Bioleaching of manganese from a low-grade pyrolusite ore using Aspergillus niger: Process optimization and kinetic studies.

Low-grade metal resources generated during different mineral processing activities are increasing while there are not many economic and environmentally friendly techniques to manage them. There is no viable technique for the manganese extraction from low-grade ores as the conventional procedures are costly and environmentally unfriendly. In this research, the D-optimal response surface methodology has been used to optimize the bioleaching parameters. Varied contact methods (one-step, two-step, and spent medium), nutrition sources (sucrose and glucose), and pulp densities (1 g.L-1 to 10 g.L-1) were used in different experiments having been done in 30 days using Aspergillus niger. A maximum recovery of over 80% of Mn was achieved based on the acidolysis, complexolysis, and redoxolysis leaching of the organic acids produced by the fungi under the optimum condition; a two-step approach, in a glucose medium, and with a pulp density of 1 g.L-1. A kinetic study was also performed and revealed that the leaching mechanism was a mixed one which consisted of two stages (diffusion through the liquid film and a chemical reaction) for the first 12 day period, and a mechanism of diffusion through the product layer for the rest of the experiment.

Bulk Single Crystal-Like Structural and Magnetic Characteristics of Epitaxial Spinel Ferrite Thin Films with Elimination of Antiphase Boundaries.

Spinel ferrite NiFe2 O4 thin films have been grown on three isostructural substrates, MgAl2 O4 , MgGa2 O4 , and CoGa2 O4 using pulsed laser deposition. These substrates have lattice mismatches of 3.1%, 0.8%, and 0.2%, respectively, with NiFe2 O4 . As expected, the films grown on MgAl2 O4 substrate show the presence of the antiphase boundary defects. However, no antiphase boundaries (APBs) are observed for films grown on near-lattice-matched substrates MgGa2 O4 and CoGa2 O4 . This demonstrates that by using isostructural and lattice-matched substrates, the formation of APBs can be avoided in NiFe2 O4 thin films. Consequently, static and dynamic magnetic properties comparable with the bulk can be realized. Initial results indicate similar improvements in film quality and magnetic properties due to the elimination of APBs in other members of the spinel ferrite family, such as Fe3 O4 and CoFe2 O4 , which have similar crystallographic structure and lattice constants as NiFe2 O4 .