New chitosan-biochar composite derived from agricultural waste for removing sulfamethoxazole antibiotics in water.

This study aims to develop a new chitosan-biochar composite derived from agricultural waste for removing sulfamethoxazole (SMX) antibiotics in water. Biochar was prepared from orange peel (OB) and spent coffee grounds (SCB). To fabricate chitosan-biochar composites, chitosan and biochar were crosslinked with glutaraldehyde. Results showed that pH, adsorbent dosage, time, temperature, and initial concentrations have a significant impact on the SMX adsorption. The adsorption data was better described by Langmuir (with good regression) than Freundlich model. The highest adsorption capacity (Qmax) of SMX on OB, SCB, CTS-OB, and CTS-SCB were 3.49, 7.65, 7.24, and 14.73 mg/g, respectively. The Freundlich constant (KF) values for adsorption capacity were 1.66, 1.91, 2.57, and 5.57 (mg1-nLn/g), respectively, for OB, SCB, CTS-OB, and CTS-SCB. Ion exchange, π bonding, hydrogen bonding and pore filling, were proposed as dominant mechanisms of SMX removal process.

Green and Facile Synthesis of Porous SiO2@C Adsorbents from Rice Husk: Preparation, Characterization, and Their Application in Removal of Reactive Red 120 in Aqueous Solution.

In this work, a green, novel, fast, and facile approach for synthesizing a SiO2/C nanocomposite series from rice husk (RH) through quenching and grinding techniques has been reported along with its application for the adsorptive removal of Reactive Red 120 (RR120) dye from an aqueous solution. The effect of carbonization temperature on the textural and interfacial features of RH was confirmed by scanning electron microscopy (SEM), while the structure and elemental composition of the as-synthesized RH were investigated via XRD, Brunauer-Emmett-Teller (BET), FT-IR, Raman, and X-ray photoelectron spectroscopy (XPS). The RH had a high surface area (521.35 m2 g-1), large micropores, mesopores, and total pore volumes of 0.5059, 3.9931, and 5.2196 cm3 g-1, while SiO2 and C were the two major components. In the batch adsorption test, the effects of pH, contact time, adsorbent mass, temperature, and initial RR120 concentration were investigated. The maximum adsorption capacity was fitted by Langmuir, Freundlich, Temkin, Dubinin-Radushkevich (D-R), Hasley, Harkins-Jura, and BET isotherm models, and Langmuir was the best-fitted model. In addition, the pseudo-first-order, pseudo-second-order, intraparticle diffusion, and Elovich chemisorption models were used to explain the adsorption kinetics. Additionally, the values of Gibbs free energy, enthalpy, and entropy thermodynamics suggested that the RR120 adsorption phenomenon by RH8-3 was endothermic and spontaneous. The adsorption process was controlled by a physical mechanism, and the maximum adsorption capacity was found to be 151.52 mg g-1 at pH 2, with a contact time of 90 min, adsorbent amount of 0.03 g, and temperature of 313 K. The adopted technique may open up a new alternative route for the mass utilization of RH for the removal of dyes in water and wastewater and also for various practical applications.

Green synthesis of Piper chaudocanum stem extract mediated silver nanoparticles for colorimetric detection of Hg2+ ions and antibacterial activity.

A green synthetic approach to synthesize silver nanoparticles (AgNPs) using the stem extract of Piper chaudocanum for highly sensitive colorimetric detection of Hg2+ with a low limit of detection of 23 nM and easy colorimetric read-out has been reported. In addition, the biosynthesized AgNPs demonstrated efficient antibacterial activity against Escherichia coli, Pseudomonas aeruginosa and Staphylococcus aureus. The morphology and structure of the as-synthesized AgNPs were examined using SEM, TEM, EDX, XRD and FT-IR analyses. The XRD and TEM results confirm the formation of AgNPs with an average particle size of 8-12 nm. The TLC, CC and HPLC revealed that four main compounds, pentacosanoic acid (1), piperine (2), ß-sitosterol (3), and campesterol glucoside (4), isolated from P. chaudocanum extract act as reducing and stabilizing agents for AgNP formation, and piperine plays a vital role in green synthesis. The chemical structures of these compounds were determined by ESI MS, FTIR, and one- and two-dimensional NMR spectroscopic data analysis. This approach is an efficient, green, cost-effective, eco-friendly and promising technique for synthesizing AgNPs with applications in the colorimetric detection of Hg2+ and antibacterial activity.

Polycyclic aromatic hydrocarbons in airborne particulate matter samples from Hanoi, Vietnam: Particle size distribution, aryl hydrocarbon ligand receptor activity, and implication for cancer risk assessment.

