Subduction history of the Caribbean from upper-mantle seismic imaging and plate reconstruction.

The margins of the Caribbean and associated hazards and resources have been shaped by a poorly understood history of subduction. Using new data, we improve teleseismic P-wave imaging of the eastern Caribbean upper mantle and compare identified subducted-plate fragments with trench locations predicted from plate reconstruction. This shows that material at 700-1200 km depth below South America derives from 90-115 Myr old westward subduction, initiated prior to Caribbean Large-Igneous-Province volcanism. At shallower depths, an accumulation of subducted material is attributed to Great Arc of the Caribbean subduction as it evolved over the past 70 Ma. We interpret gaps in these subducted-plate anomalies as: a plate window and tear along the subducted Proto-Caribbean ridge; tearing along subducted fracture zones, and subduction of a volatile-rich boundary between Proto-Caribbean and Atlantic domains. Phases of back-arc spreading and arc jumps correlate with changes in age, and hence buoyancy, of the subducting plate.

A thin mantle transition zone beneath the equatorial Mid-Atlantic Ridge.

The location and degree of material transfer between the upper and lower mantle are key to the Earth's thermal and chemical evolution. Sinking slabs and rising plumes are generally accepted as locations of transfer1,2, whereas mid-ocean ridges are not typically assumed to have a role3. However, tight constraints from in situ measurements at ridges have proved to be challenging. Here we use receiver functions that reveal the conversion of primary to secondary seismic waves to image the discontinuities that bound the mantle transition zone, using ocean bottom seismic data from the equatorial Mid-Atlantic Ridge. Our images show that the seismic discontinuity at depths of about 660 kilometres is broadly uplifted by 10 ± 4 kilometres over a swath about 600 kilometres wide and that the 410-kilometre discontinuity is depressed by 5 ± 4 kilometres. This thinning of the mantle transition zone is coincident with slow shear-wave velocities in the mantle, from global seismic tomography4-7. In addition, seismic velocities in the mantle transition zone beneath the Mid-Atlantic Ridge are on average slower than those beneath older Atlantic Ocean seafloor. The observations imply material transfer from the lower to the upper mantle-either continuous or punctuated-that is linked to the Mid-Atlantic Ridge. Given the length and longevity of the mid-ocean ridge system, this implies that whole-mantle convection may be more prevalent than previously thought, with ridge upwellings having a role in counterbalancing slab downwellings.

Probing layered arc crust in the Lesser Antilles using receiver functions.

Oceanic arcs can provide insight into the processes of crustal growth and crustal structure. In this work, changes in crustal thickness and composition along the Lesser Antilles Arc (LAA) are analysed at 10 islands using receiver function (RF) inversions that combine seismological data with vP/vS ratios estimated based on crustal lithology. We collected seismic data from various regional networks to ensure station coverage for every major island in the LAA from Saba in the north to Grenada in the south. RFs show the subsurface response of an incoming signal assuming horizontal layering, where phase conversions highlight discontinuities beneath a station. In most regions of the Earth, the Mohorovicic discontinuity (Moho) is seismically stronger than other crustal discontinuities. However, in the LAA we observe an unusually strong along-arc variation in depth of the strongest discontinuity, which is difficult to explain by variations in crustal thickness. Instead, these results suggest that in layered crust, especially where other discontinuities have a stronger seismic contrast than the Moho, H-k stacking results can be easily misinterpreted. To circumvent this problem, an inversion modelling approach is introduced to investigate the crustal structure in more detail by building a one-dimensional velocity-depth profile for each island. Using this method, it is possible to identify any mid-crustal discontinuity in addition to the Moho. Our results show a mid-crustal discontinuity at about 10-25 km depth along the arc, with slightly deeper values in the north (Montserrat to Saba). In general, the depth of the Moho shows the same pattern with values of around 25 km (Grenada) to 35 km in the north. The results suggest differences in magmatic H2O content and differentiation history of each island.

Imaging Lithospheric Discontinuities Beneath the Northern East African Rift Using S-to-P Receiver Functions.

Imaging the lithosphere is key to understand mechanisms of extension as rifting progresses. Continental rifting results in a combination of mechanical stretching and thinning of the lithosphere, decompression upwelling, heating, sometimes partial melting of the asthenosphere, and potentially partial melting of the mantle lithosphere. The northern East African Rift system is an ideal locale to study these processes as it exposes the transition from tectonically active continental rifting to incipient seafloor spreading. Here we use S-to-P receiver functions to image the lithospheric structure beneath the northernmost East African Rift system where it forms a triple junction between the Main Ethiopian rift, the Red Sea rift, and the Gulf of Aden rift. We image the Moho at 31 ± 6 km beneath the Ethiopian plateau. The crust is 28 ± 3 km thick beneath the Main Ethiopian rift and thins to 23 ± 2 km in northern Afar. We identify a negative phase, a velocity decrease with depth, at 67 ± 3 km depth beneath the Ethiopian plateau, likely associated with the lithosphere-asthenosphere boundary (LAB), and a lack of a LAB phase beneath the rift. Using observations and waveform modeling, we show that the LAB phase beneath the plateau is likely defined by a small amount of partial melt. The lack of a LAB phase beneath the rift suggests melt percolation through the base of the lithosphere beneath the northernmost East African Rift system.

