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Bioorg Khim ; 34(6): 847-53, 2008.
Article in Russian | MEDLINE | ID: mdl-19088761

ABSTRACT

Synthesis of tetraphenyl-substituted porphyrins with tret-butyl and methoxycarbonyl groups in meso-aryl radicals is described. It is shown that, during the condensation of dipyrromethanes with substituted benzaldehydes, a rearrangement occurs with the formation of a mixture of isomeric porphyrins. The character of these rearrangements depends on the position of substituents in the starting compounds.


Subject(s)
Benzaldehydes/chemistry , Platinum/chemistry , Porphyrins/chemistry , Porphyrins/chemical synthesis
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