Concentrations and profiles of unsubstituted and methylated polycyclic aromatic hydrocarbons (PAHs and Me-PAHs) were analyzed in airborne particulate matter (PM) samples collected from high-traffic roads in Hanoi urban area. Levels of PAHs and Me-PAHs ranged from 210 to 660 (average 420) ng/m3 in total PM, and these pollutants were mainly associated with fine particles (PM2.5) rather than coarser ones (PM > 10 and PM10). Proportions of high-molecular-weight compounds (i.e., 5- and 6-ring) increased with decreasing particle size. Benzo[b+k]fluoranthene, indeno[1,2,3-cd]pyrene, and benzo[ghi]perylene were the most predominant compounds in the PM2.5 samples. In all the samples, Me-PAHs were less abundant than unsubstituted PAHs. The PAH-CALUX assays were applied to evaluate aryl hydrocarbon receptor (AhR) ligand activities in crude extracts and different fractions from the PM samples. Benzo[a]pyrene equivalents (BaP-EQs) derived by the PAH-CALUX assays for low polar fractions (mainly PAHs and Me-PAHs) ranged from 300 to 840 ng/m3, which were more consistent with theoretical values derived by using PAH-CALUX relative potencies (270-710 ng/m3) rather than conventional toxic equivalency factor-based values (22-69 ng/m3). Concentrations of PAHs and Me-PAHs highly correlated with bioassay-derived BaP-EQs. AhR-mediated activities of more polar compounds and interaction effects between PAH-related compounds were observed. By using PAH-CALUX BaP-EQs, the ILCR values ranged from 1.0 × 10-4 to 2.8 × 10-4 for adults and from 6.4 × 10-5 to 1.8 × 10-4 for children. Underestimation of cancer risk can be eliminated by using effect-directed method (e.g., PAH-CALUX) rather than chemical-specific approach.

Renewable energy from biomass surplus resource: potential of power generation from rice straw in Vietnam.

Biomass, one of the renewable resources, is expected to play an important role in the world's energy future. In Asia, rice straw is an abundant agricultural surplus because rice is one of the leading staple food crops in the region. Often, rice straw is burned directly in the field via uncontrolled combustion methods that emit large amounts of short-lived air pollutants, greenhouse gases, and other pollutants. In Vietnam, the energy and environment protection sectors are facing great challenges because of rapid urbanisation and industrialisation. A national strategic choice is to exploit renewable energy, including biomass-derived energy, to achieve energy security and CO2 emission reduction. This study investigates the potential of rice straw as an energy source for power plants at a local scale in Vietnam using data derived from satellite Sentinel-1 images. The results show that Vietnam can produce 2,565 MW from rice straw, for which 24 out of 63 provinces have a potential capacity higher than 30 MW, and the Kien Giang province has the highest capacity (245 MW). The study also analyses limitations and obstacles overcoming which can promote the biomass energy sector in the country.

Insights of environmental impact assessment reports for industrial parks: wastewater quantity prediction aspect.

While the contribution of industrial parks to the socio-economic aspect has been widely acknowledged over the past two decades in Vietnam, the problem of environmental pollution due to the wastes generated from industrial parks, especially wastewater, has still been an emerging issue, which places a great pressure on the Government. The wastewater generation from industrial parks was ordinarily required to report in all environmental impact assessment (EIA) reports as a base for the construction of on-site wastewater treatment plants within the industrial park. In Vietnam, this data was, however, often higher than the actual generated number due to inaccurate technical guidelines on predicting wastewater generation and many different methods to be applied. This study aimed to evaluate different approaches used to calculate the effluent in the industrial parks. The results showed that all of the four approaches (i.e., previous operation-based, water-based, wastewater-based, or experience-based methods) rendered significant gaps between predicted and actual values. None can be acceptable for use at present. A revision of technical guideline should be conducted to provide more detailed instruction for the better prediction. This shall minimize the investment capital and increase the efficiency of industrial parks in pollution control.

Modeling of metal binding in tropical Fluvisols and Acrisols treated with biosolids and wastewater.

There is growing concern about the accumulation of metals in tropical agricultural soils. In this study, experimental results from batch studies were used to test whether multi-surface geochemical models could describe metal binding in selected Vietnamese soils. The multi-surface models considered metal binding to iron hydroxides (using the diffuse layer model), organic matter (Stockholm Humic model and NICA-Donnan model), and phyllosilicate clay (Gaines-Thomas equation) as well as complexation to dissolved organic and inorganic ligands in the solution phase. We found that for total dissolved Cd, Cu and Zn the two multi-surface models being tested provided very good model fits for all soils, as evidenced by low root-mean square errors between model predictions and observations. These results suggest that organic matter is an important sorbent for many metals in these soils. However, poor fits were obtained for Cr(III), Mn and Pb for all soils. The study also suggests that the pH is the main factor that controls the solubility of metals in tropical Fluvisols and Acrisols subjected to application of biosolids and wastewater, and that advanced multi-surface models can be used to simulate the binding and release of many trace metals.