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1.
ACS Omega ; 9(16): 17706-17725, 2024 Apr 23.
Article in English | MEDLINE | ID: mdl-38680368

ABSTRACT

Herein, this study was compiled to investigate a suitable solution for the fabrication and development of the multifunctional defense tent from previously reported research. The military always needs to protect their soldiers and equipment from detection. The advancement of infrared detection technology emphasizes the significance of infrared camouflage materials, reducing thermal emissions for various applications. Objects emit infrared radiation detectable by devices, making military targets easily identifiable. Infrared camouflage mitigates detection by lowering an object's infrared radiation, achieved by methods such as reducing surface temperature, which is crucial in designing military tents with infrared (IR) camouflage, considering water repellency and antibacterial features. Water repellency, as well as antimicrobial properties, in army tents is also important as they have to survive in different situations. All these problems should be addressed with the required properties; therefore, the authors try to introduce a new method from which multifunctional tents can be produced through economical, multifunctional, and sustainable materials that have IR protection, water repellency, ultraviolet (UV) protection, air filtration and permeability, and antimicrobial properties. There is still no tent that performs multiple functions at a time, even those functions that do not correlate with each other such as water repellency, IR protection, antimicrobial, and air permeability. So, a multifunctional tent could be the solution to all these problems having all the properties discussed above. In this study based on the literature review, authors concluded a method for the required tent for canvas fabric coated with zinc sulfide (ZnS), graphene oxide (GO), and zinc oxide (ZnO), or these materials should be incorporated in fiber formation because fiber composition has more impact. These multifunctional tents will be very beneficial due to their multifunctions like weather resistance, durability, and long life. These would help the army in their missions by concealing their soldiers and equipment from detection by cameras and providing filtered air inside the tent in case of gases or explosions. The proposed method will help to fulfill the stated and implied needs of customers.

2.
Membranes (Basel) ; 12(12)2022 Dec 05.
Article in English | MEDLINE | ID: mdl-36557137

ABSTRACT

Sweat is a natural body excretion produced by skin glands, and the body cools itself by releasing salty sweat. Wetness in the underarms and feet for long durations causes itchiness and an unpleasant smell. Skin-friendly reusable sweat pads could be used to absorb sweat. Transportation of moisture and functionality is the current challenge that many researchers are working on. This study aims to develop a functional and breathable sweat pad with antimicrobial and quick drying performance. Three layered functional sweat pads (FSP) are prepared in which the inner layer is made of an optimized needle-punched coolmax/polypropylene nonwoven blend. This layer is then dipped in antimicrobial ZnO solution (2, 4, and 6 wt.%), and super absorbent polymer (SAP) is embedded, and this is called a functional nonwoven (FNW1) sheet. Electrospun nanofiber-based nanomembranes of polyamide-6 are optimized for bead-free fibers. They are used as a middle layer to enhance the pad's functionality, and the third layer is again made of needle-punched optimized coolmax/polypropylene nonwoven sheets. A simple nonwoven-based sweat pad (SSP) is also prepared for comparison purposes. Nonwoven sheets are optimized based on better comfort properties, including air/water vapor permeability and moisture management (MMT). Nonwoven webs having a higher proportion of coolmax show better air permeability and moisture transfer from the inner to the outer layer. Antimicrobial activity of the functional nonwoven layer showed 8 mm of bacterial growth, but SSP and FSP showed only 6 mm of growth against Staphylococcus aureus. FSP showed superior comfort and antibacterial properties. This study could be a footstone toward highly functional sweat pads with remarkable comfort properties.

