HFIP-Mediated Dual C(Ar)-Alkylation Process towards the Regioselective Synthesis of Triarylmethanes (TRAMs).

The distinct roles of different chemical species are essential for the discovery of novel chemical transformations in organic synthesis. Here, we have designed a potential strategy for the synthesis of triarylmethanes (TRAMs) using the dual C(aryl)-alkylation process. This protocol was influenced by 1,1,1,3,3,3-hexafluoro isopropanol (HFIP) as a pivotal reagent and proceeds through the selective para C-H functionalization method. The described approach has been proven to be highly efficient in terms of substrate scope with excellent functional group tolerance and gram scale synthesis of the desired product with 90% yield. The recyclability and reusability of HFIP has enhanced the feasibility of this protocol towards the sustainable synthesis of TRAMs.

Exploring optical, electrochemical, thermal, and theoretical aspects of simple carbazole-derived organic dyes.

This study highlights the recent advancements in organic electronic materials and their potential for cost-effective optoelectronic devices. The investigation focuses on the molecular design, synthesis, and comprehensive analysis of two organic dyes, aiming to explore their suitability for optoelectronic applications. The dyes are strategically constructed with carbazole as the foundational structure, connecting two electron-withdrawing groups: barbituric acid (Cz-BA) and thiobarbituric acid (Cz-TBA). These dyes, featuring carbazole as the core and electron-withdrawing groups, demonstrate promising spectral, optical, electrochemical, thermal, and theoretical properties. They show strong potential for diverse optoelectronic applications, promising efficient light absorption and robust stability. The results endorse their suitability for practical optoelectronic systems.

Push-Pull Phenoxazine-Based Sensitizers for p-Type DSSCs: Effect of Acceptor Units on Photovoltaic Performance.

Finding new efficient p-type sensitizers for NiO photocathodes is a great challenge for the development of promising low-cost tandem dye-sensitized solar cells (DSSCs). Now, the focus of researchers investigating these cells has been to create high-performance p-type systems. With this intention, herein, the design and synthesis of six new phenoxazine-based donor-acceptor (D-A)-configured organic dyes PO1-6 was reported, comprising different acceptor moieties specially designed for the sensitization of mesoporous p-type semiconductor NiO for the construction of p-type DSSCs (p-DSSCs). This work includes structural, photophysical, thermal, electrochemical, theoretical, and photoelectrochemical studies of these dyes, including evaluation of their structure-property relationships. The optical studies revealed that PO1-6 displayed adequate absorption and emission features in the range of 480-550 and 560-650 nm, respectively, with a bandgap in the order of 2.05-2.40 eV, and their thermodynamic parameters favored an efficient interfacial charge transfer involving NiO. Among the six new dyes, the device based on sensitizer PO2 carrying electron-withdrawing 1,3-diethyl-2-thiobarbituric acid achieved the highest power conversion efficiency of 0.031 % (short-circuit current density=0.89 mA cm-2 , open-circuit voltage=101 mV, and fill factor=35 %). Conclusively, the study furnishes an understanding of the intricacies involved in the structural modification of phenoxazine-based sensitizers to further ameliorate the performance of the p-type DSSCs.

Simple 3,6-disubstituted Carbazoles as Potential Hole Transport Materials: Photophysical, Electrochemical and Theoretical Studies.

Developing effective and low-cost organic hole-transporting materials (HTMs) is crucial for the construction of high-performance perovskite solar cells (PSCs) and to promote their production in commercial ventures. In this context, we herein report the molecular design, synthesis and characterization of two novel D-A-D-A-D architectured 9-(2-ethylhexyl)-9H-carbazoles, connecting the mono/dimethoxyphenyl substituted cyanovinylene sidearms symmetrically at 3rd and 6th positions of the carbazole heterocycle (CZ1-2 ), as potential hole-transporting materials (HTMs). The current work highlights their structural, photophysical, thermal, electrochemical and theoretical investigations, including their structure-property correlation studies. Evidently, the optical studies showcased their excellent fluorescence ability due to their push-pull natured structure with extended π-conjugation. Further, in-depth solvatochromic studies demonstrated their intramolecular charge-transfer (ICT)-dominated optoelectronic behavior, supported by various correlation studies. Also, the optical results revealed that CZ1  and CZ2 display λabs  and λemi  in the order of 410-430 nm and 530-560 nm, respectively, with a bandgap in the range of 2.5-2.6 eV. Finally, their quantum chemical simulations have provided an insight into the predictions of their structural, molecular, electronic and optical parameters. Conclusively, the study furnishes a deeper understanding of the intricacies involved in the structural modification of carbazole-based HTMs for achieving better performance.

Simple thiophene-bridged D-π-A type chromophores for DSSCs: a comprehensive study of their sensitization and co-sensitization properties.

Herein, we report the design and synthesis of four new thiophene-bridged D-π-A configured organic dyes T1-4 comprising different donors, π-spacers and anchoring units, as potential sensitizers and co-sensitizers for DSSCs. The current work also highlights their structural, photophysical, thermal, electrochemical, theoretical, and photoelectrochemical studies, including evaluation of their structure-property relationships. The optical results revealed that the dyes T1-4 display λabs and λemi in the range of 402-461 nm and 556-575 nm, respectively, with a bandgap in the order of 2.31-2.58 eV. Furthermore, the results showed that the dyes possess all the pre-requisites to act as sensitizers/co-sensitizers. Among the tested dyes, the device based on sensitizer T2 achieved the highest PCE compared to the other three dyes, under the standard conditions. Furthermore, their co-sensitized devices were fabricated by co-adsorbing them with the well-known Ru-based MH-12 sensitizer and interestingly the co-sensitizer T3 carrying an alkoxy group and a barbituric acid anchor displayed the highest PCE of 8.79%, which is much higher than that of MH-12 alone (8.18%). Conclusively, the study furnishes a deeper understanding of the intricacies involved in the structural modification of sensitizers/co-sensitizers in achieving an enhanced performance of the devices.