-intuitive lateral coalescence of dipolar chains. There, we first demonstrate that two bent dipolar chains can either attract or repel each other depending if they possess similar or opposite curvatures, respectively. Upon bending, dipolar chains become the siege of polarization-induced local charges that in turn lead to quadrupolar couplings. This striking feature is then exploited to understand our conducted Monte Carlo simulations at finite temperature where thermal fluctuations cause local curvatures in the formed dipolar chains. The related quadrupolar attractive mode with correlated chain-curvatures is clearly identified in the simulation snapshots. Our findings shed new light on a longstanding problem in soft matter and related areas.
ABSTRACT
A striking and highly versatile feature of magnetic (nano)particles is their ability to be manipulated at will at a distance by external fields. In this paper, the influence of gravity on the self-assembly of dipolar particles near a surface in the presence of a strong vertical magnetic field is investigated theoretically. A rich ground-state phase diagram stems from the effects of the number of particles N and gravity. Two distinct regimes are discovered for the gravity-mediated breakup of a standing chain. When N is small, there is a chain fragmentation (with two widely separated repulsive chain fragments) above a critical value for the gravity, whereas for higher chains, ribbonization (with two cohesive chain fragments) sets in. In both scenarios, simple algebraic decays for the transition gravity as a function of N are analytically predicted and accurately corroborate the exact numerical results. Further intricate chain fragmentations and internal ribbon transformations operate upon further increasing the gravity until all N constitutive particles lie on the surface. Our findings shed additional light on various recent experiments and computer simulations on magnetic colloids and granular media.
ABSTRACT
The interaction of two dipolar hard spheres near a surface and under the influence of gravity and external perpendicular magnetic fields is investigated theoretically. The full ground-state phase diagram as a function of gravity and magnetic field strengths is established. A dimer (i.e., two touching beads) can only exist when the gravity and magnetic field strengths are simultaneously not too large. Thereby, upon increasing the magnetic field strength, three dimeric states emerge: a lying state (dimer axis parallel to the substrate), an inclined state (intermediate state between the lying and standing ones) and a standing state (dimer axis normal to the substrate). It is found that the orientation angles of the dimer axis and the dipole moment in the newly discovered inclined phase are related by a strikingly simple Snell-Descartes-like law. We argue that our findings can be experimentally verified in colloidal and granular systems.