3.
Membranes (Basel) ; 12(11)2022 Nov 17.
Article in English | MEDLINE | ID: mdl-36422150

ABSTRACT

Textile-supported nanocomposite as a scaffold has been extensively used in the medical field, mainly to give support to weak or harmed tissues. However, there are some challenges in fabricating the nanofiber/textile composite, i.e., suitable porous structure with defined pore size, less skin contact area, biocompatibility, and availability of degradable materials. Herein, polyamide-6 (PA) nanofibers were synthesized using needleless electrospinning with the toothed wheel as a spinneret. The electrospinning process was optimized using different process and solution parameters. In the next phase, optimized PA nanofiber membranes of optimum fiber diameter with uniform distribution and thickness were used in making nanofiber membrane-textile composite. Different textile fabrics (woven, non-woven, knitted) were developed. The optimized nanofiber membranes were combined with non-woven, woven, and knitted fabrics to make fabric-supported nanocomposite. The nanofiber/fabric composites were compared with available market woven and knitted meshes for mechanical properties, morphology, structure, and chemical interaction analysis. It was found that the tear strength of the nanofiber/woven composite was three times higher than market woven mesh, and the nanofiber/knitted composite was 2.5 times higher than market knitted mesh. The developed composite structures with woven and knitted fabric exhibited improved bursting strength (613.1 and 751.1 Kpa), tensile strength (195.76 and 227.85 N), and puncture resistance (68.76 and 57.47 N), respectively, than market available meshes. All these properties showed that PA nanofibers/textile structures could be utilized as a composite with multifunctional properties.

4.
Materials (Basel) ; 15(9)2022 Apr 30.
Article in English | MEDLINE | ID: mdl-35591579

ABSTRACT

Modernization and the global fashion market demand continuous improvements in upland cotton cultivars (Gossypium hirustum L.) to meet these improved fiber characteristics (fiber length, fiber strength, micronaire) requirements. Researchers have centered their efforts on improved fiber quality; however, the efforts are not immediately supporting the textile sector. The daily mean and temperature amplitude fluctuation affect cotton yield and fiber characteristics. This study analyzed four newly developed cotton varieties in two cotton regions for fiber characteristics' variations. It was observed that cotton fiber quality characteristics (fiber length, uniformity, strength, and micronaire) are impacted in diverse ways. Fiber quality is mainly affected by the genotype and environmental conditions, e.g., weather conditions, irrigation management, fertilization, and cultural practices. The Khanewal region had shown better fiber characteristics than the Multan region, whereas cotton variety CIM-785 had better fiber characteristics in both regions.

5.
Polymers (Basel) ; 14(5)2022 Mar 04.
Article in English | MEDLINE | ID: mdl-35267852

ABSTRACT

Due to the current COVID-19 pandemic, there is a crucial need for the development of antimicrobial and antiviral personal protective equipment such as facemasks and gowns. Therefore, in this research we fabricated electrospun nanofibers composite with polyvinyl alcohol, aloe vera, and zinc oxide nanoparticles for end application in medical devices. Electrospun nanofibers were made with varying concentrations of aloe vera (1%, 2%, 3%, 4%) having a constant concentration of ZnO (0.5%) with varying concentrations of ZnO nanoparticles (1%, 2%, 3%, 4%) having a constant concentration of aloe vera (0.5%). To check the morphology and composition, all prepared nanofibers were subjected to different characterization techniques, such as Scanning Electron Microscopy (SEM), and Fourier Transform Infrared Spectroscopy (FTIR). In addition, its antimicrobial activity was checked both with qualitative and quantitative approaches against gram-positive (Staphylococcus aureus) bacteria and gram-negative (Escherichia coli) bacteria. The results suggest that increasing ZnO concentration kills and inhibits bacterial growth more proficiently compared to increasing aloe vera concentration in electrospun nanofibers; the highest antimicrobial was found with 4% ZnO, killing almost 100% of gram-positive (Staphylococcus aureus) bacteria and 99.2% of gram-negative (Escherichia coli) bacteria. These fabricated nanofibers have potential applications in medical devices and would help control the spread of many diseases.