Marine Geophysical Investigation of the Chain Fracture Zone in the Equatorial Atlantic From the PI-LAB Experiment.

The Chain Fracture Zone is a 300-km-long transform fault that offsets the Mid-Atlantic Ridge. We analyzed new multibeam bathymetry, backscatter, gravity, and magnetic data with 100% multibeam bathymetric data over the active transform valley and adjacent spreading segments as part of the Passive Imaging of the Lithosphere Asthenosphere Boundary (PI-LAB) Experiment. Analyses of these data sets allow us to determine the history and mode of crustal formation and the tectonic evolution of the transform system and adjacent ridges over the past 20 Myr. We model the total field magnetic anomaly to determine the age of the crust along the northern ridge segment to better establish the timing of the variations in the seafloor fabric and the tectonic-magmatic history of the region. Within the active transform fault zone, we observe four distinct positive flower structures with several en échelon fault scarps visible in the backscatter data. We find up to -10 mGal residual Mantle Bouguer Anomaly in the region of the largest positive flower structure within the transform zone suggesting crustal thickening relative to the crustal thinning typically observed in fracture zones in the Atlantic. The extensional/compressional features observed in the Chain Transform are less pronounced than those observed further north in the Vema, St. Paul, and Romanche and may be due to local ridge segment adjustments.

The initiation of segmented buoyancy-driven melting during continental breakup.

Melting of the mantle during continental breakup leads to magmatic intrusion and volcanism, yet our understanding of the location and dominant mechanisms of melt generation in rifting environments is impeded by a paucity of direct observations of mantle melting. It is unclear when during the rifting process the segmented nature of magma supply typical of seafloor spreading initiates. Here, we use Rayleigh-wave tomography to construct a high-resolution absolute three-dimensional shear-wave velocity model of the upper 250 km beneath the Afar triple junction, imaging the mantle response during progressive continental breakup. Our model suggests melt production is highest and melting depths deepest early during continental breakup. Elevated melt production during continental rifting is likely due to localized thinning and melt focusing when the rift is narrow. In addition, we interpret segmented zones of melt supply beneath the rift, suggesting that buoyancy-driven active upwelling of the mantle initiates early during continental rifting.

Seismic evidence for flow in the hydrated mantle wedge of the Ryukyu subduction zone.

It is widely accepted that water-rich serpentinite domains are commonly present in the mantle above shallow subducting slabs and play key roles in controlling the geochemical cycling and physical properties of subduction zones. Thermal and petrological models show the dominant serpentine mineral is antigorite. However, there is no good consensus on the amount, distribution and alignment of this mineral. Seismic velocities are commonly used to identify antigorite-rich domains, but antigorite is highly-anisotropic and depending on the seismic ray path, its properties can be very difficult to distinguish from non-hydrated olivine-rich mantle. Here, we utilize this anisotropy and show how an analysis of seismic anisotropy that incorporates measured ray path geometries in the Ryukyu arc can constrain the distribution, orientation and amount of antigorite. We find more than 54% of the wedge must consist of antigorite and the alignment must change from vertically aligned to parallel to the slab. This orientation change suggests convective flow in the hydrated forearc mantle. Shear wave splitting analysis in other subduction zones indicates large-scale serpentinization and forearc mantle convection are likely to be more widespread than generally recognized. The view that the forearc mantle of cold subduction zones is dry needs to be reassessed.

First recorded eruption of Nabro volcano, Eritrea, 2011.

We present a synthesis of diverse observations of the first recorded eruption of Nabro volcano, Eritrea, which began on 12 June 2011. While no monitoring of the volcano was in effect at the time, it has been possible to reconstruct the nature and evolution of the eruption through analysis of regional seismological and infrasound data and satellite remote sensing data, supplemented by petrological analysis of erupted products and brief field surveys. The event is notable for the comparative rarity of recorded historical eruptions in the region and of caldera systems in general, for the prodigious quantity of SO2 emitted into the atmosphere and the significant human impacts that ensued notwithstanding the low population density of the Afar region. It is also relevant in understanding the broader magmatic and tectonic significance of the volcanic massif of which Nabro forms a part and which strikes obliquely to the principal rifting directions in the Red Sea and northern Afar. The whole-rock compositions of the erupted lavas and tephra range from trachybasaltic to trachybasaltic andesite, and crystal-hosted melt inclusions contain up to 3,000 ppm of sulphur by weight. The eruption was preceded by significant seismicity, detected by regional networks of sensors and accompanied by sustained tremor. Substantial infrasound was recorded at distances of hundreds to thousands of kilometres from the vent, beginning at the onset of the eruption and continuing for weeks. Analysis of ground deformation suggests the eruption was fed by a shallow, NW-SE-trending dike, which is consistent with field and satellite observations of vent distributions. Despite lack of prior planning and preparedness for volcanic events in the country, rapid coordination of the emergency response mitigated the human costs of the eruption.