6.
Beilstein J Nanotechnol ; 13: 192-200, 2022.
Article in English | MEDLINE | ID: mdl-35223350

ABSTRACT

Piezoelectric materials have attracted more attention than other materials in the field of textiles. Piezoelectric materials offer advantages as transducers, sensors, and energy-harvesting devices. Commonly, ceramics and quartz are used in such applications. However, polymeric piezoelectric materials have the advantage that they can be converted into any shape and size. In smart textiles, polyvinylidene fluoride (PVDF) and other piezoelectric polymers are used in the form of fibers, filaments, and composites. In this research, PVDF nanofibers were developed and integrated onto a knitted fabric to fabricate a piezoelectric device for human body angle monitoring. Scanning electron microscopy and X-ray diffraction analyses were used to study the morphology and to confirm the beta phase in fibers. The results reveal that the nanofibers made from solutions with high concentration were smooth and defect-free, compared to the fibers obtained from solutions with low concentration, and possess high crystallinity as well. Under high dynamic strain more output voltage is generated than under low dynamic strain. The maximum current density shown by the device is 172.5 nA/cm2. The developed piezoelectric nanofiber sensor was then integrated into a knitted fabric through stitching to be used for angle measurement. With increasing bending angle, the output voltage increased. The promising results show that the textile-based piezoelectric sensor developed in this study has a great potential to be used as an angle measuring wearable device for the human body due to its high current density output and flexibility.

7.
Materials (Basel) ; 15(3)2022 Jan 29.
Article in English | MEDLINE | ID: mdl-35160998

ABSTRACT

The hybridization of natural and synthetic fibers leads to composites' optimum mechanical properties. In this study, an attempt was made to study the effect of the stacking sequence on PBS-based Glass-Jute (GJ) hybrid composites. Six types of hybrid composite, each containing five different layers of jute and glass fabric, were manufactured by the compression molding method. Mechanical properties, such as tensile, flexural, and impact resistance were studied and analyzed in detail. The surface characterization of the composites was performed through scanning electron microscopic images. The moisture absorption properties were also investigated by immersing the composites in distilled water for one week at ambient temperature. The TGA test was conducted to study their thermal properties. The experimental results showed that the stacking sequence of the fiber layers has a significant effect on the overall performance of GJ hybrid composites. Among the hybrid GJ composites, composites with glass fiber layers on their outer surfaces showed optimum mechanical, thermal, and water resistance properties.

8.
Micromachines (Basel) ; 12(12)2021 Nov 29.
Article in English | MEDLINE | ID: mdl-34945325

ABSTRACT

Scaffold-based bone tissue engineering has been introduced as an alternative treatment option for bone grafting due to limitations in the allograft. Not only physical conditions but also biological conditions such as gene expression significantly impact bone regeneration. Scaffolds in composition with bioactive molecules such as miRNA mimics provide a platform to enhance migration, proliferation, and differentiation of osteoprogenitor cells for bone regeneration. Among scaffolds, fibrous structures showed significant advantages in promoting osteogenic differentiation and bone regeneration via delivering bioactive molecules over the past decade. Here, we reviewed the bone and bone fracture healing considerations for the impact of miRNAs on bone regeneration. We also examined the methods used to improve miRNA mimics uptake by cells, the fabrication of fibrous scaffolds, and the effective delivery of miRNA mimics using fibrous scaffold and their processes for bone development. Finally, we offer our view on the principal challenges of miRNA mimics delivery by nanofibers for bone tissue engineering.

9.
Materials (Basel) ; 14(19)2021 Oct 06.
Article in English | MEDLINE | ID: mdl-34640247

ABSTRACT

The aerial parts of the Argy Worm Wood (AWW) plant have been used in different Chinese foods as a colorant and a taste enhancer for a long time. Despite its application as a food colorant, it has rarely been considered for the coloration of textiles. Keeping in mind the variation in color strength due to the change in phytochemical contents by seasonal change and other variables, the extraction of AWW aerial parts was optimized using the Taguchi method. Optimization was performed on the basis of total phytochemical contents (phenols, flavonoids, and tannins) in the extracted solutions. For this purpose, two different solvent systems, namely sodium hydroxide/water (NaOH/water) and ethanol/water (EtOH/water), were applied through a simple aqueous extraction method at varying levels of solvent concentration, and extraction temperature and duration. Maximum phytochemicals yield of 21.96% was obtained using NaOH/water system with 9 g/L NaOH/water at 85 °C for 20 min and 25.5% with 75% aqueous ethanol at 85 °C for 40 min. Optimized extracts were characterized by UV-Vis and FTIR spectrophotometry, which showed the presence of multiple phytochemicals in the extracts. The dyeing temperature and time were also optimized. Dyed cotton fabrics showed medium to high colorfastness to washing and excellent antibacterial and UV radiation absorption properties. The effect of pre-mordanting with salts of iron and copper was also studied on the color fastness properties. Cotton fabrics dyed with two different solvent system extracts displayed various shades of brown with NaOH/water, and green with aqueous ethanol with and without pre-mordanting. The present study provides the textile industry with a promising source of functional bio-colorant and a value-adding approach for the AWW plant industry.

10.
Nanomaterials (Basel) ; 11(9)2021 Aug 27.
Article in English | MEDLINE | ID: mdl-34578527

ABSTRACT

Designing novel antiviral personal protective equipment (PPE) is crucial for preventing viral infections such as COVID-19 in humans. Here, we fabricate an electrospun nanofiber-based Viroblock (VB)-loaded polyacrylonitrile (PAN)/zinc oxide (ZnO) hybrid nanocomposite for PPE applications. Five different concentrations of Viroblock (0.5%, 1.5%, 2.5%, 3.5%, and 5%) were added to PAN/ZnO solution and loaded for electrospinning. The developed samples reflected antibacterial activity of 92.59% and 88.64% against Staphylococcus aureus and Pseudomonas aeruginosa bacteria, respectively, with 5% VB loading. Moreover, a significant reduction in virus titer (37%) was observed with the 5% VB/PAN/ZnO nanofiber sheet. Hence, VB-loaded PAN/ZnO nanofibers have great potential to kill enveloped viruses such as influenzas and coronaviruses and could be the ideal candidate for the development of nanofiber-based PPE, such as facemasks and surgical gowns, which can play a key role in the protection of frontline health workers and the general public in the COVID-19 pandemic.

11.
Polymers (Basel) ; 13(4)2021 Feb 08.
Article in English | MEDLINE | ID: mdl-33567692

ABSTRACT

Side effects of the drugs' oral administration led us to examine the possibility of using diclofenac sodium (DLF) in a polymeric drug delivery system based on electrospun polyacrylonitrile (PAN) nanofibers, which can be produced cost-effectively and with good applicability for transdermal treatments. The inclusion of DLF in PAN nanofibers increased the nanofiber diameter from ~200 nm to ~500 nm. This increase can be attributed to the increase in the spinning solution viscosity. FTIR spectra confirm the entrapment of the DLF into the PAN nanofibers. X-ray diffraction pattern showed that the inclusion of the DLF in the PAN nanofibers had caused the misalignment in the polymeric chains of the PAN, thus resulting in a decrease of the peak intensity at 2θ = 17o. The DLF loaded PAN nanofibers were efficient against the gram-positive Staphylococcus aureus (S. aureus) and gram-negative Escherichia coli (E. coli), with maximum inhibition zone of 16 ± 0.46 mm for E. coli and 15.5 ± 0.28 mm for S. aureus. Good cell viability ~95% for L929 cells in more extended incubation periods was reported. A gradual release of DLF from the PAN nanofiber was observed and can be attributed to the stability of Pan in PBS medium. Cell adhesion micrographs show that cell-cell interaction is stronger than the cell-material interaction. This type of weak cell interaction with the wound dressing is particularly advantageous, as this will not disturb the wound surface during the nursing of the wound.

12.
Polymers (Basel) ; 14(1)2021 Dec 27.
Article in English | MEDLINE | ID: mdl-35012108

ABSTRACT

This study demonstrated a controllable release properties and synergistic antibacterial actions between orange essential oil (OEO) and silver nanoparticles (AgNPs) incorporated onto cellulose (CL) nanofibers. The preparation of AgNPs attached on CL nanofibers was conducted through multiple processes including the deacetylation process to transform cellulose acetate (CA) nanofibers to CL nanofibers, the in situ synthesis of AgNPs, and the coating of as-prepared silver composite CL nanofibers using OEO solutions with two different concentrations. The success of immobilization of AgNPs onto the surface of CL nanofibers and the incorporation of OEO into the polymer matrix was confirmed by SEM-EDS, TEM, XRD, and FT-IR characterizations. The tensile strength, elongation at break, and Young's modulus of the nanofibers after each step of treatment were recorded and compared to pristine CA nanofibers. The high antibacterial activities of AgNPs and OEO were assessed against Gram-positive B. subtilis and Gram-negative E. coli microorganisms. The combined effects of two antimicrobials, AgNPs and OEO, were distinctively recognized against E. coli.