Comparison of geomechanical deformation induced by megatonne-scale CO2 storage at Sleipner, Weyburn, and In Salah.

Geological storage of CO2 that has been captured at large, point source emitters represents a key potential method for reduction of anthropogenic greenhouse gas emissions. However, this technology will only be viable if it can be guaranteed that injected CO2 will remain trapped in the subsurface for thousands of years or more. A significant issue for storage security is the geomechanical response of the reservoir. Concerns have been raised that geomechanical deformation induced by CO2 injection will create or reactivate fracture networks in the sealing caprocks, providing a pathway for CO2 leakage. In this paper, we examine three large-scale sites where CO2 is injected at rates of ~1 megatonne/y or more: Sleipner, Weyburn, and In Salah. We compare and contrast the observed geomechanical behavior of each site, with particular focus on the risks to storage security posed by geomechanical deformation. At Sleipner, the large, high-permeability storage aquifer has experienced little pore pressure increase over 15 y of injection, implying little possibility of geomechanical deformation. At Weyburn, 45 y of oil production has depleted pore pressures before increases associated with CO2 injection. The long history of the field has led to complicated, sometimes nonintuitive geomechanical deformation. At In Salah, injection into the water leg of a gas reservoir has increased pore pressures, leading to uplift and substantial microseismic activity. The differences in the geomechanical responses of these sites emphasize the need for systematic geomechanical appraisal before injection in any potential storage site.

Deformation of the lowermost mantle from seismic anisotropy.

The lowermost part of the Earth's mantle-known as D″-shows significant seismic anisotropy, the variation of seismic wave speed with direction. This is probably due to deformation-induced alignment of MgSiO(3)-post-perovskite (ppv), which is believed to be the main mineral phase present in the region. If this is the case, then previous measurements of D″ anisotropy, which are generally made in one direction only, are insufficient to distinguish candidate mechanisms of slip in ppv because the mineral is orthorhombic. Here we measure anisotropy in D″ beneath North and Central America, where material from subducting oceanic slabs impinges on the core-mantle boundary, using shallow as well as deep earthquakes to increase the azimuthal coverage in D″. We make more than 700 individual measurements of shear wave splitting in D″ in three regions from two different azimuths in each case. We show that the previously assumed case of vertical transverse isotropy (where wave speed shows no azimuthal variation) is not possible, and that more complicated mechanisms must be involved. We test the fit of different MgSiO(3)-ppv deformation mechanisms to our results and find that shear on (001) is most consistent with observations and the expected shear above the core-mantle boundary beneath subduction zones. With new models of mantle flow, or improved experimental determination of the dominant ppv slip systems, this method will allow us to map deformation at the core-mantle boundary and link processes in D″, such as plume initiation, to the rest of the mantle.

Efficacy of the post-perovskite phase as an explanation for lowermost-mantle seismic properties.

Constraining the chemical, rheological and electromagnetic properties of the lowermost mantle (D'') is important to understand the formation and dynamics of the Earth's mantle and core. To explain the origin of the variety of characteristics of this layer observed with seismology, a number of theories have been proposed, including core-mantle interaction, the presence of remnants of subducted material and that D'' is the site of a mineral phase transformation. This final possibility has been rejuvenated by recent evidence for a phase change in MgSiO3 perovskite (thought to be the most prevalent phase in the lower mantle) at near core-mantle boundary temperature and pressure conditions. Here we explore the efficacy of this 'post-perovskite' phase to explain the seismic properties of the lowermost mantle through coupled ab initio and seismic modelling of perovskite and post-perovskite polymorphs of MgSiO3, performed at lowermost-mantle temperatures and pressures. We show that a post-perovskite model can explain the topography and location of the D'' discontinuity, apparent differences in compressional- and shear-wave models and the observation of a deeper, weaker discontinuity. Furthermore, our calculations show that the regional variations in lower-mantle shear-wave anisotropy are consistent with the proposed phase change in MgSiO3 perovskite.

Mid-mantle deformation inferred from seismic anisotropy.

With time, convective processes in the Earth's mantle will tend to align crystals, grains and inclusions. This mantle fabric is detectable seismologically, as it produces an anisotropy in material properties--in particular, a directional dependence in seismic-wave velocity. This alignment is enhanced at the boundaries of the mantle where there are rapid changes in the direction and magnitude of mantle flow, and therefore most observations of anisotropy are confined to the uppermost mantle or lithosphere and the lowermost-mantle analogue of the lithosphere, the D" region. Here we present evidence from shear-wave splitting measurements for mid-mantle anisotropy in the vicinity of the 660-km discontinuity, the boundary between the upper and lower mantle. Deep-focus earthquakes in the Tonga-Kermadec and New Hebrides subduction zones recorded at Australian seismograph stations record some of the largest values of shear-wave splitting hitherto reported. The results suggest that, at least locally, there may exist a mid-mantle boundary layer, which could indicate the impediment of flow between the upper and lower mantle in this region.