13.
Carbohydr Polym ; 252: 117175, 2021 Jan 15.
Article in English | MEDLINE | ID: mdl-33183622

ABSTRACT

Water contamination by heavy metals and dyes has been one of the most severe problems globally. Various techniques have been employed to remove these contaminants from water, including adsorption and photocatalysis, which are highly efficient and environmentally friendly approaches. The overuse of traditional petroleum-based plastics in the production of filtration systems aggravates the status quo due to negative impacts on the environment. Bio-based polysaccharide polymers with the green and benign features and potential for commercial applications have been employed as feasible alternatives to replace synthetic polymers and reduce environmental impacts. With unique chemical composition, molecular weights, and functional chemical groups such as hydroxyl, amine, and carboxyl groups, carbohydrate polymers show multitude potentials for dye and metal ion chelation. This review focused on the fabrication of carbohydrate polymers, such as chitosan, cellulose, alginate, pullulan, starch, and hyaluronic acid, into nanofibrous structures using the electrospinning method and their environmental applications.

14.
Sci Rep ; 10(1): 19751, 2020 11 12.
Article in English | MEDLINE | ID: mdl-33184317

ABSTRACT

Textile-based Scaffolds preparation has the attractive features to fulfill the stated and implied needs of the consumer but there are still challenges of stability, elongation, appreciable bio-compatibility, and stated hydrophilic behavior. To overcome these challenges, the authors tried to fabricate a scaffold by blending of two highly biocompatible polymers; polyvinyl alcohol and poly(1,4 cyclohexane isosorbide terephthalate) through co-electrospinning. The resultant scaffold by the stated innovative approach evaluated from different characterizations such as dimensional stability/morphology was evaluated by scanning electron microscopy, chemical interactions by that Fourier transmission infrared spectra, wetting behavior was analyzed by a static angle with a contact angle meter from drop method, elongation was examined by tensile strength tester and in-vitro assessment was done by MTT analysis. Based on verified results, it was concluded that PVA/PICT scaffold has a potential for dual nature of hydrophilicity & hydrophobicity and appreciable cell culture growth, stated dimensional stability and suitable elongation as per requirements of the nature of scaffold.

15.
Materials (Basel) ; 13(17)2020 Sep 02.
Article in English | MEDLINE | ID: mdl-32887482

ABSTRACT

In the present condition of COVID-19, the demand for antimicrobial products such as face masks and surgical gowns has increased. Because of this increasing demand, there is a need to conduct a study on the development of antimicrobial material. Therefore, this study was conducted on the development of Aloe Vera and Polyvinyl Alcohol (AV/PVA) electrospun nanofibers. Four different fibers were developed by varying the concentrations of Aloe vera (0.5%, 1.5%, 2.5%, and 3%) while maintaining the concentration of PVA constant. The developed samples were subjected to different characterization techniques such as SEM, FTIR, XRD, TGA, and ICP studies. After that, the antimicrobial activity of the developed Aloe Vera/PVA electrospun nanofibers was checked against Gram-positive (Staphylococcus aureus) bacteria and Gram-negative (Escherichia coli) bacteria. The developed nanofibers had high profile antibacterial activity against both bacteria, but showed excellent results against S. aureus bacteria as compared with E. coli. These nanofibers have potential applications in the development of surgical gowns, gloves, etc.

16.
Int J Biol Macromol ; 155: 479-489, 2020 Jul 15.
Article in English | MEDLINE | ID: mdl-32240741

ABSTRACT

Wound dressings are the primary barrier between the wound surface and the outer environment. Here we report the fabrication of cellulose acetate (CA)-Manuka honey (MH) composite nanofibrous mats as a biocompatible and antimicrobial wound dressing. CA mats with different quantities of MH were developed by electrospinning. The ATR-FTIR spectra confirm the inclusion of MH in the composite CA-MH nanofibrous mats. The fibers were continuous and bead-free with acceptable mechanical properties. The fiber diameter increased with an increase in MH content. Inclusion of MH in the electrospun composite CA-MH nanofibrous mats shows high efficacy to prevent bacterial growth on the wound surface. The MH loaded CA nanofiber mats showed good antioxidant abilities, while the ability to free radicalize the DPPH was dependent upon the factors of MH content in the fiber and the time of immersion in the DPPH solution. Besides, the nanofibrous mat's high porosity (85-90%) and WVTR values of 2600 to 1950 g/m2/day, suitable for wound breathability and the mats show high cytocompatibility to NIH 3T3 cell line in in vitro testing, proving to be effective for promoting wound healing.


Subject(s)
Anti-Bacterial Agents/pharmacology , Bacteria/drug effects , Bandages , Cellulose/analogs & derivatives , Nanofibers/chemistry , Wound Healing/drug effects , Animals , Anti-Bacterial Agents/chemistry , Biocompatible Materials/chemistry , Biocompatible Materials/pharmacology , Cell Proliferation , Cellulose/chemistry , Cellulose/pharmacology , Honey/analysis , In Vitro Techniques , Mice , NIH 3T3 Cells
17.
Polymers (Basel) ; 12(3)2020 Mar 13.
Article in English | MEDLINE | ID: mdl-32183033

ABSTRACT

The use of acoustic panels is one of the most important methods for sound insulation in buildings. Moreover, it has become increasingly important to use green/natural origin materials in this area to reduce environmental impact. This study focuses on the investigation of acoustic, mechanical and thermal properties of natural fiber waste reinforced green epoxy composites. Three different types of fiber wastes were used, e.g., cotton, coconut and sugarcane with epoxy as the resin. Different fiber volume fractions, i.e., 10%, 15% and 20% for each fiber were used with a composite thickness of 3 mm. The sound absorption coefficient, impact strength, flexural strength, thermal conductivity, diffusivity, coefficient of thermal expansion and thermogravimetric properties of all samples were investigated. It has been found that by increasing the fiber content, the sound absorption coefficient also increases. The coconut fiber-based composites show a higher sound absorption coefficient than in the other fiber-reinforced composites. The impact and flexural strength of the cotton fiber-reinforced composite samples are higher than in other samples. The coefficient of thermal expansion of the cotton fiber-based composite is also higher than the other composites. Thermogravimetric analysis revealed that all the natural fiber-reinforced composites can sustain till 300 °C with a minor weight loss. The natural fiber-based composites can be used in building interiors, automotive body parts and household furniture. Such composite development is an ecofriendly approach to the acoustic world.

18.
Sci Rep ; 9(1): 12640, 2019 09 02.
Article in English | MEDLINE | ID: mdl-31477774

ABSTRACT

Core-shell nanofibers with the ability to carry multiple drugs are attracting the attention to develop appropriate drug delivery systems for wounds dressing applications. In this study, biocompatible core-shell nanofibers have been designed as a promising dual-drug carrier with the capability of delivering both water-soluble and organic solvent-soluble drugs simultaneously. With the aim of fabricating the core-shell nanofibers, the dipping method has been employed. For this propose, core nanofibers made from polyvinyl alcohol (PVA) were immersed in various concentrations of polyacrylonitrile (PAN) and cross-linked by dipping into ethanol. Diclofenac sodium salt (DSs) and gentamicin sulfate (GENs) have been loaded into the core and shell nanofibers as models of the drug, respectively. The morphology study of core-shell nanofibers showed that the concentrations between 1% w/w up to 2% w/w PAN/GENs, with deep penetration into the internal layers of PAV/DSs nanofibers could lead to the core-shell structure. The cytotoxicity results showed the competency of designed core-shell nanofibers for wound dressing application. Also, the release profile exhibits the controllable behavior of drug release.


Subject(s)
Acrylic Resins/chemistry , Bandages , Drug Delivery Systems , Nanofibers/chemistry , Polyvinyl Alcohol/chemistry , Wounds and Injuries/drug therapy , Cell Adhesion/drug effects , Cell Death/drug effects , Cross-Linking Reagents/chemistry , Diclofenac/pharmacology , Diclofenac/therapeutic use , Drug Liberation , Nanofibers/ultrastructure , Photoelectron Spectroscopy , Spectroscopy, Fourier Transform Infrared , Temperature , Thermogravimetry
19.
Int J Nanomedicine ; 14: 2693-2703, 2019.
Article in English | MEDLINE | ID: mdl-31354260

ABSTRACT

BACKGROUND: Silver, incorporation with natural or synthetic polymers, has been used as an effective antibacterial agent since decades. Silver has potential applications in healthcare especially in nanoparticles form but silver sulfadiazine (AgSD) is the most efficient antibacterial agent especially for burn wound dressings. METHOD: In this report, mechanical, structural, and antibacterial properties of PAN nanofibers incorporation with silver sulfadiazine are mainly focused. AgSD was loaded for the first time on electrospinning as well as self-synthesized AgSD on PAN nanofibers by solution immersion method and then compared the results of both. RESULTS: Occurrence of chemical reaction among the functional groups of AgSD and PAN were analyzed using FTIR, for both types of specimen. Morphological and surface properties of prepared nanofiber mats were characterized by scanning electron microscope, and it resulted in uniform nanofibers without bead formation. Diameter of nanofibers was slightly increased with addition of AgSD by in situ and immersion methods respectively. Nanoparticles distribution was analyzed by transmission electron microscopy. Thermal properties were analyzed by thermo-gravimetric analyzer and it was observed that AgSD decreased thermal stability of PAN which is better from biomedical perspective. X-ray diffraction declared crystalline structure of nanofiber mats. Presence of Ag and S contents in nanofiber mats was analyzed by X-ray photo spectroscopy. Antibacterial properties of nanofiber mats were investigated by disc diffusion method was carried out. E. coli and Bacillus bacteria strain were used as gram-negative and gram-positive respectively. Zone inhibition of the bacteria was used as a tool to determine effectiveness of AgSD released from PAN nanofiber mats. The antibacterial properties of PAN nanofibers impregnated with AgSD were determined with both types of bacteria strains to compare with control one. CONCLUSION: On the basis of characterization results it is concluded that PAN/AgSD (immersion) nanofiber mats have better structural and antibacterial properties than that of PAN/AgSD (in situ) nanofiber mats. So, from our point of view, self-synthesized AgSD is recommended for further production of nanofiber mats for antibacterial applications.


Subject(s)
Acrylic Resins/chemistry , Anti-Bacterial Agents/pharmacology , Nanofibers/chemistry , Silver Sulfadiazine/pharmacology , Bacillus/drug effects , Elastic Modulus , Escherichia coli/drug effects , Microbial Sensitivity Tests , Nanofibers/ultrastructure , Photoelectron Spectroscopy , Spectrometry, X-Ray Emission , Spectroscopy, Fourier Transform Infrared , Stress, Mechanical , Tensile Strength , Thermogravimetry , X-Ray Diffraction
20.
Nanomaterials (Basel) ; 8(9)2018 Aug 22.
Article in English | MEDLINE | ID: mdl-30131479

ABSTRACT

In this report, polyvinyl alcohol/zinoxide (PVA/ZnO) & polyvinyl alcohol/titanium dioxide (PVA/TiO2) nanofibers were manufactured in three different concentrations of ZnO and TiO2 NPs for the application of self-cleaning properties because metallic oxides, specifically ZnO & TiO2, have the properties to remove the contaminants by hydroxyl radical (OH-1), which degrades the contaminants into small molecules and finally into CO2 and H2O. Therefore, these composites were manufactured by electrospinning. The resultant nanofibers were characterized for morphology by scan electron microscopy (SEM) & transmission electron microscopy (TEM), chemical interactions by Fourier-transform infrared (FT-IR) spectra, crystalline structure by X-ray diffraction (XRD) spectra water absorbency was evaluated by water contact angle, self-cleaning by solar simulator, and thermal degradation was done by thermogravimetric analysis (TGA) for the sake of nanoparticles the content. On the base of the characterization results it was concluded that these PVA/ZnO & PVA/TiO2 nanofibers have self cleaning properties, but PVA/ZnO nanofibers have higher self-cleaning properties than PVA/TiO2 nanofibers because PVA/ZnO nanofibers have 95% self-cleaning properties, which is higher than PVA/TiO2 nanofibers.

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